Ethene, chloro-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C2H3Cl+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)9.99 ± 0.02eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.98 ± 0.02PISheng, Qi, et al., 1995LL
9.99 ± 0.02PIReinke, Kraessig, et al., 1973LLK
10.01PEMines and Thompson, 1973LLK
10.00PELake and Thompson, 1970RDSH
10.00 ± 0.01PISood and Watanabe, 1966RDSH
10.00 ± 0.01SSood and Watanabe, 1966RDSH
10.00 ± 0.02PIMomigny, 1963RDSH
10.0 ± 0.01PIWatanabe, Nakayama, et al., 1962RDSH
9.995PIBralsford, Harris, et al., 1960RDSH
10.00 ± 0.01SWalsh, 1945RDSH
10.2PECambi, Ciullo, et al., 1983Vertical value; LBLHLM
10.2PEVon Niessen, Asbrink, et al., 1982Vertical value; LBLHLM
10.15PEWittel and Bock, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H2+12.5 ± 0.1HClPIReinke, Kraessig, et al., 1973LLK
C2H2+13.8 ± 0.3HClEIHughes, Tiernan, et al., 1969RDSH
C2H2Cl+14.90 ± 0.05HPISheng, Qi, et al., 1995LL
C2H3+12.54 ± 0.02ClPISheng, Qi, et al., 1995LL
C2H3+12.48 ± 0.04ClPIReinke, Kraessig, et al., 1973LLK
C2H3+12.56 ± 0.09ClEIFinney and Harrison, 1972LLK
C2H3+12.5ClEILossing, 1971LLK
H+18.63 ± 0.05C2H2ClPISheng, Qi, et al., 1995LL


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sheng, Qi, et al., 1995
Sheng, L.; Qi, F.; Tao, L.; Zhang, Y.; Yu, S.; Wong, C.-K.; Li, W.-K., Experimental and theoretical studies of the photoionization and dissociative photoionization of vinyl chloride, Int. J. Mass Spectrom. Ion Processes, 1995, 148, 179. [all data]

Reinke, Kraessig, et al., 1973
Reinke, D.; Kraessig, R.; Baumgartel, H., Photoreactions of small organic molecules, Z. Naturforsch. A:, 1973, 28, 1021. [all data]

Mines and Thompson, 1973
Mines, G.W.; Thompson, H.W., Photoelectron spectra of vinyl and allyl halides, Spectrochim. Acta Part A, 1973, 29, 1377. [all data]

Lake and Thompson, 1970
Lake, R.F.; Thompson, H., Photoelectron spectra of halogenated ethylenes, Proc. Roy. Soc. (London), 1970, A315, 323. [all data]

Sood and Watanabe, 1966
Sood, S.P.; Watanabe, K., Absorption and ionization coefficients of vinyl chloride, J. Chem. Phys., 1966, 45, 2913. [all data]

Momigny, 1963
Momigny, J., Ionization potentials and the structures of the photo-ionization yield curves of ethylene and its halogeno derivatives, Nature, 1963, 199, 1179. [all data]

Watanabe, Nakayama, et al., 1962
Watanabe, K.; Nakayama, T.; Mottl, J., Ionization potentials of some molecules, J. Quant. Spectry. Radiative Transfer, 1962, 2, 369. [all data]

Bralsford, Harris, et al., 1960
Bralsford, R.; Harris, P.V.; Price, W.C., The effect of fluorine on the electronic spectra and ionization potentials of molecules, Proc. Roy. Soc. (London), 1960, A258, 459. [all data]

Walsh, 1945
Walsh, A.D., The absorption spectra of the chloro ethylenes in the vacuum ultra-violet, J. Chem. Soc. Faraday Trans., 1945, 41, 35. [all data]

Cambi, Ciullo, et al., 1983
Cambi, R.; Ciullo, G.; Sgamellotti, A.; Tarantelli, F.; Fantoni, R.; Giardini-Guidoni, A.; McCarthy, I.E.; di Martino, V., An (e,2e) spectroscopic investigation and a Green's Function Study of the ionization of chloro- and bromoethylene, Chem. Phys. Lett., 1983, 101, 477. [all data]

Von Niessen, Asbrink, et al., 1982
Von Niessen, W.; Asbrink, L.; Bieri, G., 30.4 nm He(II) Photoelectron spectra of organic molecules. Part VI. Halogeno-compounds (C,H,X: X = Cl, Br, I), J. Electron Spectrosc. Relat. Phenom., 1982, 26, 173. [all data]

Wittel and Bock, 1974
Wittel, K.; Bock, H., Photoelektronenspekten und molekuleigenschaften. XXVII. Chlor- und bromathylene- beispiele fur anderungen in π- und σ-Systemen, Chem. Ber., 1974, 107, 317. [all data]

Hughes, Tiernan, et al., 1969
Hughes, B.M.; Tiernan, T.O.; Futrell, J.H., Ionic reactions in unsaturated compounds. IV. Vinyl chloride, J. Phys. Chem., 1969, 73, 829. [all data]

Finney and Harrison, 1972
Finney, C.D.; Harrison, A.G., A third-derivative method for determining electron-impact onset potentials, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 221. [all data]

Lossing, 1971
Lossing, F.P., Free radicals by mass spectrometry. XLIII. Ionization potentials and ionic heats of formation for vinyl, allyl, and benzyl radicals, Can. J. Chem., 1971, 49, 357. [all data]


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