vanadium
- Formula: V
- Molecular weight: 50.9415
- IUPAC Standard InChI: InChI=1S/V
- IUPAC Standard InChIKey: LEONUFNNVUYDNQ-UHFFFAOYSA-N
- CAS Registry Number: 7440-62-2
- Chemical structure:
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- Other data available:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
View reactions leading to V+ (ion structure unspecified)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| IE (evaluated) | 6.746 ± 0.002 | eV | N/A | N/A | L |
| Quantity | Value | Units | Method | Reference | Comment |
| Proton affinity (review) | 859.4 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
| Quantity | Value | Units | Method | Reference | Comment |
| Gas basicity | 836.8 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.526 ± 0.012 | LPES | Feigerle, Corderman, et al., 1981 | B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 6.746 ± 0.002 | LS | James, Kowalczyk, et al., 1994 | LL |
| 6.743 | EVAL | Lide, 1992 | LL |
| 6.7463 | LS | Page and Gudeman, 1990 | LL |
| 6.740 | S | Kelly, 1987 | LBLHLM |
| 6.740 ± 0.002 | S | Sugar and Corliss, 1985 | LBLHLM |
| 6.83 | PE | Dyke, Gravenor, et al., 1985 | LBLHLM |
| ~7.5 | EI | Owzarski and Franzen, 1974 | LLK |
| 7. ± 1. | EI | Farber and Srivastava, 1973 | LLK |
| 6.74 | S | Moore, 1970 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C.,
Binding Energies and Structure of Transition Metal Negative Ions,
J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289
. [all data]
James, Kowalczyk, et al., 1994
James, A.M.; Kowalczyk, P.; Langlois, E.; Campbell, M.D.; Ogawa, A.; Simard, B.,
Resonant two photon ionization spectroscopy of the molecules V2, VNb, and Nb2,
J. Chem. Phys., 1994, 101, 4485. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Page and Gudeman, 1990
Page, R.H.; Gudeman, C.S.,
Completing the iron period: Double-resonance, fluorescence-dip rydberg spectroscopy and ionization potentials of titanium, vanadium, iron, cobalt, and nickel,
J. Opt. Soc. Am. B, 1990, 1761. [all data]
Kelly, 1987
Kelly, R.L.,
Atomic and ionic spectrum lines of hydrogen through kryton,
J. Phys. Chem. Ref. Data, 1987, 16. [all data]
Sugar and Corliss, 1985
Sugar, J.; Corliss, C.,
Atomic energy levels of the iron period elements: Potassium through nickel,
J. Phys. Chem. Ref. Data, 1985, 14. [all data]
Dyke, Gravenor, et al., 1985
Dyke, J.M.; Gravenor, B.W.J.; Hastings, M.P.; Josland, G.D.; Morris, A.,
Gas phase high temperature photoelectron spectroscopy: An investigation of the transition metals scandium and vanadium,
J. Electron Spectrosc. Relat. Phenom., 1985, 35, 65. [all data]
Owzarski and Franzen, 1974
Owzarski, T.P.; Franzen, H.F.,
High temperature mass spectrometry, vaporization, and thermodynamics of vanadium monosulfide,
J. Chem. Phys., 1974, 60, 1113. [all data]
Farber and Srivastava, 1973
Farber, M.; Srivastava, R.D.,
Effusion-mass spectrometric study of thermodynamic properties of vanadium and vanadium nitride,
J. Chem. Soc. Faraday Trans. 1, 1973, 69, 390. [all data]
Moore, 1970
Moore, C.E.,
Ionization potentials and ionization limits derived from the analyses of optical spectra,
Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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