bismuth

• Formula: Bi
• Molecular weight: 208.98040
• IUPAC Standard InChI: InChI=1S/Bi Copy

  
• IUPAC Standard InChIKey: JCXGWMGPZLAOME-UHFFFAOYSA-N Copy
• CAS Registry Number: 7440-69-9
• Chemical structure:
  This structure is also available as a 2d Mol file
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • IR Spectrum
  • References
  • Notes
• Data at other public NIST sites:
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  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 121055-32-1 • 4294967295) +  = CAS Reg. No. 121055-32-1

By formula: (CAS Reg. No. 121055-32-1 • 4294967295Bi) + Bi = CAS Reg. No. 121055-32-1

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Bi⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

IR Spectrum

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Timothy J. Johnson, Tanya L. Myers, Yin-Fong Su, Russell G. Tonkyn, Molly Rose K. Kelly-Gorham, and Tyler O. Danby

Condensed Phase Spectrum

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Additional Data

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Polak, Ho, et al., 1991
Polak, M.L.; Ho, J.; Gerber, G.; Lineberger, W.C., Photoelectron Spectroscopy of Negatively Charged Bismuth Clusters: Bi2-, Bi3-, and Bi4-, J. Chem. Phys., 1991, 95, 5, 3053, https://doi.org/10.1063/1.460862 . [all data]

Bilodeau and Haugen, 2001
Bilodeau, R.C.; Haugen, H.K., Electron affinity of Bi using infrared laser photodetachment threshold spectroscopy - art. no. 024501, Phys. Rev. A, 2001, 64, 2, 024501, https://doi.org/10.1103/PhysRevA.64.024501 . [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Lineberger, W.C., Electron affinities of B, Al, Bi, and Pb, J. Chem. Phys., 1981, 74, 2, 1513, https://doi.org/10.1063/1.441174 . [all data]

Sobhy, Reveles, et al., 2009
Sobhy, M.A.; Reveles, J.U.; Gupta, U.; Khanna, S.N.; Castleman, A.W., Photoelectron imaging and theoretical investigation of bimetallic Bi1-2Ga0-2- and Pb-1-4(-) cluster anions, J. Chem. Phys., 2009, 130, 5, 054304, https://doi.org/10.1063/1.3069295 . [all data]

Feldmann, Rackwitx, et al., 1977
Feldmann, D.; Rackwitx, R.; Heinicke, E.; Kaiser, H.J., Photodetachment of Some Atomic Negative Ions: P-, As-, Sb-, Te-, Cr-, Ni-, Z. Physik A., 1977, 282, 2, 143-148, https://doi.org/10.1007/BF01408156 . [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

George, Munsee, et al., 1985
George, S.; Munsee, J.K.; Verges, J., Newly observed 5f-ng transitions in Bi I spectrum, J. Opt. Soc. Am. B, 1985, 2, 1264. [all data]

Young, Mirza, et al., 1980
Young, W.A.; Mirza, M.Y.; Duley, W.W., Three-photon excitation of Rydberg series in lead and bismuth, J. Phys. B:, 1980, 13, 3175. [all data]

Wagner and Grimley, 1974
Wagner, L.C.; Grimley, R.T., A mass spectrometric study of the bismuth vapor system by the angular distribution technique, Chem. Phys. Lett., 1974, 29, 594. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, References

• Symbols used in this document:
  

  EA	Electron affinity
  IE (evaluated)	Recommended ionization energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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