1-Propanol
- Formula: C3H8O
- Molecular weight: 60.0950
- IUPAC Standard InChIKey: BDERNNFJNOPAEC-UHFFFAOYSA-N
- CAS Registry Number: 71-23-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Propyl alcohol; n-Propan-1-ol; n-Propanol; n-Propyl alcohol; Ethylcarbinol; Optal; Osmosol extra; Propanol; Propylic alcohol; 1-Propyl alcohol; n-C3H7OH; 1-Hydroxypropane; Propanol-1; Propan-1-ol; n-Propyl alkohol; Alcool propilico; Alcool propylique; Propanole; Propanolen; Propanoli; Propylowy alkohol; UN 1274; Propylan-propyl alcohol; NSC 30300; Alcohol, propyl
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -61.2 ± 0.7 | kcal/mol | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
S°gas | 77.077 | cal/mol*K | N/A | Chao J., 1986 | Other values based on low-temperature thermal measurements are: 321.6 [ Buckley E., 1967], 321.7 [ Counsell J.F., 1968], 322.59 [ Green J.H.S., 1961], 323.42 [ Chermin H.A.G., 1961], and 324.72 J/mol*K [ Wilhoit R.C., 1973].; GT |
Constant pressure heat capacity of gas
Cp,gas (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
9.699 | 50. | Thermodynamics Research Center, 1997 | p=1 bar. Discrepancies with other statistically calculated S(T) and Cp(T) values [ Green J.H.S., 1961, Mathews J.F., 1961, Chao J., 1986, 2], [ Chermin H.A.G., 1961], and [ Kobe K.A., 1951, Zhuravlev E.Z., 1959] amount up to 2.5, 4, and 7 J/mol*K, respectively. Please also see Chao J., 1986.; GT |
12.32 | 100. | ||
14.08 | 150. | ||
15.86 | 200. | ||
19.17 | 273.15 | ||
20.45 ± 0.033 | 298.15 | ||
20.54 | 300. | ||
25.820 | 400. | ||
30.638 | 500. | ||
34.754 | 600. | ||
38.253 | 700. | ||
41.257 | 800. | ||
43.860 | 900. | ||
46.121 | 1000. | ||
48.093 | 1100. | ||
49.809 | 1200. | ||
51.307 | 1300. | ||
52.615 | 1400. | ||
53.760 | 1500. | ||
56.05 | 1750. | ||
57.70 | 2000. | ||
58.94 | 2250. | ||
59.87 | 2500. | ||
60.7 | 2750. | ||
61.2 | 3000. |
Constant pressure heat capacity of gas
Cp,gas (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
24.441 ± 0.048 | 371.2 | Stromsoe E., 1970 | Ideal gas heat capacities are given by [ Stromsoe E., 1970] as a linear function Cp=f1*(a+bT). This expression approximates the experimental values with the average deviation of 0.96 J/mol*K. The accuracy of the experimental heat capacities [ Stromsoe E., 1970] is estimated as less than 0.3%. Please also see Mathews J.F., 1961.; GT |
25.64 ± 0.23 | 375.45 | ||
25.97 ± 0.23 | 383.05 | ||
26.15 ± 0.23 | 387.15 | ||
25.440 ± 0.050 | 391.2 | ||
26.58 ± 0.23 | 396.95 | ||
27.15 ± 0.23 | 409.95 | ||
26.391 ± 0.053 | 411.2 | ||
27.62 ± 0.23 | 420.75 | ||
27.72 ± 0.23 | 422.95 | ||
27.330 ± 0.055 | 431.2 | ||
28.37 ± 0.23 | 437.95 | ||
28.351 ± 0.057 | 451.2 | ||
29.38 ± 0.23 | 461.05 | ||
30.01 ± 0.23 | 475.35 | ||
31.30 ± 0.23 | 504.95 | ||
31.60 ± 0.23 | 511.85 | ||
32.50 ± 0.23 | 532.35 | ||
33.71 ± 0.23 | 560.05 | ||
34.53 ± 0.23 | 578.85 | ||
35.60 ± 0.23 | 603.25 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -72.309 ± 0.060 | kcal/mol | Ccb | Mosselman and Dekker, 1975 | ALS |
ΔfH°liquid | -72.42 ± 0.31 | kcal/mol | Eqk | Connett, 1972 | ALS |
ΔfH°liquid | -72.79 ± 0.09 | kcal/mol | Ccb | Chao and Rossini, 1965 | see Rossini, 1934; ALS |
ΔfH°liquid | -72.3 ± 1.0 | kcal/mol | Ccb | Snelson and Skinner, 1961 | ALS |
ΔfH°liquid | -73.20 ± 0.24 | kcal/mol | Ccb | Green, 1960 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -483.105 ± 0.060 | kcal/mol | Ccb | Mosselman and Dekker, 1975 | Corresponding ΔfHºliquid = -72.309 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -482.64 ± 0.07 | kcal/mol | Ccb | Chao and Rossini, 1965 | see Rossini, 1934; Corresponding ΔfHºliquid = -72.77 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -483.12 ± 0.18 | kcal/mol | Ccb | Snelson and Skinner, 1961 | Corresponding ΔfHºliquid = -72.29 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -482.23 ± 0.24 | kcal/mol | Ccb | Green, 1960 | Corresponding ΔfHºliquid = -73.18 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -485.801 | kcal/mol | Ccb | Richards and Davis, 1920 | At 291 K; Corresponding ΔfHºliquid = -69.613 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 46.08 | cal/mol*K | N/A | Counsell, Lees, et al., 1968 | DH |
S°liquid | 51.20 | cal/mol*K | N/A | Parks and Huffman, 1926 | Extrapolation below 90 K, 64.85 J/mol*K.; DH |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 26.94 | cal/mol*K | N/A | Counsell, Lees, et al., 1968 | glass phase; DH |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
34.56 | 298. | Korolev, Kukharenko, et al., 1986 | DH |
34.407 | 298.15 | Tanaka, Toyama, et al., 1986 | DH |
34.522 | 298.15 | Zegers and Somsen, 1984 | DH |
33.078 | 288.15 | Benson and D'Arcy, 1982 | DH |
35.105 | 298.15 | Villamanan, Casanova, et al., 1982 | DH |
33.89 | 293.15 | Arutyunyan, Bagdasaryan, et al., 1981 | T = 293 to 353 K. p = 0.1 MPa. Unsmoothed experimental datum given as 2.360 kJ/kg*K. Cp given from 293.25 to 533.15 K for pressure range 10 to 60 MPa.; DH |
34.976 | 298.216 | Kalinowska, Jedlinska, et al., 1980 | T = 185 to 300 K. Unsmoothed experimental datum.; DH |
35.35 | 303.4 | Griigo'ev, Yanin, et al., 1979 | T = 303 to 463 K. p = 0.98 bar.; DH |
34.362 | 298.15 | Vesely, Zabransky, et al., 1979 | DH |
35.61 | 298.15 | Murthy and Subrahmanyam, 1977 | DH |
34.364 | 298.15 | Vesely, Svoboda, et al., 1977 | DH |
34.386 | 298.15 | Fortier, Benson, et al., 1976 | DH |
34.4316 | 298.15 | Fortier and Benson, 1976 | DH |
37.91 | 313.2 | Paz Andrade, Paz, et al., 1970 | DH |
34.37 | 298.15 | Counsell, Lees, et al., 1968 | T = 11 to 350 K.; DH |
34.92 | 298. | Recko, 1968 | T = 24 to 40°C, equation only.; DH |
37.19 | 320. | Swietoslawski and Zielenkiewicz, 1960 | Mean value 21 to 74°C.; DH |
33.511 | 303. | Eucken and Eigen, 1951 | T = 303 to 393 K.; DH |
34.80 | 298.1 | Zhdanov, 1941 | T = 5 to 46°C.; DH |
39.39 | 301.2 | Phillip, 1939 | DH |
32.50 | 270. | Mitsukuri and Hara, 1929 | T = 170 to 270 K.; DH |
46.10 | 298.1 | Parks, Kelley, et al., 1929 | Extrapolation below 90 K, 43.5 J/mol*K. Revision of previous data.; DH |
31.91 | 275.4 | Parks and Huffman, 1927 | T = 86 to 275 K. Value is unsmoothed experimental datum.; DH |
31.91 | 275.0 | Parks and Huffman, 1926 | T = 86 to 275 K. Value is unsmoothed experimental datum.; DH |
31.38 | 274.6 | Gibson, Parks, et al., 1920 | T = 77 to 274.6 K. Unsmoothed experimental datum.; DH |
34.61 | 298. | von Reis, 1881 | T = 289 to 363 K.; DH |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
25.41 | 150. | Counsell, Lees, et al., 1968 | glass phase; T = 10 to 150 K.; DH |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Henry's Law data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 370.3 ± 0.5 | K | AVG | N/A | Average of 127 out of 139 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 146.7 | K | N/A | Tschamler, Richter, et al., 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
Tfus | 147. | K | N/A | Timmermans, 1935 | Uncertainty assigned by TRC = 3. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 148.75 | K | N/A | Wilhoit, Chao, et al., 1985 | Uncertainty assigned by TRC = 0.02 K; TRC |
Ttriple | 148.75 | K | N/A | Counsell, Lees, et al., 1968, 2 | Uncertainty assigned by TRC = 0.02 K; TRC |
Ttriple | 147.0 | K | N/A | Parks and Huffman, 1926, 2 | Uncertainty assigned by TRC = 0.3 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 536.9 ± 0.8 | K | AVG | N/A | Average of 20 out of 25 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 51. ± 1. | atm | AVG | N/A | Average of 12 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.218 | l/mol | N/A | Gude and Teja, 1995 | |
Vc | 0.216 | l/mol | N/A | Zawisza and Vejrosta, 1982 | Uncertainty assigned by TRC = 0.001 l/mol; Visual; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 4.58 ± 0.06 | mol/l | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 11.3 ± 0.4 | kcal/mol | AVG | N/A | Average of 15 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
9.904 | 370.3 | N/A | Majer and Svoboda, 1985 | |
9.85 | 371. | N/A | Wormald and Vine, 2000 | AC |
8.41 | 423. | N/A | Wormald and Vine, 2000 | AC |
7.03 | 453. | N/A | Wormald and Vine, 2000 | AC |
5.02 | 498. | N/A | Wormald and Vine, 2000 | AC |
2.72 | 528. | N/A | Wormald and Vine, 2000 | AC |
11.2 | 318. | N/A | Aucejo, Gonzalez-Alfaro, et al., 1995 | Based on data from 303. to 370. K.; AC |
10.3 | 375. | N/A | Ortega, Susial, et al., 1990 | Based on data from 360. to 377. K.; AC |
11.5 | 214. | A | Stephenson and Malanowski, 1987 | Based on data from 200. to 228. K.; AC |
10.4 | 366. | A | Stephenson and Malanowski, 1987 | Based on data from 356. to 376. K.; AC |
10.1 | 384. | A | Stephenson and Malanowski, 1987 | Based on data from 369. to 407. K.; AC |
9.58 | 416. | A | Stephenson and Malanowski, 1987 | Based on data from 401. to 482. K.; AC |
8.72 | 492. | A | Stephenson and Malanowski, 1987 | Based on data from 478. to 507. K.; AC |
11.1 ± 0.02 | 313. | C | Svoboda, Veselý, et al., 1973 | AC |
10.9 ± 0.02 | 323. | C | Svoboda, Veselý, et al., 1973 | AC |
10.7 ± 0.02 | 333. | C | Svoboda, Veselý, et al., 1973 | AC |
10.5 ± 0.02 | 343. | C | Svoboda, Veselý, et al., 1973 | AC |
10.3 ± 0.02 | 353. | C | Svoboda, Veselý, et al., 1973 | AC |
10.1 ± 0.02 | 363. | C | Svoboda, Veselý, et al., 1973 | AC |
11.8 | 290. | N/A | Wilhoit and Zwolinski, 1973 | Based on data from 275. to 373. K.; AC |
10.7 | 348. | EB | Ambrose, Counsell, et al., 1970 | Based on data from 333. to 377. K. See also Stephenson and Malanowski, 1987.; AC |
11.2 | 307. | DTA | Kemme and Kreps, 1969 | Based on data from 292. to 370. K.; AC |
11.2 | 303. | N/A | Van Ness, Soczek, et al., 1967 | Based on data from 288. to 348. K.; AC |
9.73 | 420. | N/A | Ambrose and Townsend, 1963 | Based on data from 405. to 537. K.; AC |
10.6 | 353. | EB | Biddiscombe, Collerson, et al., 1963 | Based on data from 338. to 378. K.; AC |
10.5 | 358. | N/A | Mathews and McKetta, 1961 | Based on data from 343. to 385. K.; AC |
10.5 ± 0.02 | 343. | C | Mathews and McKetta, 1961 | AC |
10.1 ± 0.02 | 360. | C | Mathews and McKetta, 1961 | AC |
9.85 ± 0.02 | 370. | C | Mathews and McKetta, 1961 | AC |
9.63 ± 0.02 | 378. | C | Mathews and McKetta, 1961 | AC |
9.49 ± 0.02 | 384. | C | Mathews and McKetta, 1961 | AC |
10.9 | 321. to 367. | N/A | Aronovich, Kastorskii, et al., 1959 | AC |
10.3 | 354. | N/A | Williamson and Harrison, 1957 | AC |
10.75 ± 0.10 | 333.13 | V | Williamson and Harrison, 1957, 2 | ALS |
Enthalpy of vaporization
ΔvapH = A exp(-αTr)
(1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kcal/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | 298. to 390. |
---|---|
A (kcal/mol) | 12.44 |
α | -0.8386 |
β | 0.6888 |
Tc (K) | 536.7 |
Reference | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
333.32 to 377.72 | 4.87030 | 1441.629 | -74.299 | Ambrose and Sprake, 1970 | Coefficents calculated by NIST from author's data. |
292.4 to 370.5 | 5.30813 | 1690.864 | -51.804 | Kemme and Kreps, 1969 | |
405.46 to 536.71 | 4.59300 | 1300.491 | -86.364 | Ambrose and Townsend, 1963, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
1.284 | 148.75 | Counsell, Lees, et al., 1968 | DH |
1.3 | 148.7 | van Miltenburg and van den Berg, 2004 | AC |
1.28 | 148.8 | Counsell, Lees, et al., 1968, 2 | AC |
1.241 | 147.0 | Parks and Huffman, 1926 | DH |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
8.630 | 148.75 | Counsell, Lees, et al., 1968 | DH |
8.44 | 147.0 | Parks and Huffman, 1926 | DH |
Henry's Law data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
110. | Q | N/A | missing citation give several references for the Henry's law constants but don't assign them to specific species. | |
130. | 7500. | M | N/A | |
150. | C | N/A | ||
160. | M | N/A | ||
140. | M | Butler, Ramchandani, et al., 1935 | This paper supersedes earlier work with more concentrated solutions Butler, Thomson, et al., 1933. |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman
View reactions leading to C3H8O+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 10.22 ± 0.06 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 188.0 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 180.7 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.22 ± 0.07 | EI | Bowen and Maccoll, 1984 | LBLHLM |
10.0 | EI | McLafferty, Bente, et al., 1973 | LLK |
10.15 ± 0.025 | PE | Johnstone and Mellon, 1972 | LLK |
10.16 ± 0.03 | EI | Johnstone and Mellon, 1972 | LLK |
10.32 ± 0.02 | PE | Cocksey, Eland, et al., 1971 | LLK |
10.25 | PE | Dewar and Worley, 1969 | RDSH |
10.22 ± 0.04 | PI | Refaey and Chupka, 1968 | RDSH |
10.20 | PI | Watanabe, Nakayama, et al., 1962 | RDSH |
10.51 | PE | Benoit and Harrison, 1977 | Vertical value; LLK |
10.52 ± 0.03 | PE | Peel and Willett, 1975 | Vertical value; LLK |
10.51 | PE | Robin and Kuebler, 1973 | Vertical value; LLK |
10.49 | PE | Katsumata, Iwai, et al., 1973 | Vertical value; LLK |
10.48 | PE | Baker, Betteridge, et al., 1971 | Vertical value; LLK |
Appearance energy determinations
De-protonation reactions
C3H7O- + =
By formula: C3H7O- + H+ = C3H8O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 375.7 ± 1.3 | kcal/mol | D-EA | Ellison, Engleking, et al., 1982 | gas phase; B |
ΔrH° | 376.0 ± 2.1 | kcal/mol | G+TS | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrH° | 376.2 ± 2.0 | kcal/mol | CIDC | Haas and Harrison, 1993 | gas phase; Both metastable and 50 eV collision energy.; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 369.2 ± 1.4 | kcal/mol | H-TS | Ellison, Engleking, et al., 1982 | gas phase; B |
ΔrG° | 369.4 ± 2.0 | kcal/mol | IMRE | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrG° | 369.6 ± 2.1 | kcal/mol | H-TS | Haas and Harrison, 1993 | gas phase; Both metastable and 50 eV collision energy.; B |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chao J., 1986
Chao J.,
Thermodynamic properties of key organic oxygen compounds in the carbon range C1 to C4. Part 2. Ideal gas properties,
J. Phys. Chem. Ref. Data, 1986, 15, 1369-1436. [all data]
Buckley E., 1967
Buckley E.,
Chemical equilibria. Part 2. Dehydrogenation of propanol and butanol,
Trans. Faraday Soc., 1967, 63, 895-901. [all data]
Counsell J.F., 1968
Counsell J.F.,
Thermodynamic properties of organic oxygen compounds. Part XIX. Low-temperature heat capacity and entropy of propan-1-ol, 2-methylpropan-1-ol, and pentan-1-ol,
J. Chem. Soc. A, 1968, 1819-1823. [all data]
Green J.H.S., 1961
Green J.H.S.,
Thermodynamic properties of the normal alcohols C1-C12,
J. Appl. Chem., 1961, 11, 397-404. [all data]
Chermin H.A.G., 1961
Chermin H.A.G.,
Thermo data for petrochemicals. Part 28. Gaseous normal alcohols. The important thermo properties are presented for all the gaseous normal alcohols from methanol through n-decanol,
Petrol. Refiner, 1961, 40 (4), 127-130. [all data]
Wilhoit R.C., 1973
Wilhoit R.C.,
Physical and thermodynamic properties of aliphatic alcohols,
J. Phys. Chem. Ref. Data, 1973, 2, Suppl. 1, 1-420. [all data]
Thermodynamics Research Center, 1997
Thermodynamics Research Center,
Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]
Mathews J.F., 1961
Mathews J.F.,
The thermodynamic properties of the n-propyl alcohol,
J. Phys. Chem., 1961, 65, 758-762. [all data]
Chao J., 1986, 2
Chao J.,
Ideal gas thermodynamic properties of simple alkanols,
Int. J. Thermophys., 1986, 7, 431-442. [all data]
Kobe K.A., 1951
Kobe K.A.,
Thermochemistry for the petrochemical industry. Part XVII. Some C3 oxygenated hydrocarbons,
Petrol. Refiner, 1951, 30 (8), 119-122. [all data]
Zhuravlev E.Z., 1959
Zhuravlev E.Z.,
Isotopic effect on thermodynamic functions of some organic deuterocompounds in the ideal gas state,
Tr. Khim. i Khim. Tekhnol., 1959, 2, 475-485. [all data]
Stromsoe E., 1970
Stromsoe E.,
Heat capacity of alcohol vapors at atmospheric pressure,
J. Chem. Eng. Data, 1970, 15, 286-290. [all data]
Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H.,
Enthalpies of formation of n-alkan-1-ols,
J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]
Connett, 1972
Connett, J.E.,
Chemical equilibria. 5. Measurement of equilibrium constants for the dehydrogenation of propanol by a vapour flow technique,
J. Chem. Thermodyn., 1972, 4, 233-237. [all data]
Chao and Rossini, 1965
Chao, J.; Rossini, F.D.,
Heats of combustion, formation, and isomerization of nineteen alkanols,
J. Chem. Eng. Data, 1965, 10, 374-379. [all data]
Rossini, 1934
Rossini, F.D.,
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Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy Cp,gas Constant pressure heat capacity of gas Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid IE (evaluated) Recommended ionization energy Pc Critical pressure S°gas Entropy of gas at standard conditions S°liquid Entropy of liquid at standard conditions S°solid,1 bar Entropy of solid at standard conditions (1 bar) Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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