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aluminium chloride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
12.8 ± 0.5EIPorter and Zeller, 1960RDSH
12.01PEBarker, Lappert, et al., 1975Vertical value; LLK
12.01PELappert, Pedley, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Al+22.1 ± 0.5?EIPorter and Zeller, 1960RDSH
AlCl+19.5 ± 0.5?EIWahlbeck, 1987LBLHLM
AlCl+19.7 ± 0.5?EIPorter and Zeller, 1960RDSH
AlCl2+13.4 ± 0.5ClEIPorter and Zeller, 1960RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Porter and Zeller, 1960
Porter, R.F.; Zeller, E.E., Mass spectra of aluminum(III) halides and the heats of dissociation of Al2F6(g) and LiFAlF3(g), J. Chem. Phys., 1960, 33, 858. [all data]

Barker, Lappert, et al., 1975
Barker, G.K.; Lappert, M.F.; Pedley, J.B.; Sharp, G.J.; Westwood, N.P.C., Bonding studies of boron and the group 3-5 elements. Part XV. He(I) photoelectron spectra of monomeric group 3 tri-halide, trimethyl, and mixed halogenomethyl species, J. Chem. Soc. Dalton Trans., 1975, 1765. [all data]

Lappert, Pedley, et al., 1974
Lappert, M.F.; Pedley, J.B.; Sharp, G.J.; Westwood, N.P.C., Bonding studies of compounds of boron and the Group III and IV elements. XII. Variable temperature HeI photoelectron spectra of Group III halides, 2MX3<=>M2X6(M=Al or Ga, X=Cl, Br, or I), J. Electron Spectrosc. Relat. Phenom., 1974, 3, 237. [all data]

Wahlbeck, 1987
Wahlbeck, P.G., Mass spectrometry of and standard enthalpies of formation of gaseous sodium tetrachloroaluminate and its dimer, J. Chem. Phys., 1987, 87, 654. [all data]


Notes

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