Hydroxymethyl-d3 radical
- Formula: CD3O
- Molecular weight: 34.0524
- CAS Registry Number: 6853-31-2
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
B - John E. Bartmess
View reactions leading to CD3O+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.5546 ± 0.0019 | LPES | Nee, Osterwalder, et al., 2006 | B |
| 1.5590 ± 0.0040 | LPES | Ramond, Davico, et al., 2000 | B |
| 1.5510 ± 0.0050 | LPES | Osborn, Leahy, et al., 1998 | B |
| 1.552 ± 0.022 | LPES | Engleking, Ellison, et al., 1978 | B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.53 ± 0.02 | PI | Kuo, Zhang, et al., 1994 | LL |
| 7.56 ± 0.01 | PE | Dyke, 1987 | LBLHLM |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nee, Osterwalder, et al., 2006
Nee, M.J.; Osterwalder, A.; Zhou, J.; Neumark, D.M.,
Slow electron velocity-map imaging photoelectron spectra of the methoxide anion,
J. Chem. Phys., 2006, 125, 1, 014306, https://doi.org/10.1063/1.2212411
. [all data]
Ramond, Davico, et al., 2000
Ramond, T.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C.,
Vibronic structure of alkoxy radicals via photoelectron spectroscopy,
J. Chem. Phys., 2000, 112, 3, 1158-1169, https://doi.org/10.1063/1.480767
. [all data]
Osborn, Leahy, et al., 1998
Osborn, D.L.; Leahy, D.J.; Kim, E.H.; deBeer, E.; Neumark, D.M.,
Photoelectron spectroscopy of CH3O- and CD3O-,
Chem. Phys. Lett., 1998, 292, 4-6, 651-655, https://doi.org/10.1016/S0009-2614(98)00717-9
. [all data]
Engleking, Ellison, et al., 1978
Engleking, P.C.; Ellison, G.B.; Lineberger, W.C.,
Laser photodetachment electron spectrometry of methoxide, deuteromethoxide, and thiomethoxide: Electron affinities and vibrational structure of CH3O, and CH3S,
J. Chem. Phys., 1978, 69, 1826. [all data]
Kuo, Zhang, et al., 1994
Kuo, S.-C.; Zhang, Z.; Klemm, R.B.; Liebman, J.F.; Stief, L.J.; Nesbitt, F.L.,
Photoionization of hydroxymethyl (CD2OH and CD3O) radicals: Photoion efficiency spectra, ionization energies and thermochemistry,
J. Phys. Chem., 1994, 98, 4026. [all data]
Dyke, 1987
Dyke, J.M.,
Properties of gas-phase ions,
J. Chem. Soc. Faraday Trans., 1987, 83, 69. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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