antimony

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
1058. to 1373.2.254704475.449-152.352Jellinek and Wannow, 1935Coefficents calculated by NIST from author's data.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 64177-62-4 • 4294967295antimony) + antimony = CAS Reg. No. 64177-62-4

By formula: (CAS Reg. No. 64177-62-4 • 4294967295Sb) + Sb = CAS Reg. No. 64177-62-4

Quantity Value Units Method Reference Comment
Δr74.51kcal/molN/APolak, Gerber, et al., 1992gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Sb+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)8.64eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
1.047418 ± 0.000044N/AScheer, Haugen, et al., 1997B
1.0460 ± 0.0050LPESPolak, Gerber, et al., 1992B
1.070 ± 0.050PDFeldmann, Rackwitx, et al., 1977B

Ionization energy determinations

IE (eV) Method Reference Comment
8.64EVALLide, 1992LL
8.6EIBusse and Weil, 1982LBLHLM
8.3 ± 0.4EIPiacente and Balducci, 1974LLK
8.68 ± 0.06EICabaud, Hoareau, et al., 1973LLK
8.641SMoore, 1970RDSH

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jellinek and Wannow, 1935
Jellinek, K.; Wannow, H.-A., Dampfspannungen und Aktivataten Vollstandig und Unvollstandig Mischbarer Metalle in Flussigen Binaren und Ternaren Legierungen Mit Einer und Zwei Fluchtigen Komponentenq, Z. Elektrochem., 1935, 41, 6, 346-362. [all data]

Polak, Gerber, et al., 1992
Polak, M.L.; Gerber, G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Small Antimony Cluster Anions - Sb(-) Sb2(-), Sb3(-), and Sb4(-), J. Chem. Phys., 1992, 97, 12, 8990, https://doi.org/10.1063/1.463326 . [all data]

Scheer, Haugen, et al., 1997
Scheer, M.; Haugen, H.K.; Beck, D.R., Single- and Multiphoton Infrared Laser Spectroscopy of Sb-: A Case Study, Phys. Rev. Lett., 1997, 79, 21, 4104-4107, https://doi.org/10.1103/PhysRevLett.79.4104 . [all data]

Feldmann, Rackwitx, et al., 1977
Feldmann, D.; Rackwitx, R.; Heinicke, E.; Kaiser, H.J., Photodetachment of Some Atomic Negative Ions: P-, As-, Sb-, Te-, Cr-, Ni-, Z. Physik A., 1977, 282, 2, 143-148, https://doi.org/10.1007/BF01408156 . [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Busse and Weil, 1982
Busse, B.; Weil, K.G., Mass spectrometric studies on the vapour phase composition over solid and fused Cs3Sb, Ber. Bunsen-Ges. Phys. Chem., 1982, 86, 93. [all data]

Piacente and Balducci, 1974
Piacente, V.; Balducci, G., The dissociation energy of the molecule GaSb, High Temp. Sci., 1974, 6, 254. [all data]

Cabaud, Hoareau, et al., 1973
Cabaud, B.; Hoareau, A.; Nounou, P.; Uzan, R., High temperature mass spectrometric study of polyatomic antimony species by electron impact. Direct evidence for the existence of Sb3 molecules, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 157. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

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