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Cesium ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Cesium ion (1+) + Argon = (Cesium ion (1+) bullet Argon)

By formula: Cs+ + Ar = (Cs+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar8.16kJ/molIMobGatland, 1984gas phase; M
Deltar6.11kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar8.20kJ/molIMobViehland, 1984gas phase; M
Deltar9.54kJ/molIMobTakebe, 1983gas phase; M
Deltar9.6kJ/molIMobTakebe, 1983gas phase; values from this reference are consistently too high; M

Cesium ion (1+) + Carbon dioxide = (Cesium ion (1+) bullet Carbon dioxide)

By formula: Cs+ + CO2 = (Cs+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molDTMcKnight and Sawina, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.8J/mol*KDTMcKnight and Sawina, 1972gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
10.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Cesium ion (1+) + Acetonitrile = (Cesium ion (1+) bullet Acetonitrile)

By formula: Cs+ + C2H3N = (Cs+ bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar80.3kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar77.8J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Cesium ion (1+) bullet Acetonitrile) + Acetonitrile = (Cesium ion (1+) bullet 2Acetonitrile)

By formula: (Cs+ bullet C2H3N) + C2H3N = (Cs+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar69.9kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.4J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Cesium ion (1+) bullet 2Acetonitrile) + Acetonitrile = (Cesium ion (1+) bullet 3Acetonitrile)

By formula: (Cs+ bullet 2C2H3N) + C2H3N = (Cs+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar59.8kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Cesium ion (1+) bullet 3Acetonitrile) + Acetonitrile = (Cesium ion (1+) bullet 4Acetonitrile)

By formula: (Cs+ bullet 3C2H3N) + C2H3N = (Cs+ bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar50.6kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Cesium ion (1+) bullet 4Acetonitrile) + Acetonitrile = (Cesium ion (1+) bullet 5Acetonitrile)

By formula: (Cs+ bullet 4C2H3N) + C2H3N = (Cs+ bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar45.6kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar138.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

Cesium ion (1+) + Dimethyl ether = (Cesium ion (1+) bullet Dimethyl ether)

By formula: Cs+ + C2H6O = (Cs+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) bullet 2Dimethyl ether)

By formula: (Cs+ bullet C2H6O) + C2H6O = (Cs+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar46.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) bullet 3Dimethyl ether)

By formula: (Cs+ bullet 2C2H6O) + C2H6O = (Cs+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar40. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Cesium ion (1+) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Cs+ + C4H10O2 = (Cs+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Cs+ bullet C4H10O2) + C4H10O2 = (Cs+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Cesium ion (1+) + Benzene, fluoro- = (Cesium ion (1+) bullet Benzene, fluoro-)

By formula: Cs+ + C6H5F = (Cs+ bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar50.2 ± 5.0kJ/molCIDTAmunugama and Rodgers, 2002RCD

(Cesium ion (1+) bullet Benzene, fluoro-) + Benzene, fluoro- = (Cesium ion (1+) bullet 2Benzene, fluoro-)

By formula: (Cs+ bullet C6H5F) + C6H5F = (Cs+ bullet 2C6H5F)

Quantity Value Units Method Reference Comment
Deltar44.8 ± 4.6kJ/molCIDTAmunugama and Rodgers, 2002RCD

Cesium ion (1+) + Phenol = (Cesium ion (1+) bullet Phenol)

By formula: Cs+ + C6H6O = (Cs+ bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar66. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Cesium ion (1+) bullet Phenol) + Phenol = (Cesium ion (1+) bullet 2Phenol)

By formula: (Cs+ bullet C6H6O) + C6H6O = (Cs+ bullet 2C6H6O)

Quantity Value Units Method Reference Comment
Deltar61. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

Cesium ion (1+) + Benzene = (Cesium ion (1+) bullet Benzene)

By formula: Cs+ + C6H6 = (Cs+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar64.4 ± 5.0kJ/molCIDTAmicangelo and Armentrout, 2000RCD

(Cesium ion (1+) bullet Benzene) + Benzene = (Cesium ion (1+) bullet 2Benzene)

By formula: (Cs+ bullet C6H6) + C6H6 = (Cs+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar58.6 ± 7.9kJ/molCIDTAmicangelo and Armentrout, 2000RCD

Cesium ion (1+) + Anisole = (Cesium ion (1+) bullet Anisole)

By formula: Cs+ + C7H8O = (Cs+ bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar66.5 ± 5.0kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Cesium ion (1+) bullet Anisole) + Anisole = (Cesium ion (1+) bullet 2Anisole)

By formula: (Cs+ bullet C7H8O) + C7H8O = (Cs+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
Deltar62. ± 4.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Cesium ion (1+) + Toluene = (Cesium ion (1+) bullet Toluene)

By formula: Cs+ + C7H8 = (Cs+ bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar64.0 ± 4.6kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Cesium ion (1+) bullet Toluene) + Toluene = (Cesium ion (1+) bullet 2Toluene)

By formula: (Cs+ bullet C7H8) + C7H8 = (Cs+ bullet 2C7H8)

Quantity Value Units Method Reference Comment
Deltar61.5 ± 4.2kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

Cesium ion (1+) + 12-Crown-4 = (Cesium ion (1+) bullet 12-Crown-4)

By formula: Cs+ + C8H16O4 = (Cs+ bullet C8H16O4)

Quantity Value Units Method Reference Comment
Deltar84.9 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Cesium ion (1+) + 15-Crown-5 = (Cesium ion (1+) bullet 15-Crown-5)

By formula: Cs+ + C10H20O5 = (Cs+ bullet C10H20O5)

Quantity Value Units Method Reference Comment
Deltar100. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Cesium ion (1+) + 1,4,7,10,13,16-Hexaoxacyclooctadecane = (Cesium ion (1+) bullet 1,4,7,10,13,16-Hexaoxacyclooctadecane)

By formula: Cs+ + C12H24O6 = (Cs+ bullet C12H24O6)

Quantity Value Units Method Reference Comment
Deltar168. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Cesium ion (1+) + Water = (Cesium ion (1+) bullet Water)

By formula: Cs+ + H2O = (Cs+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar49.8kJ/molDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Deltar57.3kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.8J/mol*KDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Deltar81.2J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Cesium ion (1+) bullet Water) + Carbon dioxide = (Cesium ion (1+) bullet Carbon dioxide bullet Water)

By formula: (Cs+ bullet H2O) + CO2 = (Cs+ bullet CO2 bullet H2O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
5.0301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Cesium ion (1+) bullet Water) + Water = (Cesium ion (1+) bullet 2Water)

By formula: (Cs+ bullet H2O) + H2O = (Cs+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar47.3kJ/molDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Deltar52.3kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar69.5J/mol*KDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Deltar92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Cesium ion (1+) bullet 2Water) + Water = (Cesium ion (1+) bullet 3Water)

By formula: (Cs+ bullet 2H2O) + H2O = (Cs+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Deltar46.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar69.5J/mol*KDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Deltar99.2J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

(Cesium ion (1+) bullet 3Water) + Water = (Cesium ion (1+) bullet 4Water)

By formula: (Cs+ bullet 3H2O) + H2O = (Cs+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar44.4kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Cesium ion (1+) bullet Water) + Sulfur dioxide = (Cesium ion (1+) bullet Sulfur dioxide bullet Water)

By formula: (Cs+ bullet H2O) + O2S = (Cs+ bullet O2S bullet H2O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Cesium ion (1+) bullet 2Water) + Sulfur dioxide = (Cesium ion (1+) bullet Sulfur dioxide bullet 2Water)

By formula: (Cs+ bullet 2H2O) + O2S = (Cs+ bullet O2S bullet 2H2O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Cesium ion (1+) bullet Water bullet Sulfur dioxide) + Water = (Cesium ion (1+) bullet 2Water bullet Sulfur dioxide)

By formula: (Cs+ bullet H2O bullet O2S) + H2O = (Cs+ bullet 2H2O bullet O2S)

Quantity Value Units Method Reference Comment
Deltar22.kJ/molHPMSBanic and Iribarne, 1985gas phase; electeric fields; M

Cesium ion (1+) + helium = (Cesium ion (1+) bullet helium)

By formula: Cs+ + He = (Cs+ bullet He)

Quantity Value Units Method Reference Comment
Deltar1.5kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar1.3kJ/molIMobMason and Sharp, 1958gas phase; M

Cesium ion (1+) + Krypton = (Cesium ion (1+) bullet Krypton)

By formula: Cs+ + Kr = (Cs+ bullet Kr)

Quantity Value Units Method Reference Comment
Deltar11.7kJ/molIMobGatland, 1984gas phase; M
Deltar9.75kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar11.4kJ/molIMobViehland, 1984gas phase; M
Deltar13.kJ/molIMobTakebe, 1983gas phase; M
Deltar12.8kJ/molIMobTakebe, 1983gas phase; values form this reference are too high; M

Cesium ion (1+) + neon = (Cesium ion (1+) bullet neon)

By formula: Cs+ + Ne = (Cs+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar2.3kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar2.7kJ/molIMobTakebe, 1983gas phase; values from this reference are too high; M

Cesium ion (1+) + Sulfur dioxide = (Cesium ion (1+) bullet Sulfur dioxide)

By formula: Cs+ + O2S = (Cs+ bullet O2S)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molDTMcKnight and Sawina, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KDTMcKnight and Sawina, 1972gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
22.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Cesium ion (1+) + Xenon = (Cesium ion (1+) bullet Xenon)

By formula: Cs+ + Xe = (Cs+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar10.5kJ/molIMobGatland, 1984gas phase; M
Deltar11.5kJ/molSCATTERINGGislason, 1984gas phase; M
Deltar11.0kJ/molIMobViehland, 1984gas phase; M
Deltar10.2kJ/molIMobMason and Sharp, 1958gas phase; M
Deltar14.9kJ/molIMobTakebe, 1983gas phase; values from this source are too high; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gatland, 1984
Gatland, I.R., Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Gislason, 1984
Gislason, E.A., Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Viehland, 1984
Viehland, L.A., Interaction Potentials for Li+ - Rare - Gas Systems, Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3 . [all data]

Takebe, 1983
Takebe, M., The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves, J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763 . [all data]

McKnight and Sawina, 1972
McKnight, L.G.; Sawina, J.M., Drift Velocities and Interactions of Cs+ Ions with Atmospheric Gases, J. Chem. Phys., 1972, 57, 12, 5156, https://doi.org/10.1063/1.1678205 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Ionic Solvation by Aprotic Solvents. Gas Phase Solvation of the Alkali Ions by Acetonitrile, J. Am. Chem. Soc., 1976, 98, 20, 6125, https://doi.org/10.1021/ja00436a010 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a . [all data]

Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T., The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4 . [all data]

Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W., Mobility of gaseous lons in weak electric fields, Ann. Phys., 1958, 4, 3, 233, https://doi.org/10.1016/0003-4916(58)90049-6 . [all data]


Notes

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