C6F5Cl+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19990 ± 10 gas B-X 485 625 Maier, Marthaler, et al., 1980
To = 19914 Ne B-X 450 525 Bondybey, Miller, et al., 1980
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 7 583 Ne LF Bondybey, Miller, et al., 1980
8 507 Ne LF Bondybey, Miller, et al., 1980
9 387 Ne LF Bondybey, Miller, et al., 1980
11 268 Ne LF Bondybey, Miller, et al., 1980

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
590 Ne LF Bondybey, Miller, et al., 1980
512 Ne LF Bondybey, Miller, et al., 1980
385 Ne LF Bondybey, Miller, et al., 1980
252 Ne LF Bondybey, Miller, et al., 1980
185 T Ne LF Bondybey, Miller, et al., 1980
Maier, Marthaler, et al., 1980

Additional references: Jacox, 1994, page 439; Bondybey, Vaughn, et al., 1981

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Marthaler, et al., 1980
Maier, J.P.; Marthaler, O.; Mohraz, M.; Shiley, R.H., (π-1) → (π-1), (π-1) emission spectra of chlorofluorobenzene cations in the gaseous phase and their lifetimes in the (0o) states, Chem. Phys., 1980, 47, 3, 295, https://doi.org/10.1016/0301-0104(80)85015-4 . [all data]

Bondybey, Miller, et al., 1980
Bondybey, V.E.; Miller, T.A.; English, J.H., J. Chim. Phys., 1980, 77, 667. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Bondybey, Vaughn, et al., 1981
Bondybey, V.E.; Vaughn, C.R.; Miller, T.A.; English, J.H.; Shiley, R.H., Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution, J. Chem. Phys., 1981, 74, 12, 6584, https://doi.org/10.1063/1.441120 . [all data]

Notes

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