Dimethyl methylphosphonate
- Formula: C3H9O3P
- Molecular weight: 124.0755
- IUPAC Standard InChIKey: VONWDASPFIQPDY-UHFFFAOYSA-N
- CAS Registry Number: 756-79-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: DMMP; Dimethyl methanephosphonate; Phosphonic acid, methyl-, dimethyl ester; Methanephosphonic acid, dimethyl ester; Dimethoxymethylphosphine oxide; NCI-C54762; Pyrol DMMP; Methyl phosphonic acid, dimethyl ester; Dimethyl ester of methylphosphonic acid; Furan TF 2000; Fyrol DMMP; Metaran; O,O-Dimethyl methylphosphonate; NSC 62240; Phosphonic acid, P-methyl-, dimethyl ester
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Gas phase ion energetics data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.00 | PE | Zverev and Villem, 1980 | LLK |
10.00 | PE | Zverev, Villem, et al., 1979 | LLK |
10.71 | PE | Chattorpadhyay, Findley, et al., 1981 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CHO+ | 18.9 ± 0.8 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
CH3+ | 16.8 ± 0.1 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
CH3O+ | 13.8 ± 0.2 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
CH4OP+ | 16.9 ± 0.2 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
CH4O2P+ | 13.4 ± 0.3 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
CH5O2P+ | 11.9 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
C2H5O+ | 16.3 ± 0.1 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
C2H6O2P+ | 12.5 ± 0.1 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
C2H6O3P+ | 13.3 ± 0.3 | CH3 | EI | Bafus, Gallegos, et al., 1966 | RDSH |
C2H7O2P+ | 11.5 ± 0.2 | CH2O | EI | Bafus, Gallegos, et al., 1966 | RDSH |
PO+ | 19.4 ± 0.3 | ? | EI | Bafus, Gallegos, et al., 1966 | RDSH |
Mass spectrum (electron ionization)
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-9774 |
NIST MS number | 233393 |
References
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zverev and Villem, 1980
Zverev, V.V.; Villem, Y.Y.,
Ionizationp potentials of phosphoryl compounds,
J. Struct. Chem., 1980, 21, 22, In original 30. [all data]
Zverev, Villem, et al., 1979
Zverev, V.V.; Villem, Ya.Ya.; Bel'skii, V.E.; Kitaev, Yu.P.,
The photoelectronic spectra of phosphoryl compounds,
Izv. Akad. Nauk SSSR, Ser. Khim., 1979, 1, 84. [all data]
Chattorpadhyay, Findley, et al., 1981
Chattorpadhyay, S.; Findley, G.L.; McGlynn, S.P.,
Photoelectron spectroscopy of phosphites and phosphates,
J. Electron Spectrosc. Relat. Phenom., 1981, 24, 27. [all data]
Bafus, Gallegos, et al., 1966
Bafus, D.A.; Gallegos, E.J.; Kiser, R.W.,
An electron impact investigation of some alkyl phosphate esters,
J. Phys. Chem., 1966, 70, 2614. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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