nickel


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Ni+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.6398eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)176.kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity170.7kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
1.160 ± 0.050LPESLiu, Zhai, et al., 2002B
1.15717 ± 0.00013N/AScheer, Brodie, et al., 1998B
1.157 ± 0.010LPESCorderman, Engelking, et al., 1979B

Ionization energy determinations

IE (eV) Method Reference Comment
7.6398EVALLide, 1992LL
7.6398LSPage and Gudeman, 1990LL
7.638SKelly, 1987LBLHLM
7.6374 ± 0.0012SSugar and Corliss, 1985LBLHLM
7.61PEDyke, Gravenor, et al., 1982LBLHLM
7.6 ± 0.2EIClements and Sale, 1976LLK
7.635SMoore, 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Liu, Zhai, et al., 2002
Liu, S.R.; Zhai, H.J.; Wang, L.S., Evolution of the electronic properties of small Ni-n(-) (n=1- 100) clusters by photoelectron spectroscopy, J. Chem. Phys., 2002, 117, 21, 9758-9765, https://doi.org/10.1063/1.1519008 . [all data]

Scheer, Brodie, et al., 1998
Scheer, M.; Brodie, C.A.; Bilodeau, R.C.; Haugen, H.K., Laser spectroscopic measurements of binding energies and fine-structure splittings of Co-, Ni-, Rh-, and Pd-, Phys. Rev. A, 1998, 58, 3, 2051-2062, https://doi.org/10.1103/PhysRevA.58.2051 . [all data]

Corderman, Engelking, et al., 1979
Corderman, R.R.; Engelking, P.C.; Lineberger, W.C., Laser photoelectron spectrometry of Co- and Ni-, J. Chem. Phys., 1979, 70, 4474. [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Page and Gudeman, 1990
Page, R.H.; Gudeman, C.S., Completing the iron period: Double-resonance, fluorescence-dip rydberg spectroscopy and ionization potentials of titanium, vanadium, iron, cobalt, and nickel, J. Opt. Soc. Am. B, 1990, 1761. [all data]

Kelly, 1987
Kelly, R.L., Atomic and ionic spectrum lines of hydrogen through kryton, J. Phys. Chem. Ref. Data, 1987, 16. [all data]

Sugar and Corliss, 1985
Sugar, J.; Corliss, C., Atomic energy levels of the iron period elements: Potassium through nickel, J. Phys. Chem. Ref. Data, 1985, 14. [all data]

Dyke, Gravenor, et al., 1982
Dyke, J.M.; Gravenor, B.W.J.; Lewis, R.A.; Morris, A., Gas-phase high temperature photoelectron spectroscopy: An investigation of the transition metals iron, cobalt, and nickel, J. Phys. B:, 1982, 15, 4523. [all data]

Clements and Sale, 1976
Clements, P.J.; Sale, F.R., A mass spectrometric study of nickel tetracarbonyl, iron pentacarbonyl and binary mixtures of these compounds, Metall. Trans. B:, 1976, 7, 171. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]


Notes

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