rhenium


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Dirhenium decacarbonyl (cr) = 10Carbon monoxide (g) + 2rhenium (cr)

By formula: C10O10Re2 (cr) = 10CO (g) + 2Re (cr)

Quantity Value Units Method Reference Comment
Δr129.0 ± 1.4kcal/molTD-HFCConnor, Skinner, et al., 1973 
Δr132.0 ± 0.72kcal/molHAL-HFCConnor, Skinner, et al., 1973 

C6H3O5Re (cr) = 5Carbon monoxide (g) + rhenium (cr) + Methane (g)

By formula: C6H3O5Re (cr) = 5CO (g) + Re (cr) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr100.7 ± 2.0kcal/molHAL-HFCBrown, Connor, et al., 1974Please also see Pedley and Rylance, 1977.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to Re+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.88eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
7.88EVALLide, 1992LL
7.76 ± 0.03EIRauh and Ackermann, 1979LLK
7.88SMoore, 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Rauh and Ackermann, 1979
Rauh, E.G.; Ackermann, R.J., The first ionization potentials of the transition metals, J. Chem. Phys., 1979, 70, 1004. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

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