Glycine, N,N-dimethyl-, methyl ester
- Formula: C5H11NO2
- Molecular weight: 117.1463
- IUPAC Standard InChI: InChI=1S/C5H11NO2/c1-6(2)4-5(7)8-3/h4H2,1-3H3
- IUPAC Standard InChIKey: LRZFEBJUJIQVDQ-UHFFFAOYSA-N
- CAS Registry Number: 7148-06-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methyl (dimethylamino) acetate; N,N-Dimethylglycine methyl ester; (CH3)2NCH2COOCH3
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -88.53 ± 0.19 | kcal/mol | Ccb | Verevkin, Beckhaus, et al., 1992 |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 10.50 ± 0.11 | kcal/mol | V | Verevkin, Beckhaus, et al., 1992 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.96 ± 0.03 | PI | Loguinov, Takhistov, et al., 1981 | LLK |
| 7.96 ± 0.05 | PE | Akopyan and Loginov, 1974 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C3H8N+ | 8.62 ± 0.05 | CH3OCO | PI | Loguinov, Takhistov, et al., 1981 | LLK |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Verevkin, Beckhaus, et al., 1992
Verevkin, S.P.; Beckhaus, H.-D.; Ruchardt, C.,
Geminale substituenteneffekte Teil 5α. Standardbildungsenthalpien von alkylsubstituierten Malonsaure- und α-aminocarbonsaureestern,
Thermochim. Acta, 1992, 197, 27-39. [all data]
Loguinov, Takhistov, et al., 1981
Loguinov, Y.; Takhistov, V.V.; Vatlina, L.P.,
Photoionization studies of substituted trimethylamines,
Org. Mass Spectrom., 1981, 16, 239. [all data]
Akopyan and Loginov, 1974
Akopyan, M.E.; Loginov, Yu.V.,
Photoelectron spectra of trimethylamine derivatives,
Opt. Spectrosc., 1974, 37, 250, In original 442. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔfH°gas Enthalpy of formation of gas at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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