Methane, nitro-
- Formula: CH3NO2
- Molecular weight: 61.0400
- IUPAC Standard InChIKey: LYGJENNIWJXYER-UHFFFAOYSA-N
- CAS Registry Number: 75-52-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Nitromethane; Nitrocarbol; CH3NO2; Nitrometan; UN 1261; NM; NSC 428
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Gas phase ion energetics data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 11.08 ± 0.04 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 180.4 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 172.5 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.1720 ± 0.0060 | LPES | Adams, Schneider, et al., 2009 | B |
0.260 ± 0.080 | LPES | Compton, Carman Jr., et al., 1996 | dipole-bound state: 12±3 meV.; B |
0.01201 | N/A | Lecomte, Carles, et al., 2000 | Dipole-bound state; B |
0.500 ± 0.020 | ECD | Chen, Welk, et al., 1999 | Reanalysis of Chen and Wentworth, 1983; B |
0.49 ± 0.11 | IMRE | Grimsrud, Caldwell, et al., 1985 | ΔGea(423 K) = -12.1 kcal/mol; ΔSea (estimated) = +2.0 eu.; B |
0.451 ± 0.052 | ECD | Chen and Wentworth, 1983 | B |
0.44 ± 0.20 | NBIE | Compton, Reinhardt, et al., 1978 | B |
0.960 ± 0.010 | LPES | Goebbert, Pichugin, et al., 2009 | Stated electron affinity is the Vertical Detachment Energy; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.07 | PE | Pasa-Tolic, Klasine, et al., 1990 | LL |
11.1 ± 0.05 | PI | Lifshitz, Rejwan, et al., 1988 | LL |
10.7 | PE | Ogden, Shaw, et al., 1983 | LBLHLM |
11.12 | PE | Gilman, Hsieh, et al., 1983 | LBLHLM |
11.05 | PE | Katsumata, Shiromaru, et al., 1982 | LBLHLM |
11.28 ± 0.08 | EI | Allam, Migahed, et al., 1982 | LBLHLM |
11.28 | PE | Kimura, Katsumata, et al., 1981 | LLK |
11.1 | PE | Asbrink, Svensson, et al., 1981 | LLK |
11.28 ± 0.08 | EI | Allam, Migahed, et al., 1981 | LLK |
11.07 ± 0.01 | PE | Rabalais, 1972 | LLK |
11.040 ± 0.017 | PI | Nicholson, 1970 | RDSH |
11.23 ± 0.01 | PE | Dewar, Shanshal, et al., 1969 | RDSH |
11.130 ± 0.006 | PI | Nicholson, 1965 | RDSH |
11.08 ± 0.03 | PI | Watanabe, Nakayama, et al., 1962 | RDSH |
11.29 | PE | Bajic, Humski, et al., 1985 | Vertical value; LBLHLM |
11.47 | PE | Katsumata, Shiromaru, et al., 1982 | Vertical value; LBLHLM |
11.31 | PE | Kobayashi, 1978 | Vertical value; LLK |
11.8 | PE | Rao, 1975 | Vertical value; LLK |
11.29 | PE | Kobayashi and Nagakura, 1974 | Vertical value; LLK |
11.31 ± 0.015 | PE | Kobayashi and Nagakura, 1972 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C+ | 22.83 ± 0.05 | ? | EI | Kandel, 1955 | RDSH |
CH2NO2+ | 11.8 ± 0.1 | H | PI | Lifshitz, Rejwan, et al., 1988 | LL |
CH2NO2+ | 11.97 ± 0.02 | H | EI | Kandel, 1955 | RDSH |
CH3+ | 13.6 | NO2 | EI | Haney and Franklin, 1968 | RDSH |
CH3+ | 12.6 | NO2 | EI | Tsuda and Hamill, 1966 | RDSH |
CH3NO+ | 11.75 ± 0.05 | O | PI | Lifshitz, Rejwan, et al., 1988 | LL |
CH3NO+ | 11.95 | O | PIPECO | Gilman, Hsieh, et al., 1983 | LBLHLM |
NO+ | 11.75 ± 0.05 | CH3O | PI | Lifshitz, Rejwan, et al., 1988 | LL |
NO+ | 11.5 | CH3O | PE | Ogden, Shaw, et al., 1983 | LBLHLM |
NO+ | 11.76 | CH3O | PIPECO | Gilman, Hsieh, et al., 1983 | LBLHLM |
NO+ | 11.7 | CH3O | PIPECO | Niwa, Tajima, et al., 1981 | LLK |
NO+ | 11.75 ± 0.01 | ? | PI | Nicholson, 1970 | RDSH |
NO2+ | 12.1 ± 0.1 | CH3 | PI | Lifshitz, Rejwan, et al., 1988 | LL |
NO2+ | 11.97 | CH3 | PE | Ogden, Shaw, et al., 1983 | LBLHLM |
NO2+ | 12.1 | CH3 | PIPECO | Niwa, Tajima, et al., 1981 | LLK |
NO2+ | 13. ± 0. | CH3 | EI | Collin, 1959 | RDSH |
O+ | 14.50 ± 0.16 | ? | EI | Kandel, 1955 | RDSH |
De-protonation reactions
CH2NO2- + =
By formula: CH2NO2- + H+ = CH3NO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 358.0 ± 5.0 | kcal/mol | D-EA | Metz, Cyr, et al., 1991 | gas phase; B |
ΔrH° | 356.4 ± 2.2 | kcal/mol | G+TS | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrH° | 357.4 ± 2.9 | kcal/mol | G+TS | Cumming and Kebarle, 1978 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 349.7 ± 2.0 | kcal/mol | IMRE | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrG° | 350.7 ± 2.0 | kcal/mol | IMRE | Cumming and Kebarle, 1978 | gas phase; B |
ΔrG° | 350.7 ± 2.0 | kcal/mol | IMRE | MacKay and Bohme, 1978 | gas phase; EA: < NO2; B |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | HP-1 | 100. | 527.85 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 110. | 528.16 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 120. | 528.60 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 20. | 531.15 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 30. | 530.05 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 40. | 529.26 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 50. | 528.66 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 60. | 528.15 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 70. | 527.88 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 80. | 527.75 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Capillary | HP-1 | 90. | 526.13 | Görgényi and Héberger, 2003 | N2; Column length: 30. m; Phase thickness: 3. μm |
Packed | OV-1 | 130. | 556. | Gurevich and Roshchina, 2003 | He or N2, Gas-Chrom Q |
Packed | Apolane | 100. | 500. | Castello and D'Amato, 1983 | He, Chromosorb G; Column length: 3. m |
Packed | Apolane | 200. | 500. | Castello and D'Amato, 1983 | He, Chromosorb G; Column length: 3. m |
Packed | SE-30 | 100. | 536. | Winskowski, 1983 | Gaschrom Q; Column length: 2. m |
Packed | SF-96 | 100. | 565. | Boneva and Dimov, 1979 | N2; Column length: 2. m |
Packed | SF-96 | 110. | 565. | Boneva and Dimov, 1979 | N2; Column length: 2. m |
Packed | SF-96 | 90. | 565. | Boneva and Dimov, 1979 | N2; Column length: 2. m |
Packed | Apiezon L | 150. | 512. | Brown, Chapman, et al., 1968 | N2, DCMS-treated Chromosorb W; Column length: 2.3 m |
Kovats' RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SPB-1 | 543.6 | Castello, Timossi, et al., 1988 | N2; Column length: 60. m; Column diameter: 0.75 mm; Program: not specified |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | HP-Innowax | 100. | 1187.8 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Capillary | HP-Innowax | 110. | 1188.5 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Capillary | HP-Innowax | 120. | 1190.2 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Capillary | HP-Innowax | 50. | 1178.5 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Capillary | HP-Innowax | 60. | 1179.2 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Capillary | HP-Innowax | 70. | 1180.6 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Capillary | HP-Innowax | 80. | 1182.9 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Capillary | HP-Innowax | 90. | 1184.7 | Görgényi and Héberger, 2003 | Column length: 30. m; Phase thickness: 0.5 μm |
Packed | Carbowax 20M | 75. | 1172. | Goebel, 1982 | N2, Kieselgur (60-100 mesh); Column length: 2. m |
Kovats' RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | PEG-20M | 1159. | Slizhov and Gavrilenko, 2001 | He; Column length: 10. m; Column diameter: 0.2 mm; Program: not specified |
Capillary | Supelcowax-10 | 1160.9 | Castello, Timossi, et al., 1988 | N2; Column length: 60. m; Column diameter: 0.75 mm; Program: not specified |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-101 | 531. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
Capillary | DB-1 | 521. | Habu, Flath, et al., 1985 | 3. K/min; Column length: 50. m; Column diameter: 0.32 mm; Tstart: 0. C; Tend: 250. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Methyl Silicone | 487. | N/A | Program: not specified |
Capillary | SPB-1 | 526. | Flanagan, Streete, et al., 1997 | 60. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C |
Capillary | Polydimethyl siloxanes | 531. | Zenkevich and Chupalov, 1996 | Program: not specified |
Capillary | DB-1 | 521. | Schuberth, 1994 | 30. m/0.25 mm/1. μm, He; Program: 40C (4min) => 10C/min => 200C => 50C/min => 250C |
Capillary | SPB-1 | 526. | Strete, Ruprah, et al., 1992 | 60. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C |
Capillary | SPB-1 | 565. | Strete, Ruprah, et al., 1992 | 60. m/0.53 mm/5.0 μm, Helium; Program: not specified |
Capillary | OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc. | 536. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | OV-1 | 565. | Ramsey and Flanagan, 1982 | Program: not specified |
Normal alkane RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-Wax | 1177. | Shimadzu, 2012 | 30. m/0.32 mm/0.50 μm, Helium, 4. K/min; Tstart: 40. C; Tend: 260. C |
Capillary | DB-Wax | 1177. | Shimadzu Corporation, 2003 | 30. m/0.32 mm/0.5 μm, He, 4. K/min; Tstart: 40. C; Tend: 260. C |
Normal alkane RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Carbowax 20M | 1154. | Ramsey and Flanagan, 1982 | Program: not specified |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Adams, Schneider, et al., 2009
Adams, C.L.; Schneider, H.; Ervin, K.M.; Weber, J.M.,
Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state,
J. Chem. Phys., 2009, 130, 7, 074307, https://doi.org/10.1063/1.3076892
. [all data]
Compton, Carman Jr., et al., 1996
Compton, R.N.; Carman Jr.; Desfrancois, C.; Abdoul-Carmine, H.; Schermann, J.P.; Hendricks, J.H.,
On the binding of Electrons to Nitromethane: Dipole and Valence Bound Anions,
J. Chem. Phys., 1996, 105, 9, 3472, https://doi.org/10.1063/1.472993
. [all data]
Lecomte, Carles, et al., 2000
Lecomte, F.; Carles, S.; Desfrancois, C.; Johnson, M.A.,
Dipole bound and valence state coupling in argon-solvated nitromethane anions,
J. Chem. Phys., 2000, 113, 24, 10973-10977, https://doi.org/10.1063/1.1326476
. [all data]
Chen, Welk, et al., 1999
Chen, E.C.M.; Welk, N.; Chen, E.S.; Wentworth, W.E.,
Electron affinity, gas-phase acidity, bond dissociation energy, and negative ion states of nitromethane,
J. Phys. Chem. A, 1999, 103, 45, 9072-9079, https://doi.org/10.1021/jp990530l
. [all data]
Chen and Wentworth, 1983
Chen, E.C.M.; Wentworth, W.E.,
Determination of molecular electron affinities using the electron capture detector in the pulse sampling mode at steady state,
J. Phys. Chem., 1983, 87, 45. [all data]
Grimsrud, Caldwell, et al., 1985
Grimsrud, E.; Caldwell, G.; Kebarle, P.,
Electron affinities from electron transfer equilibria: A- + B = A + B-,
J. Am. Chem. Soc., 1985, 107, 4627. [all data]
Compton, Reinhardt, et al., 1978
Compton, R.N.; Reinhardt, P.W.; Cooper, C.D.,
Collisional ionization between alkali atoms and some methane derivatives: Electron affinities for CH3NO2, CF3I, and CF3Br,
J. Chem. Phys., 1978, 68, 4360. [all data]
Goebbert, Pichugin, et al., 2009
Goebbert, D.J.; Pichugin, K.; Sanov, A.,
Low-lying electronic states of CH3NO2 via photoelectron imaging of the nitromethane anion,
J. Chem. Phys., 2009, 131, 16, 164308, https://doi.org/10.1063/1.3256233
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Pasa-Tolic, Klasine, et al., 1990
Pasa-Tolic, L.; Klasine, L.; McGlynn, S.P.,
The HeI PE spectrum and electronic structure of nitroethene,
Chem. Phys. Lett., 1990, 170, 113. [all data]
Lifshitz, Rejwan, et al., 1988
Lifshitz, C.; Rejwan, M.; Levin, I.; Peres, T.,
Unimolecular fragmentations of the nitromenthane cation,
Int. J. Mass Spectrom. Ion Processes, 1988, 84, 271. [all data]
Ogden, Shaw, et al., 1983
Ogden, I.K.; Shaw, N.; Danby, C.J.; Powis, I.,
Competing dissociation channels of nitromethane and methyl nitrite ions and the role of electronic and internal modes of excitation,
Int. J. Mass Spectrom. Ion Processes, 1983, 54, 41. [all data]
Gilman, Hsieh, et al., 1983
Gilman, J.P.; Hsieh, T.; Meisels, G.G.,
Competition between isomerization and fragmentation of gaseous ions. II. Nitromethane and methylnitrite ions,
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Katsumata, Shiromaru, et al., 1982
Katsumata, S.; Shiromaru, H.; Mitani, K.; Iwata, S.; Kimura, K.,
Photoelectron angular distribution and assignments of photoelectron spectra of nitrogen dioxide, nitromethane and nitrobenzene,
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Allam, Migahed, et al., 1982
Allam, S.H.; Migahed, M.D.; El-Khodary, A.,
Electron impact ionization and dissociation of deuterated and non-deuterated methanol, methyl cyanide, nitromethane and nitrobenzene,
Egypt. J. Phys., 1982, 13, 167. [all data]
Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S.,
Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules
in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]
Asbrink, Svensson, et al., 1981
Asbrink, L.; Svensson, A.; Von Niessen, W.; Bieri, G.,
30.4 nm He(II) photoelectron spectra of organic molecules,
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Allam, Migahed, et al., 1981
Allam, S.H.; Migahed, M.D.; El Khodary, A.,
Electron impact study of nitrobenzene and nitromethane,
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Rabalais, 1972
Rabalais, J.W.,
Photoelectron spectroscopic investigation of the electronic structure of nitromethane and nitrobenzene,
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Nicholson, 1970
Nicholson, A.J.C.,
Determination of bond dissociation energies from photoionization efficiency curves
in Recent Developments in Mass Spectrometroscopy, ed. K Ogata and T. Hayakawa, Univ. Park Press, Baltimore, MD, 1970, 745. [all data]
Dewar, Shanshal, et al., 1969
Dewar, M.J.S.; Shanshal, M.; Worley, S.D.,
Calculated and observed ionization potentials gf nitroalkanes and of nitrous and nitric acids and esters. Extension of the MINDO method to nitrogen-oxygen compounds,
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Nicholson, 1965
Nicholson, A.J.C.,
Photoionization-efficiency curves. II. False and genuine structure,
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Watanabe, Nakayama, et al., 1962
Watanabe, K.; Nakayama, T.; Mottl, J.,
Ionization potentials of some molecules,
J. Quant. Spectry. Radiative Transfer, 1962, 2, 369. [all data]
Bajic, Humski, et al., 1985
Bajic, M.; Humski, K.; Klasinc, L.; Ruscic, B.,
Substitution effects on electronic structure of thiophene,
Z. Naturforsch. B:, 1985, 40, 1214. [all data]
Kobayashi, 1978
Kobayashi, T.,
A simple general tendency in photoelectron angular distributions of some monosubstituted benzenes,
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Rao, 1975
Rao, C.N.R.,
Lone-pair ionization bands of chromophores in the photoelectron spectra of organic molecules,
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Kobayashi and Nagakura, 1974
Kobayashi, T.; Nagakura, S.,
Photoelectron spectra of substituted benzenes,
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Kobayashi and Nagakura, 1972
Kobayashi, T.; Nagakura, S.,
Photoelectron spectra of nitro-compounds,
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Kandel, 1955
Kandel, R.J.,
Appearance potential studies. II. Nitromethane,
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Haney and Franklin, 1968
Haney, M.A.; Franklin, J.L.,
Correlation of excess energies of electron-impact dissociations with the translational energies of the products,
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Tsuda and Hamill, 1966
Tsuda, S.; Hamill, W.H.,
Ionization efficiency measurements by the retarding potential difference method,
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Niwa, Tajima, et al., 1981
Niwa, Y.; Tajima, S.; Tsuchiya, T.,
Fragmentation of energy-selected nitromethane ions,
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Collin, 1959
Collin, J.,
Ionization and dissociation of molecules by monoenergetic electrons. III. On the existence of a bent excited state of NO2+,
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Metz, Cyr, et al., 1991
Metz, R.B.; Cyr, D.R.; Neumark, D.M.,
Study of the 2B1 and 2A2 States of CH2NO2 via Ultraviolet Photoelectron Spectroscopy of the CH2NO2- Anion,
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Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr.,
The gas phase acidity scale from methanol to phenol,
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Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P.,
Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A),
Can. J. Chem., 1978, 56, 1. [all data]
MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K.,
Proton-Transfer Reactions in Nitromethane at 297K,
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Görgényi and Héberger, 2003
Görgényi, M.; Héberger, K.,
Minimum in the temperature dependence of the Kováts retention indices of nitroalkanes and alkanenitriles on an apolar phase,
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Gurevich and Roshchina, 2003
Gurevich, K.B.; Roshchina, T.M.,
G as chromatography study of silica modified with polyfluoroalkyl groups,
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Castello and D'Amato, 1983
Castello, G.; D'Amato, G.,
Classification of the Polarity of porous polymer bead stationary phases by comparison with squalane and apolane standard liquid phases,
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. [all data]
Winskowski, 1983
Winskowski, J.,
Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren,
Chromatographia, 1983, 17, 3, 160-165, https://doi.org/10.1007/BF02271041
. [all data]
Boneva and Dimov, 1979
Boneva, S.; Dimov, N.,
Chromatographic retention indices of C1-C4 nitroparaffins,
Zh. Anal. Khim., 1979, 34, 6, 902-905. [all data]
Brown, Chapman, et al., 1968
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Notes
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- Symbols used in this document:
AE Appearance energy EA Electron affinity IE (evaluated) Recommended ionization energy ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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