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Zinc Chloride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.75 ± 0.23EIKiser, Dillard, et al., 1969RDSH
11.802 ± 0.005PEWang, Niu, et al., 1990Vertical value; LL
11.83PEBauschlicher, Rosi, et al., 1990Vertical value; LL
11.85PEBerkowitz, 1974Vertical value; LLK
11.87 ± 0.05PECocksey, Eland, et al., 1973Vertical value; LLK
11.7PEBoggess, Allen, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl+19.6 ± 0.3?EIKiser, Dillard, et al., 1969RDSH
ZnCl+13.7 ± 0.2ClEIKiser, Dillard, et al., 1969RDSH
Zn+14.6 ± 0.3?EIKiser, Dillard, et al., 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]

Wang, Niu, et al., 1990
Wang, L.-S.; Niu, B.; Lee, Y.T.; Shirley, D.A., Electronic structure and chemical bonding of the first row transition metal dichlorides, MnCl2, NiCl2, and ZnCl2: A high resolution photoelectron spectroscopic study, J. Chem. Phys., 1990, 93, 957. [all data]

Bauschlicher, Rosi, et al., 1990
Bauschlicher, C.W., Jr.; Rosi, M.; Langhoff, S.R., The photoelectron spectroscopy of ZnCl2, Chem. Phys., 1990, 146, 237. [all data]

Berkowitz, 1974
Berkowitz, J., PES of high-temperature vapors. VI. 304 A and 584 APES of Zn, Cd, and Hg halides and the electronegativity scale, J. Chem. Phys., 1974, 61, 407. [all data]

Cocksey, Eland, et al., 1973
Cocksey, B.G.; Eland, J.H.D.; Danby, C.J., Photoelectron spectra of the zinc and cadmium halides, J. Chem. Soc. Faraday Trans. 2, 1973, 69, 1558. [all data]

Boggess, Allen, et al., 1973
Boggess, G.W.; Allen, J.D., Jr.; Schweitzer, G.K., The photoelectron spectra of gaseous zinc(II) and cadmium(II) chlorides, bromides, and iodides, J. Electron Spectrosc. Relat. Phenom., 1973, 2, 467. [all data]


Notes

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