potassium
- Formula: K
- Molecular weight: 39.0983
- IUPAC Standard InChIKey: ZLMJMSJWJFRBEC-UHFFFAOYSA-N
- CAS Registry Number: 7440-09-7
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- NIST Atomic Spectra Database - Lines Holdings (on physics web site)
- NIST Atomic Spectra Database - Levels Holdings (on physics web site)
- NIST Atomic Spectra Database - Ground states and ionization energies (on physics web site)
- Gas Phase Kinetics Database
- X-ray Photoelectron Spectroscopy Database, version 5.0
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Gas phase ion energetics data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to K+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 4.34066 ± 0.00001 | eV | N/A | N/A | L |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
4.34066 | EVAL | Lide, 1992 | LL |
4.34066 | S | Kelly, 1987 | LBLHLM |
4.34066 ± 0.00001 | S | Sugar and Corliss, 1985 | LBLHLM |
4.5 ± 1.0 | S | Farber, Srivastava, et al., 1982 | LBLHLM |
4.4 | EI | Zmbov, Wu, et al., 1977 | LLK |
4.1 ± 0.3 | EI | Simmons, Lowden, et al., 1977 | LLK |
4.34 | PE | Williams and Potts, 1976 | LLK |
4.34066 | S | Moore, 1970 | RDSH |
Ion clustering data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: (K+ • 2K) + K = (K+ • 3K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 43.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 3K) + K = (K+ • 4K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 64.9 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 4K) + K = (K+ • 5K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 52.3 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 5K) + K = (K+ • 6K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 72.4 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 6K) + K = (K+ • 7K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 7K) + K = (K+ • 8K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 8K) + K = (K+ • 9K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 9K) + K = (K+ • 10K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 10K) + K = (K+ • 11K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 11K) + K = (K+ • 12K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 12K) + K = (K+ • 13K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 13K) + K = (K+ • 14K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.3 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 14K) + K = (K+ • 15K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 15K) + K = (K+ • 16K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 16K) + K = (K+ • 17K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 64.9 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 17K) + K = (K+ • 18K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 67.4 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 18K) + K = (K+ • 19K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 65.7 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 19K) + K = (K+ • 20K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 72.4 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 20K) + K = (K+ • 21K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 21K) + K = (K+ • 22K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 22K) + K = (K+ • 23K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.9 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
By formula: (K+ • 23K) + K = (K+ • 24K)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 61.9 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1990 | gas phase |
References
Go To: Top, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Kelly, 1987
Kelly, R.L.,
Atomic and ionic spectrum lines of hydrogen through kryton,
J. Phys. Chem. Ref. Data, 1987, 16. [all data]
Sugar and Corliss, 1985
Sugar, J.; Corliss, C.,
Atomic energy levels of the iron period elements: Potassium through nickel,
J. Phys. Chem. Ref. Data, 1985, 14. [all data]
Farber, Srivastava, et al., 1982
Farber, M.; Srivastava, R.D.; Moyer, J.W.,
Mass spectrometric determination of the thermodynamics of potassium hydroxide and minor potassium-containing species required in magnetohydrodynamic power systems,
J. Chem. Thermodyn., 1982, 14, 1103. [all data]
Zmbov, Wu, et al., 1977
Zmbov, K.F.; Wu, C.H.; Ihle, H.R.,
A mass spectrometric study of heteronuclear diatomic alkali metal molecules. Dissociation energies ionization potentials of NaLi, KLi, NaK,
J. Chem. Phys., 1977, 67, 4603. [all data]
Simmons, Lowden, et al., 1977
Simmons, L.L.; Lowden, L.F.; Ehlert, T.C.,
A mass spectrometric study of K2CO3 and K2O,
J. Phys. Chem., 1977, 81, 706. [all data]
Williams and Potts, 1976
Williams, T.A.; Potts, A.W.,
Complexities in the HeI photoelectron spectra of alkali metal vapours,
J. Electron Spectrosc. Relat. Phenom., 1976, 8, 331. [all data]
Moore, 1970
Moore, C.E.,
Ionization potentials and ionization limits derived from the analyses of optical spectra,
Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]
Brechignac, Cahuzac, et al., 1990
Brechignac, C.; Cahuzac, P.; Carlier, F.; De Frutos, M.; Leyniger, J.,
Cohesive Energies of (K)n+ 5<n<200 from Photoevaporation Experiments,
J. Chem. Phys., 1990, 93, 10, 7449, https://doi.org/10.1063/1.459418
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.