carbon
- Formula: C
- Molecular weight: 12.0107
- IUPAC Standard InChIKey: OKTJSMMVPCPJKN-UHFFFAOYSA-N
- CAS Registry Number: 7440-44-0
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Other names: activated carbon
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- NIST Atomic Spectra Database - Lines Holdings (on physics web site)
- NIST Atomic Spectra Database - Levels Holdings (on physics web site)
- NIST Atomic Spectra Database - Ground states and ionization energies (on physics web site)
- Electron-Impact Ionization Cross Sections (on physics web site)
- Gas Phase Kinetics Database
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°solid,1 bar | 5.833 | J/mol*K | N/A | Takahashi and Westrum, 1970 | amorphous phase; Values actually S-S0; there may be a residual entropy. |
S°solid,1 bar | 6.201 | J/mol*K | N/A | Lutcov, Volga, et al., 1970 | T2 extrapolation below 50 K. |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
10.68 | 350. | Dobrosavljevic, Perovic, et al., 1987 | T = 300 to 1800 K. |
9.251 | 298.15 | Lutcov, Volga, et al., 1970 | T = 52 to 302 K. |
8.598 | 298.15 | Takahashi and Westrum, 1970 | amorphous phase; T = 5-350 K. |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 4100. | K | N/A | Honig and Kramer, 1969 | Uncertainty assigned by TRC = 100. K |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 7020.5 | K | N/A | Chang, Ryoo, et al., 1985 | |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 7967.19 | bar | N/A | Chang, Ryoo, et al., 1985 | |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.02662 | l/mol | N/A | Chang, Ryoo, et al., 1985 |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 11.26030 | eV | N/A | N/A | L |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.262114 ± 0.000044 | LPD | Scheer, Bilodeau, et al., 1998 | Given: 1.262119(20) eV; B |
1.26290 ± 0.00030 | LPD | Feldmann, 1977 | B |
>1.2 ± 1.0 | EIAE | Honig, 1954 | From graphite; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.26030 | EVAL | Lide, 1992 | LL |
11.260 | S | Kelly, 1987 | LBLHLM |
12.4 ± 1.0 | EI | Haque and Gingerich, 1981 | LLK |
11.2 ± 0.5 | EI | Gupta and Gingerich, 1979 | LLK |
11.2 ± 0.5 | EI | Gingerich and Gupta, 1978 | LLK |
10.9 ± 0.4 | EI | Cocke and Gingerich, 1974 | LLK |
11.4 ± 1.5 | EI | Cocke, Gingerich, et al., 1973 | LLK |
10.9 ± 0.4 | EI | Cocke and Gingerich, 1972 | LLK |
10.5 ± 1.0 | EI | Cocke and Gingerich, 1972, 2 | LLK |
11.26030 | S | Moore, 1970 | RDSH |
11.3 ± 0.2 | EI | Drowart, Burns, et al., 1959 | RDSH |
Anion protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1529.4 ± 0.71 | kJ/mol | D-EA | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.262119(20) eV; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1506.2 ± 1.1 | kJ/mol | H-TS | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.262119(20) eV; B |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Takahashi and Westrum, 1970
Takahashi, Y.; Westrum, E.F., Jr.,
Glassy carbon. Low-temperature thermodynamic properties,
J. Chem. Thermodynam., 1970, 2, 847-854. [all data]
Lutcov, Volga, et al., 1970
Lutcov, A.I.; Volga, V.I.; Dymov, B.K.,
Thermal conductivity, electric resistivity and specific heat of dense graphites,
Carbon, 1970, 8, 753-760. [all data]
Dobrosavljevic, Perovic, et al., 1987
Dobrosavljevic, A.; Perovic, N.; Maglic, K.,
Thermophysical properties of POCO AXM-5Q1 graphite in the 300 to 1800 K range,
High Temperatures-High Pressures, 1987, 19, 303-310. [all data]
Honig and Kramer, 1969
Honig, R.E.; Kramer, D.A.,
Vapor pressure data for the solid and liquid elements,
RCA Rev., 1969, 1969, 285. [all data]
Chang, Ryoo, et al., 1985
Chang, M.C.; Ryoo, R.; Jhon, M.S.,
Thermodynamic Properties of Liquid Carbon,
Carbon, 1985, 23, 5, 481. [all data]
Scheer, Bilodeau, et al., 1998
Scheer, M.; Bilodeau, R.C.; Brodie, C.A.; Haugen, H.K.,
Systematic study of the stable states of C-, Si-, Ge-, and Sn- via infrared laser spectroscopy,
Phys. Rev. A, 1998, 58, 4, 2844-2856, https://doi.org/10.1103/PhysRevA.58.2844
. [all data]
Feldmann, 1977
Feldmann, D.,
Infrared Photodetachment Measurements Near Thresholds of C-,
Chem. Phys. Lett., 1977, 47, 2, 338, https://doi.org/10.1016/0009-2614(77)80032-8
. [all data]
Honig, 1954
Honig, R.E.,
Mass spectrometric study of the molecular sublimation of graphite,
J. Chem. Phys., 1954, 22, 126. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Kelly, 1987
Kelly, R.L.,
Atomic and ionic spectrum lines of hydrogen through kryton,
J. Phys. Chem. Ref. Data, 1987, 16. [all data]
Haque and Gingerich, 1981
Haque, R.; Gingerich, K.A.,
Identification and atomization energies of gaseous molecules ScC2, ScC3, ScC4, ScC5, and ScC6 by high temperature mass spectrometry,
J. Chem. Phys., 1981, 74, 6407. [all data]
Gupta and Gingerich, 1979
Gupta, S.K.; Gingerich, K.A.,
Observation and atomization energies of the gaseous uranium carbides, UC, UC2, UC3, UC4, UC5, and UC6 by high temperature mass spectrometry,
J. Chem. Phys., 1979, 71, 3072. [all data]
Gingerich and Gupta, 1978
Gingerich, K.A.; Gupta, K.A.,
Dissociation energies of the molecules RhTh and RhU from high temperature mass spectrometry and predicted thermodynamic stabilities of selected diatomic actinide-platinum metal intermetallic molecules,
J. Chem. Phys., 1978, 69, 505. [all data]
Cocke and Gingerich, 1974
Cocke, D.L.; Gingerich, K.A.,
Thermodynamic investigation of the gaseous molecules TiRh, Rh2, and Ti2Rh by mass spectrometry,
J. Chem. Phys., 1974, 60, 1958. [all data]
Cocke, Gingerich, et al., 1973
Cocke, D.L.; Gingerich, K.A.; Kordis, J.,
Determination of the high bond dissociation energy of the molecule LaRh,
High Temp. Sci., 1973, 5, 474. [all data]
Cocke and Gingerich, 1972
Cocke, D.L.; Gingerich, K.A.,
Determination of the heats of atomization of the molecules RhC2, RhC, and TiC2 by high temperature mass spectrometry,
J. Chem. Phys., 1972, 57, 3654. [all data]
Cocke and Gingerich, 1972, 2
Cocke, D.L.; Gingerich, K.A.,
Mass spectrometric determination of the bond dissociation energies of the molecules CePd and CeC2,
J. Phys. Chem., 1972, 76, 2332. [all data]
Moore, 1970
Moore, C.E.,
Ionization potentials and ionization limits derived from the analyses of optical spectra,
Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]
Drowart, Burns, et al., 1959
Drowart, J.; Burns, R.P.; DeMaria, G.; Inghram, M.G.,
Mass spectrometric study of carbon vapor,
J. Chem. Phys., 1959, 31, 1131. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid EA Electron affinity IE (evaluated) Recommended ionization energy Pc Critical pressure S°solid,1 bar Entropy of solid at standard conditions (1 bar) Tboil Boiling point Tc Critical temperature Vc Critical volume ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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