Methyl Alcohol

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Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil337.8 ± 0.3KAVGN/AAverage of 154 out of 171 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus176. ± 1.KAVGN/AAverage of 13 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple175.5 ± 0.5KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tc513. ± 1.KAVGN/AAverage of 27 out of 31 values; Individual data points
Quantity Value Units Method Reference Comment
Pc81. ± 1.barAVGN/AAverage of 17 out of 20 values; Individual data points
Quantity Value Units Method Reference Comment
Vc0.117l/molN/AGude and Teja, 1995 
Vc0.113024l/molN/ACraven and de Reuck, 1986TRC
Vc0.118l/molN/AFrancesconi, Lentz, et al., 1981Uncertainty assigned by TRC = 0.004 l/mol; TRC
Vc0.11663l/molN/AZubarev and Bagdonas, 1969Uncertainty assigned by TRC = 0.0035 l/mol; TRC
Quantity Value Units Method Reference Comment
ρc8.51 ± 0.07mol/lAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δvap37.6 ± 0.5kJ/molAVGN/AAverage of 11 out of 12 values; Individual data points

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
35.21337.7N/AMajer and Svoboda, 1985 
39.2258.AStephenson and Malanowski, 1987Based on data from 175. to 273. K.; AC
36.9353.AStephenson and Malanowski, 1987Based on data from 338. to 487. K.; AC
43.7213.AStephenson and Malanowski, 1987Based on data from 188. to 228. K.; AC
38.9275.AStephenson and Malanowski, 1987Based on data from 224. to 290. K.; AC
38.3300.AStephenson and Malanowski, 1987Based on data from 285. to 345. K.; AC
37.0350.AStephenson and Malanowski, 1987Based on data from 335. to 376. K.; AC
36.1388.AStephenson and Malanowski, 1987Based on data from 373. to 458. K.; AC
35.1468.AStephenson and Malanowski, 1987Based on data from 453. to 513. K.; AC
32.7373.CYerlett and Wormald, 1986AC
28.1423.CYerlett and Wormald, 1986AC
20.6473.CYerlett and Wormald, 1986AC
7.4510.CYerlett and Wormald, 1986AC
37.5331.EBCervenkova and Boublik, 1984Based on data from 316. to 336. K.; AC
38.3303.N/AGibbard and Creek, 1974Based on data from 288. to 337. K. See also Boublik, Fried, et al., 1984.; AC
35.2 ± 0.1338.CCounsell and Lee, 1973AC
35.6 ± 0.1331.CCounsell and Lee, 1973AC
36.2 ± 0.1321.CCounsell and Lee, 1973AC
37.0 ± 0.1306.CCounsell and Lee, 1973AC
36.7 ± 0.1313.CSvoboda, Veselý, et al., 1973AC
36.2 ± 0.1323.CSvoboda, Veselý, et al., 1973AC
35.6 ± 0.1333.CSvoboda, Veselý, et al., 1973AC
35.3 ± 0.1338.CSvoboda, Veselý, et al., 1973AC
34.7 ± 0.1343.CSvoboda, Veselý, et al., 1973AC
37.0352.N/AWilhoit and Zwolinski, 1973Based on data from 337. to 383. K.; AC
38.7290.EBBoublík and Aim, 1972Based on data from 275. to 336. K. See also Stephenson and Malanowski, 1987.; AC
38.3303.EBAmbrose and Sprake, 1970Based on data from 288. to 357. K.; AC
36.3368.N/AHirata, Suda, et al., 1967Based on data from 353. to 483. K.; AC
38.4293.N/AKlyueva, Mischenko, et al., 1960Based on data from 278. to 323. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-αTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) 298. to 477.
A (kJ/mol) 45.3
α -0.31
β 0.4241
Tc (K) 512.6
ReferenceMajer and Svoboda, 1985

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
353.5 to 512.635.158531569.613-34.846Ambrose, Sprake, et al., 1975Coefficents calculated by NIST from author's data.
288.1 to 356.835.204091581.341-33.50Ambrose and Sprake, 1970Coefficents calculated by NIST from author's data.
353. to 483.5.313011676.569-21.728Hirata and Suda, 1967Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
3.18175.3Domalski and Hearing, 1996AC
2.196176.Maass and Walbauer, 1925DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
12.5176.Maass and Walbauer, 1925DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
3.7161.1Domalski and Hearing, 1996CAL
18.1175.3
4.0157.3
18.3175.6

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.6360157.34crystaline, IIcrystaline, ICarlson and Westrum, 1971DH
3.2154175.59crystaline, IliquidCarlson and Westrum, 1971DH
1.540103.crystalineglassSugisaki, Suga, et al., 1968Glass transition.; DH
0.711157.8crystaline, IIcrystaline, IStaveley and Gupta, 1949DH
3.159175.4crystaline, IliquidStaveley and Gupta, 1949DH
0.6456157.4crystaline, IIcrystaline, IKelley, 1929DH
3.167175.2crystaline, IliquidKelley, 1929DH
0.590161.1crystaline, IIcrystaline, IParks, 1925DH
3.176175.3crystaline, IliquidParks, 1925DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
4.04157.34crystaline, IIcrystaline, ICarlson and Westrum, 1971DH
18.31175.59crystaline, IliquidCarlson and Westrum, 1971DH
14.95103.crystalineglassSugisaki, Suga, et al., 1968Glass; DH
4.51157.8crystaline, IIcrystaline, IStaveley and Gupta, 1949DH
18.01175.4crystaline, IliquidStaveley and Gupta, 1949DH
4.10157.4crystaline, IIcrystaline, IKelley, 1929DH
18.08175.2crystaline, IliquidKelley, 1929DH
3.66161.1crystaline, IIcrystaline, IParks, 1925DH
18.12175.3crystaline, IliquidParks, 1925DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CH4O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)10.84 ± 0.01eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)754.3kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity724.5kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
10.85 ± 0.03PITao, Klemm, et al., 1992LL
10.82 ± 0.05EIHolmes and Lossing, 1991LL
10.84 ± 0.07EIBowen and Maccoll, 1984LBLHLM
10.9EIMishchanchuk, Pokrovskii, et al., 1982LBLHLM
10.84 ± 0.08EIAllam, Migahed, et al., 1982LBLHLM
10.90 ± 0.03EISahini, Constantin, et al., 1978LLK
10.85 ± 0.01PIBerkowitz, 1978LLK
10.846 ± 0.002PEMacNeil and Dixon, 1977LLK
10.90 ± 0.12EIFinney and Harrison, 1972LLK
10.83 ± 0.03PIWarneck, 1971LLK
10.85 ± 0.02PECocksey, Eland, et al., 1971LLK
10.85PEBaker, Betteridge, et al., 1971LLK
10.85PEBaker, Betteridge, et al., 1971LLK
10.829 ± 0.015PIOmura, Kaneko, et al., 1969RDSH
10.85EILifshitz, Shapiro, et al., 1969RDSH
10.83PEDewar and Worley, 1969RDSH
10.84 ± 0.02PIRefaey and Chupka, 1968RDSH
10.85CICermak, 1968RDSH
10.83PEAl-Joboury and Turner, 1964RDSH
10.85 ± 0.02PIWatanabe, 1954RDSH
10.96EIVorob'ev, Furlei, et al., 1989Vertical value; LL
11.0PEVon Niessen, Bieri, et al., 1980Vertical value; LLK
10.95PEUtsunomiya, Kobayashi, et al., 1980Vertical value; LLK
10.95PEKobayashi, 1978Vertical value; LLK
10.86PEBenoit and Harrison, 1977Vertical value; LLK
10.97 ± 0.03PEPeel and Willett, 1975Vertical value; LLK
10.96PERobin and Kuebler, 1973Vertical value; LLK
10.95PEOgata, Onizuka, et al., 1973Vertical value; LLK
10.94PEKatsumata, Iwai, et al., 1973Vertical value; LLK
10.95PEOgata, Onizuka, et al., 1972Vertical value; LLK
10.96PEBaker, Betteridge, et al., 1971Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH+22.31 ± 0.09?EIReed and Snedden, 1956RDSH
CHO+13.06 ± 0.10H2+HPIWarneck, 1971LLK
CHO+14.0 ± 0.2H2+HEILifshitz, Shapiro, et al., 1969RDSH
CH2+14.05 ± 0.05H2OPIWarneck, 1971LLK
CH2+15.3H2OEIHaney and Franklin, 1968RDSH
CH2O+10.9H2EIMishchanchuk, Pokrovskii, et al., 1982LBLHLM
CH2O+12.05 ± 0.12H2PIWarneck, 1971LLK
CH2O+12.45H2PIRefaey and Chupka, 1968RDSH
CH3+13.82 ± 0.04OHPIWarneck, 1971LLK
CH3+13.5OHEIFriedman, Long, et al., 1957RDSH
CH3O+11.67 ± 0.09HEIBowen and Maccoll, 1984LBLHLM
CH3O+10.4HEIMishchanchuk, Pokrovskii, et al., 1982LBLHLM
CH3O+11.85 ± 0.08HEIAllam, Migahed, et al., 1982LBLHLM
CH3O+11.88 ± 0.05HEISelim and Helal, 1981LLK
CH3O+11.69HEILossing, 1977LLK
CH3O+11.76 ± 0.11HEIFinney and Harrison, 1972LLK
CH3O+11.55 ± 0.03HPIWarneck, 1971LLK
CH3O+11.66 ± 0.04HPIOmura, Kaneko, et al., 1969RDSH
CH3O+11.67HEILifshitz, Shapiro, et al., 1969RDSH
CH3O+11.67 ± 0.03HPIRefaey and Chupka, 1968RDSH
CH3O+[CH2OH+]11.649 ± 0.003HPIBerkowitz, Ellison, et al., 1994Unpublished results of B. Ruscic and J. Berkowitz; LL
CO+13.72H2EIFriedman, Long, et al., 1957RDSH
CO+14.31 ± 0.052H2EIFriedland and Strakna, 1956RDSH

De-protonation reactions

CH3O- + Hydrogen cation = Methyl Alcohol

By formula: CH3O- + H+ = CH4O

Quantity Value Units Method Reference Comment
Δr1597. ± 8.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr1573.3 ± 2.6kJ/molH-TSNee, Osterwalder, et al., 2006gas phase; B
Δr1573.4 ± 2.3kJ/molH-TSOsborn, Leahy, et al., 1998gas phase; B
Δr1565. ± 8.4kJ/molIMREBartmess, Scott, et al., 1979gas phase; The acidity is 1.2 kcal/mol stronger than that from the D-EA cycle, due to the multi-compound fit for the acidity scale.; value altered from reference due to change in acidity scale; B
Δr1567. ± 8.8kJ/molH-TSHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.; B
Δr1569.4 ± 2.5kJ/molTDEqMeot-ner and Sieck, 1986gas phase; Experimental entropy: 21.5 eu, 0.6 less than H2O; B

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 72
NIST MS number 229809

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gude and Teja, 1995
Gude, M.; Teja, A.S., Vapor-Liquid Critical Properties of Elements and Compounds. 4. Aliphatic Alkanols, J. Chem. Eng. Data, 1995, 40, 1025-1036. [all data]

Craven and de Reuck, 1986
Craven, R.J.B.; de Reuck, K.M., Ideal-Gas and Saturation Properties of Methanol, Int. J. Thermophys., 1986, 7, 541. [all data]

Francesconi, Lentz, et al., 1981
Francesconi, A.Z.; Lentz, H.; Franck, E.U., Phase Equilibriums and PVT Data for the Methane-Methanol System to 300 MPa and 240 degree C, J. Phys. Chem., 1981, 85, 3303. [all data]

Zubarev and Bagdonas, 1969
Zubarev, V.N.; Bagdonas, A., Saturation Curve Properties and Specific Volumes of Methanol, Teploenergetika (Moscow), 1969, 16, 88-91. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Yerlett and Wormald, 1986
Yerlett, T.K.; Wormald, C.J., The enthalpy of methanol, The Journal of Chemical Thermodynamics, 1986, 18, 8, 719-726, https://doi.org/10.1016/0021-9614(86)90105-9 . [all data]

Cervenkova and Boublik, 1984
Cervenkova, Irena; Boublik, Tomas, Vapor pressure, refractive indexes and densities at 20.0.degree.C, and vapor-liquid equilibrium at 101.325 kPa in the tert-amyl methyl ether-methanol system, J. Chem. Eng. Data, 1984, 29, 4, 425-427, https://doi.org/10.1021/je00038a017 . [all data]

Gibbard and Creek, 1974
Gibbard, H. Frank; Creek, Jefferson L., Vapor pressure of methanol from 288.15 to 337.65.deg.K, J. Chem. Eng. Data, 1974, 19, 4, 308-310, https://doi.org/10.1021/je60063a013 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Counsell and Lee, 1973
Counsell, J.F.; Lee, D.A., Thermodynamic properties of organic oxygen compounds 31. Vapour heat capacity and enthalpy of vaporization of methanol, The Journal of Chemical Thermodynamics, 1973, 5, 4, 583-589, https://doi.org/10.1016/S0021-9614(73)80107-7 . [all data]

Svoboda, Veselý, et al., 1973
Svoboda, V.; Veselý, F.; Holub, R.; Pick, J., Enthalpy data of liquids. II. The dependence of heats of vaporization of methanol, propanol, butanol, cyclohexane, cyclohexene, and benzene on temperature, Collect. Czech. Chem. Commun., 1973, 38, 12, 3539-3543, https://doi.org/10.1135/cccc19733539 . [all data]

Wilhoit and Zwolinski, 1973
Wilhoit, R.C.; Zwolinski, B.J., Physical and thermodynamic properties of aliphatic alcohols, J. Phys. Chem. Ref. Data Suppl., 1973, 1, 2, 1. [all data]

Boublík and Aim, 1972
Boublík, T.; Aim, K., Heats of vaporization of simple non-spherical molecule compounds, Collect. Czech. Chem. Commun., 1972, 37, 11, 3513-3521, https://doi.org/10.1135/cccc19723513 . [all data]

Ambrose and Sprake, 1970
Ambrose, D.; Sprake, C.H.S., Thermodynamic properties of organic oxygen compounds XXV. Vapour pressures and normal boiling temperatures of aliphatic alcohols, The Journal of Chemical Thermodynamics, 1970, 2, 5, 631-645, https://doi.org/10.1016/0021-9614(70)90038-8 . [all data]

Hirata, Suda, et al., 1967
Hirata, Mitsuho; Suda, Seijiro; Onodera, Yutaka, Vapor Pressure of Methanol in High Pressure Regions, Chemical engineering, 1967, 31, 4, 339-342,a1, https://doi.org/10.1252/kakoronbunshu1953.31.339 . [all data]

Klyueva, Mischenko, et al., 1960
Klyueva, M.L.; Mischenko, K.P.; Fedorov, M.K., Zh. Prikl. Khim. (S.-Peterburg), 1960, 3, 473. [all data]

Ambrose, Sprake, et al., 1975
Ambrose, D.; Sprake, C.H.S.; Townsend, R., Thermodynamic Properties of Organic Oxygen Compounds. XXXVII. Vapour Pressures of Methanol, Ethanol, Pentan-1-ol, and Octan-1-ol from the Normal Boiling Temperature to the Critical Temperature, J. Chem. Thermodyn., 1975, 7, 2, 185-190, https://doi.org/10.1016/0021-9614(75)90267-0 . [all data]

Hirata and Suda, 1967
Hirata, M.; Suda, S., Vapor Pressure on Methanol in High Pressure Regions, Kagaku Kogaku, 1967, 31, 4, 339-342, https://doi.org/10.1252/kakoronbunshu1953.31.339 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Maass and Walbauer, 1925
Maass, O.; Walbauer, L.J., The specific heats and latent heats of fusion of ice and of several organic compounds, J. Am. Chem. Soc., 1925, 47, 1-9. [all data]

Carlson and Westrum, 1971
Carlson, H.G.; Westrum, E.F., Jr., Methanol: heat capacity, enthalpies of transition and melting, and thermodynamic properties from 5-300K, J. Chem. Phys., 1971, 54, 1464-1471. [all data]

Sugisaki, Suga, et al., 1968
Sugisaki, M.; Suga, H.; Seki, S., Calorimetric study of the glassy state. III. Novel type calorimeter for study of glassy state and heat capacity of glassy methanol, Bull. Chem. Soc. Japan, 1968, 41, 2586-2591. [all data]

Staveley and Gupta, 1949
Staveley, L.A.K.; Gupta, A.K., A semi-micro low-temperature calorimeter, and a comparison of some thermodynamic properties of methyl alcohol and methyl deuteroxide, Trans. Faraday Soc., 1949, 45, 50-61. [all data]

Kelley, 1929
Kelley, K.K., The heat capacity of methyl alcohol from 16K to 298K and the corresponding entropy and free energy, J. Am. Chem. Soc., 1929, 51, 180-187. [all data]

Parks, 1925
Parks, G.S., Thermal data on organic compounds I. The heat capacities and free energies of methyl, ethyl and normal-butyl alcohols, J. Am. Chem. Soc., 1925, 47, 338-345. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Tao, Klemm, et al., 1992
Tao, W.; Klemm, R.B.; Nesbitt, F.L.; Stief, J.L., A discharge flow-photoionization mass spectrometric study of hydroxymethyl radicals (H2COH and H2COD): Photoionization spectrum and ionization energy, J. Phys. Chem., 1992, 96, 104. [all data]

Holmes and Lossing, 1991
Holmes, J.L.; Lossing, F.P., Ionization energies of homologous organic compounds and correlation with molecular size, Org. Mass Spectrom., 1991, 26, 537. [all data]

Bowen and Maccoll, 1984
Bowen, R.D.; Maccoll, A., Low energy, low temperature mass spectra, Org. Mass Spectrom., 1984, 19, 379. [all data]

Mishchanchuk, Pokrovskii, et al., 1982
Mishchanchuk, B.G.; Pokrovskii, V.A.; Shabel'nikov, V.P.; Korol, E.N., Mass spectrometric study of energy characteristics of methanol and ethanol ions during ionization by a strong electric field, Teor. Eksp. Khim., 1982, 18, 307. [all data]

Allam, Migahed, et al., 1982
Allam, S.H.; Migahed, M.D.; El-Khodary, A., Electron impact ionization and dissociation of deuterated and non-deuterated methanol, methyl cyanide, nitromethane and nitrobenzene, Egypt. J. Phys., 1982, 13, 167. [all data]

Sahini, Constantin, et al., 1978
Sahini, V.E.; Constantin, V.; Serban, I., Determination of ionization potentials using a MI-1305 mass spectrometer, Rev. Roum. Chim., 1978, 23, 479. [all data]

Berkowitz, 1978
Berkowitz, J., Photoionization of CH3OH, CD3OH, and CH3OD: Dissociative ionization mechanisms and ionic structures, J. Chem. Phys., 1978, 69, 3044. [all data]

MacNeil and Dixon, 1977
MacNeil, K.A.G.; Dixon, R.N., High-resolution photoelectron spectroscopy of methanol and its deuterated derivatives: Internal rotation in the ground ionic state, J. Electron Spectrosc. Relat. Phenom., 1977, 11, 315. [all data]

Finney and Harrison, 1972
Finney, C.D.; Harrison, A.G., A third-derivative method for determining electron-impact onset potentials, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 221. [all data]

Warneck, 1971
Warneck, P., Photoionisation von methanol und formaldehyd, Z. Naturforsch. A:, 1971, 26, 2047. [all data]

Cocksey, Eland, et al., 1971
Cocksey, B.J.; Eland, J.H.D.; Danby, C.J., The effect of alkyl substitution on ionisation potential, J. Chem. Soc., 1971, (B), 790. [all data]

Baker, Betteridge, et al., 1971
Baker, A.D.; Betteridge, D.; Kemp, N.R.; Kirby, R.E., Application of photoelectron spectrometry to pesticide analysis. II.Photoelectron spectra of hydroxy-, and halo-alkanes and halohydrins, Anal. Chem., 1971, 43, 375. [all data]

Omura, Kaneko, et al., 1969
Omura, I.; Kaneko, T.; Yamada, Y.; Tanaka, K., Mass spectrometric studies of photoionization. V. Methanol and methanol-d, J. Phys. Soc. Japan, 1969, 27, 981. [all data]

Lifshitz, Shapiro, et al., 1969
Lifshitz, C.; Shapiro, M.; Sternberg, R., Isotopic effects on metastable transitions. IV. Isotopic methanols, Israel J. Chem., 1969, 7, 391. [all data]

Dewar and Worley, 1969
Dewar, M.J.S.; Worley, S.D., Photoelectron spectra of molecules. I. Ionization potentials of some organic molecules and their interpretation, J. Chem. Phys., 1969, 50, 654. [all data]

Refaey and Chupka, 1968
Refaey, K.M.A.; Chupka, W.A., Photoionization of the lower aliphatic alcohols with mass analysis, J. Chem. Phys., 1968, 48, 5205. [all data]

Cermak, 1968
Cermak, V., Penning ionization electron spectroscopy. I. Determination of ionization potentials of polyatomic molecules, Collection Czech. Chem. Commun., 1968, 33, 2739. [all data]

Al-Joboury and Turner, 1964
Al-Joboury, M.I.; Turner, D.W., Molecular photoelectron spectroscopy. Part II. A summary of ionization potentials, J. Chem. Soc., 1964, 4434. [all data]

Watanabe, 1954
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Notes

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