BCl3+
- Formula: BCl3+
- Molecular weight: 117.169
- CAS Registry Number: 74432-55-6
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: E
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 49300 ± 120 | gas | Bassett and Lloyd, 1971 | |||||
Biehl, Boyle, et al., 1996 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1' | 1 | BCl stretch | 380 ± 15 | gas | PE TPE | Bassett and Lloyd, 1971 Biehl, Boyle, et al., 1996 Shpinkova, Holland, et al., 1999 Mackie, Shpinkova, et al., 2003 | |
e' | 3 | BCl stretch | 1065 ± 15 | gas | TPE | Mackie, Shpinkova, et al., 2003 | |
State: D
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 29990 ± 120 | gas | Bassett and Lloyd, 1971 | |||||
Biehl, Boyle, et al., 1996 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
gas | D-X | 330 | 420 | Lee, Han, et al., 1989 | |||
Creasey, Hatherly, et al., 1993 | |||||||
Biehl, Creasey, et al., 1995 | |||||||
gas | D-A,B | 420 | 580 | Lee, Han, et al., 1989 | |||
Creasey, Hatherly, et al., 1993 | |||||||
Biehl, Creasey, et al., 1995 | |||||||
Txd = 31200 | Ar | D-X | Miller and Andrews, 1980 | ||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1' | 1 | BCl stretch | 476 ± 15 | gas | TPE | Mackie, Shpinkova, et al., 2003 | |
a2 | 2 | OPLA | 218 ± 15 | gas | TPE | Mackie, Shpinkova, et al., 2003 | |
e' | 4 | Deformation | 240 | T | gas | TPE | Mackie, Shpinkova, et al., 2003 |
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 20900 ± 120 | gas | Bassett and Lloyd, 1971 | |||||
Biehl, Boyle, et al., 1996 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1' | 1 | BCl stretch | 468 | gas | PE TPE | Bassett and Lloyd, 1971 Biehl, Boyle, et al., 1996 Shpinkova, Holland, et al., 1999 Mackie, Shpinkova, et al., 2003 | |
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 9280 ± 120 | gas | Bassett and Lloyd, 1971 | |||||
Biehl, Boyle, et al., 1996 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 5080 ± 120 | gas | Bassett and Lloyd, 1971 | |||||
Biehl, Boyle, et al., 1996 | |||||||
Shpinkova, Holland, et al., 1999 | |||||||
Mackie, Shpinkova, et al., 2003 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
e' | 4 | Deformation | 320 | T | gas | PE | Shpinkova, Holland, et al., 1999 |
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
e' | 3 | BCl stretch | 1103.8 | Ne | IR | Jacox, Irikura, et al., 1996 | |
3 | BCl stretch | 1090 | Ar | IR | Miller and Andrews, 1980 | ||
209 | gas | TPE | Yang, Mo, et al., 2005 | ||||
194 | gas | TPE | Yang, Mo, et al., 2005 | ||||
Additional references: Jacox, 1994, page 201; Jacox, 1998, page 255; Jacox, 2003, page 234; Boyle, Seccomb, et al., 1999
Notes
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
d | Photodissociation threshold |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R.,
J. Chem. Soc. A, 1971, 641. [all data]
Biehl, Boyle, et al., 1996
Biehl, H.; Boyle, K.J.; Smith, D.M.; Tuckett, R.P.; Yoxall, K.R.; Codling, K.; Hatherly, P.A.; Stankiewicz, M.,
J. Chem. Soc., 1996, Faraday Trans. 92, 185. [all data]
Shpinkova, Holland, et al., 1999
Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A.,
Mol. Phys., 1999, 96, 323. [all data]
Mackie, Shpinkova, et al., 2003
Mackie, R.A.; Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A.,
A study of the threshold photoelectron spectra and the photoionisation yield curves of the boron trihalides,
Chem. Phys., 2003, 288, 2-3, 211, https://doi.org/10.1016/S0301-0104(03)00025-9
. [all data]
Lee, Han, et al., 1989
Lee, L.C.; Han, J.C.; Suto, M.,
Fluorescence from photoexcitation of BCl3 at 45--106 nm,
J. Chem. Phys., 1989, 91, 4, 2036, https://doi.org/10.1063/1.457063
. [all data]
Creasey, Hatherly, et al., 1993
Creasey, J.C.; Hatherly, P.A.; Lambert, I.R.; Tuckett, R.P.,
Vacuum UV fluorescence excitation spectroscopy of BCl,
Mol. Phys., 1993, 79, 2, 413, https://doi.org/10.1080/00268979300101311
. [all data]
Biehl, Creasey, et al., 1995
Biehl, H.; Creasey, J.C.; Smith, D.M.; Tuckett, R.P.; Yoxall, K.R.; Baumgartel, H.; Jochims, H.W.; Rockland, U.,
J. Chem. Soc., 1995, Faraday Trans. 91, 3073. [all data]
Miller and Andrews, 1980
Miller, J.H.; Andrews, L.,
Matrix photoionization and radiolysis of boron trihalides. Infrared and ultraviolet spectra of boron trichloride(1+) and boron tribromide(1+) and infrared spectra of boron dichloride and boron dibromide,
J. Am. Chem. Soc., 1980, 102, 15, 4900, https://doi.org/10.1021/ja00535a011
. [all data]
Jacox, Irikura, et al., 1996
Jacox, M.E.; Irikura, K.K.; Thompson, W.E.,
Matrix isolation study of the interaction of excited neon atoms with BCl3: Infrared spectra of BCl+3, BCl+2, and BCl-3,
J. Chem. Phys., 1996, 104, 22, 8871, https://doi.org/10.1063/1.471622
. [all data]
Yang, Mo, et al., 2005
Yang, J.; Mo, Y.; Lau, K.C.; Song, Y.; Qian, X.M.; Ng, C.Y.,
A combined vacuum ultraviolet laser and synchrotron pulsed field ionization study of BCl3,
Phys. Chem. Chem. Phys., 2005, 7, 7, 1518, https://doi.org/10.1039/b417083k
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Boyle, Seccomb, et al., 1999
Boyle, K.J.; Seccomb, D.P.; Tuckett, R.P.; Baumgartel, H.; Jochims, H.W.,
Vacuum-UV fluorescence spectroscopy of BF,
J. Phys. B: At. Mol. Opt. Phys., 1999, 32, 11, 2569, https://doi.org/10.1088/0953-4075/32/11/308
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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