1,2-Benzenediamine, N,N,N',N'-tetramethyl-
- Formula: C10H16N2
- Molecular weight: 164.2474
- IUPAC Standard InChI: InChI=1S/C10H16N2/c1-11(2)9-7-5-6-8-10(9)12(3)4/h5-8H,1-4H3
- IUPAC Standard InChIKey: CJVYYDCBKKKIPD-UHFFFAOYSA-N
- CAS Registry Number: 704-01-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: N,N,N',N'-Tetramethyl-1,2-benzenediamine; N,N,N',N'-Tetramethyl-o-phenylenediamine; o-Phenylenebis(dimethylamine); o-Phenylenediamine, N,N,N',N'-tetramethyl-; N1,N1,N2,N2-Tetramethyl-1,2-benzenediamine; 1,2-Phenylenediamine, N,N,N',N'-tetramethyl-; N,N,N',N'-tetramethylbenzene-1,2-diamine
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Gas phase ion energetics data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Proton affinity (review) | 982.6 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
| Quantity | Value | Units | Method | Reference | Comment |
| Gas basicity | 950.2 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.1 | PE | Nelsen, Grezzo, et al., 1981 | LLK |
| 7.36 | PE | Nelsen, Grezzo, et al., 1981 | Vertical value; LLK |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1246. | Todua, 2011 | 30. m/0.25 mm/0.25 μm, He; Tstart: 60. C; Tend: 270. C |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Nelsen, Grezzo, et al., 1981
Nelsen, S.F.; Grezzo, L.A.; Hollinsed, W.C.,
Effects of structure on the ease of electron removal from o-phenylenediamines. 2. Photoelectron spectra of o-phenylenediamines,
J. Org. Chem., 1981, 46, 283. [all data]
Todua, 2011
Todua, N.G.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
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