FCO2-

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 34500 ± 240 gas Arnold, Bradforth, et al., 1995

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CO stretch 1399 gas PE Arnold, Bradforth, et al., 1995
1 CO stretch 1316 Cs Ar IR Ault, 1982
2 OCO bend 899 gas PE Arnold, Bradforth, et al., 1995
2 OCO bend 883 Cs Ar IR Ault, 1982
3 CF stretch 596 gas PE Arnold, Bradforth, et al., 1995
b2 5 CO stretch 1749 Cs Ar IR Ault, 1982

Additional references: Jacox, 1994, page 212; Jacox, 1998, page 259

Notes

dPhotodissociation threshold
CsInteraction with cesium

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-, J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575 . [all data]

Ault, 1982
Ault, B.S., Matrix isolation investigation of the fluoroformate anion, Inorg. Chem., 1982, 21, 2, 756, https://doi.org/10.1021/ic00132a056 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

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