1,3,5-C6H3Cl2F+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 17205 ± 10 gas B-X 555 710 Maier, Marthaler, et al., 1980
To = 17073 Ne B-X 540 650 Bondybey, Vaughn, et al., 1981
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1561 Ne LF Bondybey, Vaughn, et al., 1981
1548 Ne LF Bondybey, Vaughn, et al., 1981
1064 Ne LF Bondybey, Vaughn, et al., 1981
992 Ne LF Bondybey, Vaughn, et al., 1981
973 Ne LF Bondybey, Vaughn, et al., 1981
843 Ne LF Bondybey, Vaughn, et al., 1981
680 Ne LF Bondybey, Vaughn, et al., 1981
513 Ne LF Bondybey, Vaughn, et al., 1981
421 Ne LF Bondybey, Vaughn, et al., 1981
402 Ne LF Bondybey, Vaughn, et al., 1981
373 Ne LF Bondybey, Vaughn, et al., 1981
192 Ne LF Bondybey, Vaughn, et al., 1981

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1747 T Ne LF Bondybey, Vaughn, et al., 1981
1680 T Ne LF Bondybey, Vaughn, et al., 1981
1306 Ne LF Bondybey, Vaughn, et al., 1981
1289 Ne LF Bondybey, Vaughn, et al., 1981
1107 Ne LF Bondybey, Vaughn, et al., 1981
1101 Ne LF Bondybey, Vaughn, et al., 1981
1062 Ne LF Bondybey, Vaughn, et al., 1981
999 Ne LF Bondybey, Vaughn, et al., 1981
973 Ne LF Bondybey, Vaughn, et al., 1981
961 Ne LF Bondybey, Vaughn, et al., 1981
783 Ne LF Bondybey, Vaughn, et al., 1981
543 Ne LF Bondybey, Vaughn, et al., 1981
529 Ne LF Bondybey, Vaughn, et al., 1981
450 Ne LF Bondybey, Vaughn, et al., 1981
437 Ne LF Bondybey, Vaughn, et al., 1981
422 Ne LF Bondybey, Vaughn, et al., 1981
333 Ne LF Bondybey, Vaughn, et al., 1981
201 Ne LF Bondybey, Vaughn, et al., 1981

Additional references: Jacox, 1994, page 434

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Marthaler, et al., 1980
Maier, J.P.; Marthaler, O.; Mohraz, M.; Shiley, R.H., (π-1) → (π-1), (π-1) emission spectra of chlorofluorobenzene cations in the gaseous phase and their lifetimes in the (0o) states, Chem. Phys., 1980, 47, 3, 295, https://doi.org/10.1016/0301-0104(80)85015-4 . [all data]

Bondybey, Vaughn, et al., 1981
Bondybey, V.E.; Vaughn, C.R.; Miller, T.A.; English, J.H.; Shiley, R.H., Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution, J. Chem. Phys., 1981, 74, 12, 6584, https://doi.org/10.1063/1.441120 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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