vanadium tetrachloride
- Formula: Cl4V
- Molecular weight: 192.754
- CAS Registry Number: 7632-51-1
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.5 ± 0.5 | EI | Rat'kovskii, Novikova, et al., 1976 | LLK |
| 9.2 | PE | Cox, Evans, et al., 1970 | RDSH |
| 9.41 ± 0.04 | PE | Cox, Evans, et al., 1970 | Vertical value; RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Cl2V+ | 13.2 ± 0.5 | ? | EI | Rat'kovskii, Novikova, et al., 1976 | LLK |
| Cl3V+ | 11.9 ± 0.5 | Cl | EI | Rat'kovskii, Novikova, et al., 1976 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rat'kovskii, Novikova, et al., 1976
Rat'kovskii, I.A.; Novikova, L.N.; Kris'ko, L.Y.; Rokashevich, E.M.,
A mass spectrometric study of vanadium chlorides,
Russ. J. Phys. Chem., 1976, 50, 302. [all data]
Cox, Evans, et al., 1970
Cox, P.A.; Evans, S.; Hamnett, A.; Orchard, A.F.,
The helium-(I) photoelectron spectrum of vanadium tetrachloride,
Chem. Phys. Lett., 1970, 7, 414. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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