1-Butanol
- Formula: C4H10O
- Molecular weight: 74.1216
- IUPAC Standard InChIKey: LRHPLDYGYMQRHN-UHFFFAOYSA-N
- CAS Registry Number: 71-36-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Butyl alcohol; n-Butan-1-ol; n-Butanol; n-Butyl alcohol; Butyl hydroxide; CCS 203; Hemostyp; Methylolpropane; Propylcarbinol; n-C4H9OH; Butanol; Butan-1-ol; 1-Hydroxybutane; Alcool butylique; Butanolo; Butylowy alkohol; Butyric alcohol; Propylmethanol; Butanolen; 1-Butyl alcohol; Rcra waste number U031; Butanol-1; NSC 62782
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Phase change data
Go To: Top, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 390.6 ± 0.8 | K | AVG | N/A | Average of 137 out of 146 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 188. ± 9. | K | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 184.54 | K | N/A | Wilhoit, Chao, et al., 1985 | Uncertainty assigned by TRC = 0.02 K; TRC |
Ttriple | 184.51 | K | N/A | Counsell, Hales, et al., 1965 | Uncertainty assigned by TRC = 0.05 K; TRC |
Ttriple | 183.9 | K | N/A | Parks, 1925 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 562. ± 2. | K | AVG | N/A | Average of 21 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 45. ± 4. | bar | AVG | N/A | Average of 10 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.274 | l/mol | N/A | Gude and Teja, 1995 | |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 3.65 ± 0.06 | mol/l | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 52. ± 3. | kJ/mol | AVG | N/A | Average of 15 out of 16 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
43.29 | 390.9 | N/A | Majer and Svoboda, 1985 | |
46.0 | 372. | EB | Muñoz and Krähenbühl, 2001 | Based on data from 357. to 389. K.; AC |
38.2 | 423. | N/A | Wormald and Fennell, 2000 | AC |
29.6 | 473. | N/A | Wormald and Fennell, 2000 | AC |
20.8 | 523. | N/A | Wormald and Fennell, 2000 | AC |
49.9 | 330. | N/A | Dejoz, Cruz Burguet, et al., 1995 | Based on data from 315. to 390. K.; AC |
45.3 | 379. | N/A | Susial and Ortega, 1993 | Based on data from 364. to 403. K.; AC |
45.3 | 387. | A | Stephenson and Malanowski, 1987 | Based on data from 376. to 399. K.; AC |
50.1 | 338. | A | Stephenson and Malanowski, 1987 | Based on data from 323. to 413. K.; AC |
41.9 | 428. | A | Stephenson and Malanowski, 1987 | Based on data from 413. to 550. K.; AC |
51.6 | 236. | A | Stephenson and Malanowski, 1987 | Based on data from 209. to 251. K.; AC |
45.4 | 386. | A | Stephenson and Malanowski, 1987 | Based on data from 376. to 397. K.; AC |
43.8 | 406. | A | Stephenson and Malanowski, 1987 | Based on data from 391. to 429. K.; AC |
41.9 | 430. | A | Stephenson and Malanowski, 1987 | Based on data from 415. to 501. K.; AC |
37.4 | 512. | A | Stephenson and Malanowski, 1987 | Based on data from 497. to 563. K.; AC |
47.2 | 366. | EB | Stephenson and Malanowski, 1987 | Based on data from 351. to 397. K. See also Ambrose, Counsell, et al., 1970.; AC |
49.0 | 344. | N/A | Sachek, Peshchenko, et al., 1982 | Based on data from 329. to 391. K.; AC |
49.5 ± 0.1 | 333. | C | Svoboda, Veselý, et al., 1973 | AC |
48.6 ± 0.1 | 343. | C | Svoboda, Veselý, et al., 1973 | AC |
47.5 ± 0.1 | 353. | C | Svoboda, Veselý, et al., 1973 | AC |
46.4 ± 0.1 | 363. | C | Svoboda, Veselý, et al., 1973 | AC |
55.0 | 303. | N/A | Wilhoit and Zwolinski, 1973 | Based on data from 288. to 404. K.; AC |
53.0 | 310. | DTA | Kemme and Kreps, 1969 | Based on data from 295. to 391. K.; AC |
47.2 ± 0.1 | 356. | C | Counsell, Hales, et al., 1965 | AC |
45.4 ± 0.1 | 381. | C | Counsell, Hales, et al., 1965 | AC |
43.1 ± 0.1 | 391. | C | Counsell, Hales, et al., 1965 | AC |
42.1 | 434. | N/A | Ambrose and Townsend, 1963 | Based on data from 419. to 563. K.; AC |
46.6 | 377. | EB | Biddiscombe, Collerson, et al., 1963 | Based on data from 362. to 398. K.; AC |
48.3 | 352. | N/A | Brown and Smith, 1959 | Based on data from 337. to 390. K. See also Boublik, Fried, et al., 1984.; AC |
48.3 | 352. | N/A | Kahlbaum, 1898 | Based on data from 314. to 390. K. See also Boublik, Fried, et al., 1984.; AC |
Enthalpy of vaporization
ΔvapH = A exp(-αTr)
(1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | 298. to 410. |
---|---|
A (kJ/mol) | 62.53 |
α | -0.6584 |
β | 0.696 |
Tc (K) | 562.9 |
Reference | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
295.8 to 391.0 | 4.54607 | 1351.555 | -93.34 | Kemme and Kreps, 1969 | |
391. to 479. | 4.39031 | 1254.502 | -105.246 | Hessel and Geiseler, 1965 | Coefficents calculated by NIST from author's data. |
419.34 to 562.98 | 4.42921 | 1305.001 | -94.676 | Ambrose and Townsend, 1963, 2 | Coefficents calculated by NIST from author's data. |
362.36 to 398.84 | 4.50393 | 1313.878 | -98.789 | Biddiscombe, Collerson, et al., 1963, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
9.372 | 184.5 | Counsell, Hales, et al., 1965, 2 | DH |
9.28 | 183.9 | Acree, 1991 | AC |
9.280 | 183.9 | Parks, 1925, 2 | DH |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
50.79 | 184.5 | Counsell, Hales, et al., 1965, 2 | DH |
50.46 | 183.9 | Parks, 1925, 2 | DH |
Gas phase ion energetics data
Go To: Top, Phase change data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 9.99 ± 0.05 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 789.2 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 758.9 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.10 ± 0.05 | EI | Holmes and Lossing, 1991 | LL |
9.99 ± 0.05 | PIPECO | Shao, Baer, et al., 1988 | LL |
10.64 ± 0.07 | EI | Bowen and Maccoll, 1984 | LBLHLM |
10.09 ± 0.02 | PE | Cocksey, Eland, et al., 1971 | LLK |
10.37 | PE | Baker, Betteridge, et al., 1971 | LLK |
10.37 | PE | Baker, Betteridge, et al., 1971 | LLK |
10.04 | PI | Watanabe, Nakayama, et al., 1962 | RDSH |
10.43 | PE | Benoit and Harrison, 1977 | Vertical value; LLK |
10.44 ± 0.03 | PE | Peel and Willett, 1975 | Vertical value; LLK |
10.37 | PE | Katsumata, Iwai, et al., 1973 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CH3O+ | 11.36 ± 0.06 | n-C3H7 | EI | Selim and Helal, 1981 | LLK |
CH3O+ | 11.46 | ? | EI | Lambdin, Tuffly, et al., 1959 | RDSH |
C2H2O+ | 11.23 | ? | EI | Lambdin, Tuffly, et al., 1959 | RDSH |
C4H8+ | 10.18 ± 0.05 | H2O | PIPECO | Shao, Baer, et al., 1988 | LL |
C4H8+ | 10.20 ± 0.10 | H2O | EI | Bowen and Maccoll, 1984 | LBLHLM |
De-protonation reactions
C4H9O- + =
By formula: C4H9O- + H+ = C4H10O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1570. ± 8.4 | kJ/mol | CIDC | Haas and Harrison, 1993 | gas phase; Both metastable and 50 eV collision energy.; B |
ΔrH° | 1571. ± 8.8 | kJ/mol | G+TS | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrH° | 1569. ± 12. | kJ/mol | G+TS | Boand, Houriet, et al., 1983 | gas phase; value altered from reference due to change in acidity scale; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1543. ± 8.8 | kJ/mol | H-TS | Haas and Harrison, 1993 | gas phase; Both metastable and 50 eV collision energy.; B |
ΔrG° | 1543. ± 8.4 | kJ/mol | IMRE | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrG° | 1541. ± 12. | kJ/mol | CIDC | Boand, Houriet, et al., 1983 | gas phase; value altered from reference due to change in acidity scale; B |
Ion clustering data
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: CH6N+ + C4H10O = (CH6N+ • C4H10O)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 98.3 | kJ/mol | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | N/A | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.4 | 495. | PHPMS | Meot-Ner, 1984 | gas phase; Entropy change calculated or estimated; M |
By formula: C3H9Si+ + C4H10O = (C3H9Si+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 185. | kJ/mol | PHPMS | Wojtyniak and Stone, 1986 | gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 130. | J/mol*K | N/A | Wojtyniak and Stone, 1986 | gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
124. | 468. | PHPMS | Wojtyniak and Stone, 1986 | gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M |
By formula: C3H9Sn+ + C4H10O = (C3H9Sn+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 153. | kJ/mol | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 136. | J/mol*K | N/A | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
81.6 | 525. | PHPMS | Stone and Splinter, 1984 | gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M |
By formula: C4H11O+ + C4H10O = (C4H11O+ • C4H10O)
Bond type: Hydrogen bonds of the type OH-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 132. | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 129. | J/mol*K | N/A | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 93.3 | kJ/mol | ICR | Larson and McMahon, 1982 | gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984; M |
By formula: C6H5S- + C4H10O = (C6H5S- • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 61.1 | kJ/mol | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 105. | J/mol*K | PHPMS | Sieck and Meot-ner, 1989 | gas phase; M |
By formula: Cl- + C4H10O = (Cl- • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 73.6 ± 8.4 | kJ/mol | IMRE | Larson and McMahon, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 97.1 | J/mol*K | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)CH3OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 44.8 ± 8.4 | kJ/mol | IMRE | Larson and McMahon, 1984 | gas phase; B,M |
+
= C4H9D10FO-
By formula: F- + C4H10O = C4H9D10FO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 101. ± 8.4 | kJ/mol | IMRE | Wilkinson, Szulejko, et al., 1992 | gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B |
By formula: F- + C4H10O = (F- • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 135. ± 8.4 | kJ/mol | IMRE | Larson and McMahon, 1983 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 108. | J/mol*K | N/A | Larson and McMahon, 1983 | gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 103. ± 8.4 | kJ/mol | IMRE | Larson and McMahon, 1983 | gas phase; B,M |
By formula: Li+ + C4H10O = (Li+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 178. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Mg+ + C4H10O = (Mg+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 270. ± 20. | kJ/mol | ICR | Operti, Tews, et al., 1988 | gas phase; switching reaction,Thermochemical ladder(Mg+)CH3OH; M |
By formula: Na+ + C4H10O = (Na+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 109. ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 1999 | RCD |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
82.4 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wilhoit, Chao, et al., 1985
Wilhoit, R.C.; Chao, J.; Hall, K.R.,
Thermodynamic Properties of Key Organic Compounds in the Carbon Range C1 to C4. Part 1. Properties of Condensed Phases,
J. Phys. Chem. Ref. Data, 1985, 14, 1. [all data]
Counsell, Hales, et al., 1965
Counsell, J.F.; Hales, J.L.; Martin, J.F.,
Thermodynamic properties of organic oxygen compounds. Part 16.?Butyl alcohol,
Trans. Faraday Soc., 1965, 61, 1869, https://doi.org/10.1039/tf9656101869
. [all data]
Parks, 1925
Parks, G.S.,
Thermal data on organic compounds: I the heat capacities and free energies of methyl, ethyl and n-butyl alcohol,
J. Am. Chem. Soc., 1925, 47, 338-45. [all data]
Gude and Teja, 1995
Gude, M.; Teja, A.S.,
Vapor-Liquid Critical Properties of Elements and Compounds. 4. Aliphatic Alkanols,
J. Chem. Eng. Data, 1995, 40, 1025-1036. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Muñoz and Krähenbühl, 2001
Muñoz, Laura A.L.; Krähenbühl, M. Alvina,
Isobaric Vapor Liquid Equilibrium (VLE) Data of the Systems n -Butanol + Butyric Acid and n -Butanol + Acetic Acid,
J. Chem. Eng. Data, 2001, 46, 1, 120-124, https://doi.org/10.1021/je000033u
. [all data]
Wormald and Fennell, 2000
Wormald, C.J.; Fennell, D.P.,
Organometallics, 2000, 21, 3, 767-779, https://doi.org/10.1023/A:1006648903706
. [all data]
Dejoz, Cruz Burguet, et al., 1995
Dejoz, Ana; Cruz Burguet, M.; Munoz, Rosa; Sanchotello, Margarita,
Isobaric Vapor-Liquid Equilibria of Tetrachloroethylene with 1-Butanol and 2-Butanol at 6 and 20 kPa,
J. Chem. Eng. Data, 1995, 40, 1, 290-292, https://doi.org/10.1021/je00017a064
. [all data]
Susial and Ortega, 1993
Susial, Pedro; Ortega, Juan,
Isobaric vapor-liquid equilibria in the system methyl propanoate + n-butyl alcohol,
J. Chem. Eng. Data, 1993, 38, 4, 647-649, https://doi.org/10.1021/je00012a044
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Ambrose, Counsell, et al., 1970
Ambrose, D.; Counsell, J.F.; Davenport, A.J.,
The use of Chebyshev polynomials for the representation of vapour pressures between the triple point and the critical point,
The Journal of Chemical Thermodynamics, 1970, 2, 2, 283-294, https://doi.org/10.1016/0021-9614(70)90093-5
. [all data]
Sachek, Peshchenko, et al., 1982
Sachek, A.I.; Peshchenko, A.D.; Markovnik, V.S.; Ral'ko, O.V.; Andreevskii, D.N.; Leont'eva, A.A.,
Termodin. Org. Soedin., 1982, 94. [all data]
Svoboda, Veselý, et al., 1973
Svoboda, V.; Veselý, F.; Holub, R.; Pick, J.,
Enthalpy data of liquids. II. The dependence of heats of vaporization of methanol, propanol, butanol, cyclohexane, cyclohexene, and benzene on temperature,
Collect. Czech. Chem. Commun., 1973, 38, 12, 3539-3543, https://doi.org/10.1135/cccc19733539
. [all data]
Wilhoit and Zwolinski, 1973
Wilhoit, R.C.; Zwolinski, B.J.,
Physical and thermodynamic properties of aliphatic alcohols,
J. Phys. Chem. Ref. Data Suppl., 1973, 1, 2, 1. [all data]
Kemme and Kreps, 1969
Kemme, Herbert R.; Kreps, Saul I.,
Vapor pressure of primary n-alkyl chlorides and alcohols,
J. Chem. Eng. Data, 1969, 14, 1, 98-102, https://doi.org/10.1021/je60040a011
. [all data]
Ambrose and Townsend, 1963
Ambrose, D.; Townsend, R.,
681. Thermodynamic properties of organic oxygen compounds. Part IX. The critical properties and vapour pressures, above five atmospheres, of six aliphatic alcohols,
J. Chem. Soc., 1963, 3614, https://doi.org/10.1039/jr9630003614
. [all data]
Biddiscombe, Collerson, et al., 1963
Biddiscombe, D.P.; Collerson, R.R.; Handley, R.; Herington, E.F.G.; Martin, J.F.; Sprake, C.H.S.,
364. Thermodynamic properties of organic oxygen compounds. Part VIII. Purification and vapour pressures of the propyl and butyl alcohols,
J. Chem. Soc., 1963, 1954, https://doi.org/10.1039/jr9630001954
. [all data]
Brown and Smith, 1959
Brown, I.; Smith, F.,
Liquid-Vapour Equilibria. IX. The Systems n-Propanol + Benzene and n-Butanol + Benzene at 45°C,
Aust. J. Chem., 1959, 12, 3, 407-621, https://doi.org/10.1071/CH9590407
. [all data]
Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E.,
The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]
Kahlbaum, 1898
Kahlbaum, G.W.A.,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1898, 26, 577. [all data]
Hessel and Geiseler, 1965
Hessel, D.; Geiseler, G.,
Uber die Druckabhangigkeit des heteroazeotropen Systems n-Butanol/Wasser,
Z. Phys. Chem. (Leipzig), 1965, 229, 199-209. [all data]
Ambrose and Townsend, 1963, 2
Ambrose, D.; Townsend, R.,
Thermodynamic Properties of Organic Oxygen Compounds. Part 9. The Critical Properties and Vapour Pressures, above Five Atmospheres, of Six Aliphatic Alcohols,
J. Chem. Soc., 1963, 3614-3625, https://doi.org/10.1039/jr9630003614
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Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy Pc Critical pressure T Temperature Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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