Ethyne, difluoro-
- Formula: C2F2
- Molecular weight: 62.0182
- IUPAC Standard InChIKey: BWTZYYGAOGUPFQ-UHFFFAOYSA-N
- CAS Registry Number: 689-99-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Acetylene, difluoro-; Difluoroacetylene; FC≡CF; Difluoroethyne; C2F2
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C2F2+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.18 | PE | Bieri, Schmelzer, et al., 1980 | LLK |
11.18 | PE | Bieri, Heilbronner, et al., 1977 | LLK |
11.4 ± 0.5 | EI | Ehlert, 1969 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bieri, Schmelzer, et al., 1980
Bieri, G.; Schmelzer, A.; Asbrink, L.; Jonsson, M.,
Fluorine and the fluoroderivatives of acetylene and diacetylene studied by 30.4 nm He(II) photoelectron spectroscopy,
Chem. Phys., 1980, 49, 213. [all data]
Bieri, Heilbronner, et al., 1977
Bieri, G.; Heilbronner, E.; Stadelmann, J.-P.; Vogt, J.; von Niessen, W.,
Electronic states of difluoroacetylene, difluorodiacetylene, and perfluoropentadiyne-1,3 radical cations. A photoelectron spectroscopic investigation,
J. Am. Chem. Soc., 1977, 99, 6832. [all data]
Ehlert, 1969
Ehlert, T.C.,
Bonding in C1 and C2 fluorides,
J. Phys. Chem., 1969, 73, 949. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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