helium
- Formula: He
- Molecular weight: 4.002602
- IUPAC Standard InChIKey: SWQJXJOGLNCZEY-UHFFFAOYSA-N
- CAS Registry Number: 7440-59-7
- Chemical structure:
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Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Ar+ + He = (Ar+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.5 | kJ/mol | EmSpec | Dehmer and Pratt, 1982 | gas phase |
By formula: Co+ + He = (Co+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.9 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 12.6 kJ/mol, ΔrS(100 K) = 61.5 J/mol*K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.5 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 12.6 kJ/mol, ΔrS(100 K) = 61.5 J/mol*K |
By formula: (Co+ • He) + He = (Co+ • 2He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.4 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 14.3 kJ/mol, ΔrS(100 K) = 79.9 J/mol*K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.0 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 14.3 kJ/mol, ΔrS(100 K) = 79.9 J/mol*K |
By formula: (Co+ • 2He) + He = (Co+ • 3He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.5 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 5.10 kJ/mol, ΔrS(100 K) = 46.4 J/mol*K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 48.5 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 5.10 kJ/mol, ΔrS(100 K) = 46.4 J/mol*K |
By formula: Cr+ + He = (Cr+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.4 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 4.1 kJ/mol, ΔrS(100 K) = 55.6 J/mol*K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 61.9 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 4.1 kJ/mol, ΔrS(100 K) = 55.6 J/mol*K |
By formula: Cs+ + He = (Cs+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.5 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase |
ΔrH° | 1.3 | kJ/mol | IMob | Mason and Sharp, 1958 | gas phase |
By formula: HN2+ + He = (HN2+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.0 | kJ/mol | SCATTERING | Meuwly, Nizkorodov, et al., 1996 | gas phase |
By formula: He+ + He = (He+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 228. | kJ/mol | EmSpec | Dehmer and Pratt, 1982 | gas phase |
ΔrH° | 246. | kJ/mol | SCATTERING | Mittman and Weise, 1974 | gas phase |
By formula: (He+ • He) + He = (He+ • 2He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. | kJ/mol | DT | Patterson, 1968 | gas phase; corrected for ln T term |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.0 | J/mol*K | DT | Patterson, 1968 | gas phase; corrected for ln T term |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
-7.9 | 300. | SAMS | Gusinow, Gerber, et al., 1970 | gas phase |
By formula: (He+ • 2He) + He = (He+ • 3He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.6 ± 0.63 | kJ/mol | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 74.1 | J/mol*K | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
3. | 77. | DT | Helm, 1976 | gas phase |
By formula: (He+ • 3He) + He = (He+ • 4He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.7 ± 0.63 | kJ/mol | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 53.6 | J/mol*K | PHPMS | Hiraoka and Mori, 1990 | gas phase |
By formula: (He+ • 4He) + He = (He+ • 5He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.0 ± 0.63 | kJ/mol | PHPMS | Hiraoka and Mori, 1990 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 45.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1990 | gas phase |
By formula: K+ + He = (K+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.4 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase |
ΔrH° | 2.2 | kJ/mol | IMob | Viehland, 1984 | gas phase |
ΔrH° | 2.2 | kJ/mol | IMob | Takebe, 1983 | gas phase |
ΔrH° | 2.4 | kJ/mol | IMob | Robson and Kumar, 1973 | gas phase |
By formula: Li+ + He = (Li+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.15 | kJ/mol | IMob | Gatland, 1984 | gas phase |
ΔrH° | 6.86 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase |
ΔrH° | 7.07 | kJ/mol | IMob | Viehland, 1984 | gas phase |
ΔrH° | 4.56 | kJ/mol | IMob | Mason and Sharp, 1958 | gas phase |
ΔrH° | 13.2 | kJ/mol | IMob | Takebe, 1983 | gas phase |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
-15. | 309. | DT | Colonna-Romano and Keller, 1976 | gas phase; low E/N |
By formula: N2+ + He = (N2+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2. | kJ/mol | PDiss | Bieske, Soliva, et al., 1990 | gas phase; same ΔrH for N2+(B) and (N2+)X; ab initio, Miller, Tennyson, et al., 1988 |
By formula: Na+ + He = (Na+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.98 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase |
ΔrH° | 3.3 | kJ/mol | IMob | Viehland, 1984 | gas phase |
ΔrH° | 3.9 | kJ/mol | IMob | Mason and Sharp, 1958 | gas phase |
ΔrH° | 5.77 | kJ/mol | IMob | Takebe, 1983 | gas phase |
By formula: Ne+ + He = (Ne+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 66.9 | kJ/mol | EmSpec | Dehmer and Pratt, 1982 | gas phase |
By formula: Ni+ + He = (Ni+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.6 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 12.4 kJ/mol, ΔrS(100 K) = 61.5 J/mol*K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.5 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 12.4 kJ/mol, ΔrS(100 K) = 61.5 J/mol*K |
By formula: (Ni+ • He) + He = (Ni+ • 2He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.5 ± 0.4 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 14.3 kJ/mol, ΔrS(100 K) = 82.8 J/mol*K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84.9 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 14.3 kJ/mol, ΔrS(100 K) = 82.8 J/mol*K |
By formula: (Ni+ • 2He) + He = (Ni+ • 3He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.6 ± 0.8 | kJ/mol | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 5.61 kJ/mol, ΔrS(100 K) = 50.2 J/mol*K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 52.7 | J/mol*K | SIDT | Kemper, Hsu, et al., 1991 | gas phase; ΔrH(0 K) = 5.61 kJ/mol, ΔrS(100 K) = 50.2 J/mol*K |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dehmer and Pratt, 1982
Dehmer, P.M.; Pratt, S.T.,
Photoionization of ArKr, ArXe, and KrXe and bond dissociation energies of the rare gas dimer ions,
J. Chem. Phys., 1982, 77, 4804. [all data]
Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T.,
Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar),
J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022
. [all data]
Gislason, 1984
Gislason, E.A.,
Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]
Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W.,
Mobility of gaseous lons in weak electric fields,
Ann. Phys., 1958, 4, 3, 233, https://doi.org/10.1016/0003-4916(58)90049-6
. [all data]
Meuwly, Nizkorodov, et al., 1996
Meuwly, M.; Nizkorodov, S.A.; Maier, J.P.; Bieske, E.J.,
Mid-Infrared Spectra of He-HN2+ and He2-HN2+,
J. Chem. Phys., 1996, 104, 11, 3876, https://doi.org/10.1063/1.471244
. [all data]
Mittman and Weise, 1974
Mittman, H.U.; Weise, H.P.,
Scattering of Ions V. Elastic Scattering of the Symmetric Rare Gas Ion - Rare Gas Atom Systems,
Z. Naturforsch., 1974, A29, 400. [all data]
Patterson, 1968
Patterson, P.L.,
Evidence of the Existence of an He3+ Ion,
J. Chem. Phys., 1968, 48, 8, 3625, https://doi.org/10.1063/1.1669660
. [all data]
Gusinow, Gerber, et al., 1970
Gusinow, M.A.; Gerber, R.A.; Gerardo, J.B.,
He3+ and He4+ in 300K Helium Plasmas: Their Effect on Recombination Loss of Electrons,
Phys. Rev. Lett., 1970, 25, 18, 1248, https://doi.org/10.1103/PhysRevLett.25.1248
. [all data]
Hiraoka and Mori, 1990
Hiraoka, K.; Mori, T.,
Stability of Rare - Gas Cluster Ions,
J. Chem. Phys., 1990, 92, 7, 4408, https://doi.org/10.1063/1.457751
. [all data]
Helm, 1976
Helm, H.,
The Mobilities and Equilibrium Reactions of Helium Ions in Helium at 77K,
J. Phys. B, 1976, 9, 7, 1171, https://doi.org/10.1088/0022-3700/9/7/017
. [all data]
Viehland, 1984
Viehland, L.A.,
Interaction Potentials for Li+ - Rare - Gas Systems,
Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3
. [all data]
Takebe, 1983
Takebe, M.,
The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves,
J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763
. [all data]
Robson and Kumar, 1973
Robson, R.E.; Kumar, K.,
Mobility and Diffusion II. Dependence on Experimental Variables and Interaction Potential for Alkali Ions in Rare Gases,
Aust. J. Phys., 1973, 26, 2, 187, https://doi.org/10.1071/PH730187
. [all data]
Gatland, 1984
Gatland, I.R.,
Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]
Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E.,
The Clustering of O2 and He to Li+,
J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522
. [all data]
Bieske, Soliva, et al., 1990
Bieske, E.J.; Soliva, A.; Welker, M.A.; Maier, J.P.,
The B<---X Electronic Spectrum of N2+ He,
J. Chem. Phys., 1990, 93, 6, 4477, https://doi.org/10.1063/1.458732
. [all data]
Miller, Tennyson, et al., 1988
Miller, S.; Tennyson, J.; Follmeg, B.; Rosmus, P.; Werner, H.,
Ab initio Investigation of the Bond Rovibrational States in the Electronic Ground State of HeN2+,
J. Chem. Phys., 1988, 89, 4, 2178, https://doi.org/10.1063/1.455062
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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