BrOO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txd = 38200 Ar 240 300 Maier and Bothur, 1995
Kolm, Engdahl, et al., 1997

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 OO stretch 1487.0 Ne IR Lee and Lee, 2000
Akai, Wakamatsu, et al., 2010
1 OO stretch 1485.1 Ar IR Tevault and Smardzewski, 1978
Schriver-Mazzuoli, Abdelaoui, et al., 1993
Maier and Bothur, 1995
Kolm, Engdahl, et al., 1997

Additional references: Jacox, 1994, page 110; Jacox, 1998, page 204; Jacox, 2003, page 147; Suma, Sumiyoshi, et al., 2005

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier and Bothur, 1995
Maier, G.; Bothur, A., Bromsuperoxid: Bildung und Photoisomerisierung zu Bromdioxid, Z. Anorg. Allg. Chem., 1995, 621, 5, 743, https://doi.org/10.1002/zaac.19956210509 . [all data]

Kolm, Engdahl, et al., 1997
Kolm, J.; Engdahl, A.; Schrems, O.; Nelander, B., A spectroscopic and photoisomerisation study of bromine dioxides in argon matrices, Chem. Phys., 1997, 214, 2-3, 313, https://doi.org/10.1016/S0301-0104(96)00307-2 . [all data]

Lee and Lee, 2000
Lee, Y.-C.; Lee, Y.-P., The Visible Absorption Spectrum of, J. Phys. Chem. A, 2000, 104, 30, 6951, https://doi.org/10.1021/jp000527y . [all data]

Akai, Wakamatsu, et al., 2010
Akai, N.; Wakamatsu, D.; Yoshinobu, T.; Kawai, A.; Shibuya, K., Matrix-isolation infrared spectra of HOOBr and HOBrO produced upon VUV light irradiation of HBr/O2/Ne system, Chem. Phys. Lett., 2010, 499, 1-3, 117, https://doi.org/10.1016/j.cplett.2010.09.039 . [all data]

Tevault and Smardzewski, 1978
Tevault, D.E.; Smardzewski, R.R., Matrix infrared spectrum of the O2Br radical. Bonding in the O2X species, J. Am. Chem. Soc., 1978, 100, 12, 3955, https://doi.org/10.1021/ja00480a065 . [all data]

Schriver-Mazzuoli, Abdelaoui, et al., 1993
Schriver-Mazzuoli, L.; Abdelaoui, O.; Lugez, C.; Schriver, A., Matrix reaction of ozone with Cl2 and Br2. FTIR identification of BrC10 and ClBrO species, Chem. Phys. Lett., 1993, 214, 5, 519, https://doi.org/10.1016/0009-2614(93)85676-F . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Suma, Sumiyoshi, et al., 2005
Suma, K.; Sumiyoshi, Y.; Endo, Y., Spectroscopic characterization of a molecule with a weak bond: The BrOO radical, J. Chem. Phys., 2005, 123, 2, 024312, https://doi.org/10.1063/1.1953508 . [all data]

Notes

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