Perfluoropropane

• Formula: C₃F₈
• Molecular weight: 188.0193
• IUPAC Standard InChI: InChI=1S/C3F8/c4-1(5,2(6,7)8)3(9,10)11 Copy

  
• IUPAC Standard InChIKey: QYSGYZVSCZSLHT-UHFFFAOYSA-N Copy
• CAS Registry Number: 76-19-7
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Propane, octafluoro-; Freon 218; Genetron 218; Octafluoropropane; C3F8; UN 2424; 1,1,1,2,2,3,3,3-Octafluoropropane; R 218; Perflutren; Propane, 1,1,1,2,2,3,3,3-octafluoro-; Definity; DMP 115; FC 218; FC 218 (refrigerant); HFC 218; MRX 115; PFC 218
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• Information on this page:
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Phase change data
  • Mass spectrum (electron ionization)
  • Fluid Properties
• Data at other public NIST sites:
  • Electron-Impact Ionization Cross Sections (on physics web site)
  • Gas Phase Kinetics Database
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

8 +  = 3 + 8

By formula: 8Na + C₃F₈ = 3C + 8FNa

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pace and Plaush, 1967
Pace, E.L.; Plaush, A.C., Thermodynamic properties of octafluoropropane from 14K to its normal boiling point. An estimate of the barrier to internal rotation from the entropy and heat capacity of the gas, J. Chem. Phys., 1967, 47, 38-43. [all data]

Kolesov, Talakin, et al., 1967
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M., Standard enthalpy of formation of perfluoropropane and enthalpies of formation of normal perfluoroalkanes, Vestn. Mosk. Univ. Khim., 1967, 22, 38-42. [all data]

Dewar and Worley, 1969
Dewar, M.J.S.; Worley, S.D., Photoelectron spectra of molecules. I. Ionization potentials of some organic molecules and their interpretation, J. Chem. Phys., 1969, 50, 654. [all data]

Smith and Kevan, 1967
Smith, D.; Kevan, L., Dissociative charge exchange of rare-gas ions with C₂F₆ and C₃F₈, J. Chem. Phys., 1967, 46, 1586. [all data]

Lifshitz and Grajower, 1969
Lifshitz, C.; Grajower, R., Dissociative electron capture and dissociative ionization in perfluoropropane, Intern. J. Mass Spectrom. Ion Phys., 1969, 3, 211. [all data]

Noutary, 1968
Noutary, C.J., Mass spectrometric study of some fluorocarbons and trifluoromethyl halides, J.Res. NBS, 1968, 72A, 479. [all data]

Bibby and Carter, 1963
Bibby, M.M.; Carter, G., Ionization and dissociation in some fluorocarbon gases, J. Chem. Soc. Faraday Trans., 1963, 59, 2455. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  Cp,liquid	Constant pressure heat capacity of liquid
  S°liquid	Entropy of liquid at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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