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Ethane

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - R.C. Dunbar
M - M. M. Meot-Ner (Mautner) and S. G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Aluminum ion (1+) + Ethane = (Aluminum ion (1+) bullet Ethane)

By formula: Al+ + C2H6 = (Al+ bullet C2H6)

QuantityValueUnitsMethodReferenceComment
Deltar38. ± 8.4kJ/molCIDC,EqGStockigt, Schwarz, et al., 1996Anchored to theory; RCD

C2H4+ + Ethane = (C2H4+ bullet Ethane)

By formula: C2H4+ + C2H6 = (C2H4+ bullet C2H6)

QuantityValueUnitsMethodReferenceComment
Deltar64.0kJ/molPHPMSHiraoka and Kebarle, 1980gas phase; M
QuantityValueUnitsMethodReferenceComment
Deltar88.J/mol*KPHPMSHiraoka and Kebarle, 1980gas phase; M

(Cobalt ion (1+) bullet Methane) + Ethane = (Cobalt ion (1+) bullet Ethane bullet Methane)

By formula: (Co+ bullet CH4) + C2H6 = (Co+ bullet C2H6 bullet CH4)

QuantityValueUnitsMethodReferenceComment
Deltar108.J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Enthalpy of reaction

DeltarH° (kJ/mol)T (K)MethodReferenceComment
119. (+5.4,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, «DELTA»rS(480 K); M

Cobalt ion (1+) + Ethane = (Cobalt ion (1+) bullet Ethane)

By formula: Co+ + C2H6 = (Co+ bullet C2H6)

QuantityValueUnitsMethodReferenceComment
Deltar93.3J/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

Enthalpy of reaction

DeltarH° (kJ/mol)T (K)MethodReferenceComment
100. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
117. (+6.7,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, «DELTA»rS(500 K); M

(Cobalt ion (1+) bullet 2Ethane) + Ethane = (Cobalt ion (1+) bullet 3Ethane)

By formula: (Co+ bullet 2C2H6) + C2H6 = (Co+ bullet 3C2H6)

QuantityValueUnitsMethodReferenceComment
Deltar50.kJ/molSIDTKemper, Bushnell, et al., 1993gas phase; «DELTA»rH<; M

Iron ion (1+) + Ethane = (Iron ion (1+) bullet Ethane)

By formula: Fe+ + C2H6 = (Fe+ bullet C2H6)

QuantityValueUnitsMethodReferenceComment
Deltar70. ± 10.kJ/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol)T (K)MethodReferenceComment
64.0 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Nickel ion (1+) + Ethane = (Nickel ion (1+) bullet Ethane)

By formula: Ni+ + C2H6 = (Ni+ bullet C2H6)

QuantityValueUnitsMethodReferenceComment
Deltar120. ± 10.kJ/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stockigt, Schwarz, et al., 1996
Stockigt, D.; Schwarz, J.; Schwarz, H., Theoretical and Experimental Studies on the Bond Dissociation Energies of Al(methane)+, Al(acetylene)+, Al(ethene)+, and Al(ethane)+, J. Phys. Chem., 1996, 100, 21, 8786. [doi:10.1021/jp960060k] [all data]

Hiraoka and Kebarle, 1980
Hiraoka, K.; Kebarle, P., Ion Molecule Reactions in Ethane. Thermochemistry and Structures of the Intermediate Complexes: C4H11+ and C4H10+ Formed in the Reactions of C2H5+ and C2H4+ with C2H6, Can. J. Chem., 1980, 58, 21, 2262. [doi:10.1139/v80-364] [all data]

Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T., Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters, J. Phys. Chem., 1993, 97, 9, 1810. [doi:10.1021/j100111a016] [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976. [doi:10.1021/ja00149a021] [all data]


Notes

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