carbon
- Formula: C
- Molecular weight: 12.0107
- IUPAC Standard InChIKey: OKTJSMMVPCPJKN-UHFFFAOYSA-N
- CAS Registry Number: 7440-44-0
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Other names: activated carbon
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- NIST Atomic Spectra Database - Lines Holdings (on physics web site)
- NIST Atomic Spectra Database - Levels Holdings (on physics web site)
- NIST Atomic Spectra Database - Ground states and ionization energies (on physics web site)
- Electron-Impact Ionization Cross Sections (on physics web site)
- Gas Phase Kinetics Database
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 11.26030 | eV | N/A | N/A | L |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.262114 ± 0.000044 | LPD | Scheer, Bilodeau, et al., 1998 | Given: 1.262119(20) eV; B |
1.26290 ± 0.00030 | LPD | Feldmann, 1977 | B |
>1.2 ± 1.0 | EIAE | Honig, 1954 | From graphite; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.26030 | EVAL | Lide, 1992 | LL |
11.260 | S | Kelly, 1987 | LBLHLM |
12.4 ± 1.0 | EI | Haque and Gingerich, 1981 | LLK |
11.2 ± 0.5 | EI | Gupta and Gingerich, 1979 | LLK |
11.2 ± 0.5 | EI | Gingerich and Gupta, 1978 | LLK |
10.9 ± 0.4 | EI | Cocke and Gingerich, 1974 | LLK |
11.4 ± 1.5 | EI | Cocke, Gingerich, et al., 1973 | LLK |
10.9 ± 0.4 | EI | Cocke and Gingerich, 1972 | LLK |
10.5 ± 1.0 | EI | Cocke and Gingerich, 1972, 2 | LLK |
11.26030 | S | Moore, 1970 | RDSH |
11.3 ± 0.2 | EI | Drowart, Burns, et al., 1959 | RDSH |
Anion protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 365.54 ± 0.17 | kcal/mol | D-EA | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.262119(20) eV; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 360.00 ± 0.27 | kcal/mol | H-TS | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.262119(20) eV; B |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Scheer, Bilodeau, et al., 1998
Scheer, M.; Bilodeau, R.C.; Brodie, C.A.; Haugen, H.K.,
Systematic study of the stable states of C-, Si-, Ge-, and Sn- via infrared laser spectroscopy,
Phys. Rev. A, 1998, 58, 4, 2844-2856, https://doi.org/10.1103/PhysRevA.58.2844
. [all data]
Feldmann, 1977
Feldmann, D.,
Infrared Photodetachment Measurements Near Thresholds of C-,
Chem. Phys. Lett., 1977, 47, 2, 338, https://doi.org/10.1016/0009-2614(77)80032-8
. [all data]
Honig, 1954
Honig, R.E.,
Mass spectrometric study of the molecular sublimation of graphite,
J. Chem. Phys., 1954, 22, 126. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Kelly, 1987
Kelly, R.L.,
Atomic and ionic spectrum lines of hydrogen through kryton,
J. Phys. Chem. Ref. Data, 1987, 16. [all data]
Haque and Gingerich, 1981
Haque, R.; Gingerich, K.A.,
Identification and atomization energies of gaseous molecules ScC2, ScC3, ScC4, ScC5, and ScC6 by high temperature mass spectrometry,
J. Chem. Phys., 1981, 74, 6407. [all data]
Gupta and Gingerich, 1979
Gupta, S.K.; Gingerich, K.A.,
Observation and atomization energies of the gaseous uranium carbides, UC, UC2, UC3, UC4, UC5, and UC6 by high temperature mass spectrometry,
J. Chem. Phys., 1979, 71, 3072. [all data]
Gingerich and Gupta, 1978
Gingerich, K.A.; Gupta, K.A.,
Dissociation energies of the molecules RhTh and RhU from high temperature mass spectrometry and predicted thermodynamic stabilities of selected diatomic actinide-platinum metal intermetallic molecules,
J. Chem. Phys., 1978, 69, 505. [all data]
Cocke and Gingerich, 1974
Cocke, D.L.; Gingerich, K.A.,
Thermodynamic investigation of the gaseous molecules TiRh, Rh2, and Ti2Rh by mass spectrometry,
J. Chem. Phys., 1974, 60, 1958. [all data]
Cocke, Gingerich, et al., 1973
Cocke, D.L.; Gingerich, K.A.; Kordis, J.,
Determination of the high bond dissociation energy of the molecule LaRh,
High Temp. Sci., 1973, 5, 474. [all data]
Cocke and Gingerich, 1972
Cocke, D.L.; Gingerich, K.A.,
Determination of the heats of atomization of the molecules RhC2, RhC, and TiC2 by high temperature mass spectrometry,
J. Chem. Phys., 1972, 57, 3654. [all data]
Cocke and Gingerich, 1972, 2
Cocke, D.L.; Gingerich, K.A.,
Mass spectrometric determination of the bond dissociation energies of the molecules CePd and CeC2,
J. Phys. Chem., 1972, 76, 2332. [all data]
Moore, 1970
Moore, C.E.,
Ionization potentials and ionization limits derived from the analyses of optical spectra,
Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]
Drowart, Burns, et al., 1959
Drowart, J.; Burns, R.P.; DeMaria, G.; Inghram, M.G.,
Mass spectrometric study of carbon vapor,
J. Chem. Phys., 1959, 31, 1131. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity IE (evaluated) Recommended ionization energy ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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