Trimethyl vinyl tin


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas91.4 ± 4.8kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation relies on -185.5 ± 3.7 kJ/mol for the enthalpy of formation of Sn(Me)3(Br)(l).
Δfgas207.0 ± 4.0kJ/molReviewMartinho Simões 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.7PEHosomi and Traylor, 1975Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H9Sn+10.44 ± 0.11?EIYergey and Lampe, 1968RDSH
C4H9Sn+9.56 ± 0.08CH3EIYergey and Lampe, 1968RDSH

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L190.703.Putnam and Pu, 1965Celite; Column length: 1. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
PackedApiezon L692.Putnam and Pu, 1965, 2Celite, 10. K/min; Column length: 3. m; Tstart: 60. C
PackedApiezon L686.Putnam and Pu, 1965, 2Celite, 15. K/min; Column length: 3. m; Tstart: 60. C
PackedApiezon L705.Putnam and Pu, 1965, 2Celite, 6. K/min; Column length: 3. m; Tstart: 60. C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G., Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy, J. Am. Chem. Soc., 1975, 97, 3682. [all data]

Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W., An electron impact study of ionization and dissociation of trimethylstannanes, J. Organometal. Chem., 1968, 15, 339. [all data]

Putnam and Pu, 1965
Putnam, R.C.; Pu, H., Retention indices of organotins, J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160 . [all data]

Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H., Retention indices of organotins (II), J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289 . [all data]


Notes

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