Methylphosphonyl dichloride
- Formula: CH3Cl2OP
- Molecular weight: 132.914
- IUPAC Standard InChIKey: SCLFRABIDYGTAZ-UHFFFAOYSA-N
- CAS Registry Number: 676-97-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methyl phosphonic dichloride; CH3POCl2; Methanephosphonic dichloride; Methanephosphonic acid dichloride; Phosphonic dichloride, methyl-; NA 9206; Phosphonodichloridic acid, methyl-; Methanephosphonyl chloride; Phosphonic dichloride, P-methyl-
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Gas phase ion energetics data
Go To: Top, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.91 | PE | Zverev and Villem, 1980 | LLK |
10.92 | PE | Zverev, Vilesov, et al., 1975 | LLK |
11.49 | PE | Zverev, Villem, et al., 1979 | Vertical value; LLK |
11.45 | PE | Zverev, Villem, et al., 1978 | Vertical value; LLK |
11.43 | PE | Elbel and Dieck, 1976 | Vertical value; LLK |
11.4 | PE | Betteridge, Thompson, et al., 1972 | Vertical value; LLK |
IR Spectrum
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compiled by: Coblentz Society, Inc.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Mass spectrum (electron ionization)
Go To: Top, Gas phase ion energetics data, IR Spectrum, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | VERIFIN - Methodology B4-1983 |
NIST MS number | 226264 |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Methyl Silicone | 100. | 805. | Huber, Kenndler, et al., 1993 | H2; Column length: 5. m; Phase thickness: 2.65 μm |
Capillary | Methyl Silicone | 80. | 802. | Huber, Kenndler, et al., 1993 | H2; Column length: 5. m; Phase thickness: 2.65 μm |
References
Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zverev and Villem, 1980
Zverev, V.V.; Villem, Y.Y.,
Ionizationp potentials of phosphoryl compounds,
J. Struct. Chem., 1980, 21, 22, In original 30. [all data]
Zverev, Vilesov, et al., 1975
Zverev, V.V.; Vilesov, F.I.; Vovna, V.I.; Lopatin, S.N.; Kitaev, Y.P.,
Photoelectron spectra,
Izv. Akad. Nauk SSSR, Ser. Khim., 1975, 1975, 1051. [all data]
Zverev, Villem, et al., 1979
Zverev, V.V.; Villem, Y.Y.; Islamov, R.G.; Kitaev, Y.P.,
Photoelectron spectrum and electron structure of vinylphosphonic dichloride Cl2P(O)CH=CH2,
Zh. Obshch. Khim., 1979, 49, 1737. [all data]
Zverev, Villem, et al., 1978
Zverev, V.V.; Villem, Y.Y.; Ermolaeva, L.V.; Lisin, A.F.,
The photoelectron spectra and electronic structure of unsaturated phosphoryl compounds,
Dokl. Phys. Chem., 1978, 246, 1368. [all data]
Elbel and Dieck, 1976
Elbel, S.; Dieck, H.t.,
Photoelectron spectra of group 5 compounds. Part V. Phosphorus halides, R2P(X)Y and RP(X)Y2(R = Me or F; X = O, S, or Se; Y = Cl or Br),
J. Chem. Soc. Dalton Trans., 1976, 1762. [all data]
Betteridge, Thompson, et al., 1972
Betteridge, D.; Thompson, M.; Baker, A.D.; Kemp, N.R.,
Photoelectron spectra of phosphorus halides, alkyl phosphites and phosphates, organophosphorus pesticides, and related compounds,
Anal. Chem., 1972, 44, 2005. [all data]
Huber, Kenndler, et al., 1993
Huber, J.F.K.; Kenndler, E.; Reich, G.; Hack, W.; Wolf, J.,
Optimal Selection of Gas Chromatographic Columns for the Analytical Control of Chemical Warfare Agents by Application of Information Theory to Retention Data,
Anal. Chem., 1993, 65, 20, 2903-2906, https://doi.org/10.1021/ac00068a031
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References
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