p-Benzanisidide


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Benzenamine, 4-methoxy- + Benzoyl iodide = Hydrogen iodide + p-Benzanisidide

By formula: C7H9NO + C7H5IO = HI + C14H13NO2

Quantity Value Units Method Reference Comment
Δr-185. ± 2.kJ/molCacKiselev, Khuzyasheva, et al., 1979liquid phase; solvent: Benzene

Benzenamine, 4-methoxy- + Benzoyl bromide = Hydrogen bromide + p-Benzanisidide

By formula: C7H9NO + C7H5BrO = HBr + C14H13NO2

Quantity Value Units Method Reference Comment
Δr-172. ± 0.8kJ/molCacKiselev, Khuzyasheva, et al., 1979liquid phase; solvent: Benzene

Benzenamine, 4-methoxy- + Benzoyl chloride = p-Benzanisidide + Hydrogen chloride

By formula: C7H9NO + C7H5ClO = C14H13NO2 + HCl

Quantity Value Units Method Reference Comment
Δr-168. ± 0.8kJ/molCacKiselev, Khuzyasheva, et al., 1979liquid phase; solvent: Benzene

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
7.6 ± 0.1EIShapiro, Turk, et al., 1970

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C7H5O+11.2 ± 0.1?EIShapiro, Turk, et al., 1970 

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kiselev, Khuzyasheva, et al., 1979
Kiselev, V.D.; Khuzyasheva, d.G.; Konovalov, A.I., Thermochemical study of the acylation of para-substituted anilines, J. Gen. Chem. USSR, 1979, 49, 2273-2276. [all data]

Shapiro, Turk, et al., 1970
Shapiro, R.H.; Turk, J.; Serum, J.W., The effect of substituents on the average internal energy of benzoyl ions generated from N-(substituted-phenyl)benzamides,, Org. Mass Spectrom., 1970, 3, 171. [all data]


Notes

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