Dimolybdenum,tetrakis[μ-(6-methyl-2(1H)-pyridinonato-]


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-594. ± 13.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-751. ± 12.kJ/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub157.0 ± 3.0kJ/molN/APilcher and Skinner, 1983See also Cavell, Garner, et al., 1981.; AC
Δsub157.0 ± 3.0kJ/molRSCCavell, Garner, et al., 1981MS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
5.5PEBursten, Cotton, et al., 1979LLK
5.89PEBursten, Cotton, et al., 1979Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Cavell, Garner, et al., 1981
Cavell, K.J.; Garner, C.D.; Martinho-Simoes, J.A.; Pilcher, G.; Al-Samman, H.; Skinner, H.A.; Al-Tekhin, G.; Walton, I.B.; Zafarani-Moattar, M.T., J. Chem. Soc. Faraday Trans. 1, 1981, 77, 2927. [all data]

Bursten, Cotton, et al., 1979
Bursten, B.E.; Cotton, F.A.; Cowley, A.H.; Hanson, B.E.; Lattman, M.; Stanley, G.S., Strong metal-to-metal quadruple bonds in a series of five isostructural compounds as indicated by photoelectron spectroscopy, J. Am. Chem. Soc., 1979, 101, 6244. [all data]


Notes

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