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Copper trimer


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.27 ± 0.10LPESHo, Ervin, et al., 1990Vertical Detachment Energy: 2.37±0.01 eV.; B
2.25 ± 0.15LPESTaylor, Pettiettehall, et al., 1992EA set as 0.2 eV above onset to correct for unresolved hot bands.; B
2.45 ± 0.10LPESLeopold, Ho, et al., 1987EA given is Vertical Detachment Energy. Adiabatic EA est. as 0.05 eV lower; B

Ionization energy determinations

IE (eV) Method Reference Comment
6.1 ± 1.0EIFranzreb, Wucher, et al., 1990LL
5.5 ± 0.5LSMorse, Hopkins, et al., 1983LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ho, Ervin, et al., 1990
Ho, J.; Ervin, K.M.; Lineberger, W.C., Photoelectron Spectroscopy of Metal Cluster Anions - Cun-, Agn-, and Aun-, J. Chem. Phys., 1990, 93, 10, 6987, https://doi.org/10.1063/1.459475 . [all data]

Taylor, Pettiettehall, et al., 1992
Taylor, K.J.; Pettiettehall, C.L.; Cheshnovsky, O.; Smalley, R.E., Ultraviolet Photoelectron Spectra of Coinage Metal Clusters, J. Chem. Phys., 1992, 96, 4, 3319, https://doi.org/10.1063/1.461927 . [all data]

Leopold, Ho, et al., 1987
Leopold, D.G.; Ho, J.; Lineberger, W.C., Photoelectron Spectroscopy of Mass-selected Metal Cluster Anions. I. Cun-, n=1-10, J. Chem. Phys., 1987, 86, 4, 1715, https://doi.org/10.1063/1.452170 . [all data]

Franzreb, Wucher, et al., 1990
Franzreb, K.; Wucher, A.; Oechsner, H., Electron impact ionization of small silver and copper clusters, Z. Phys. D, 1990, 17, 51. [all data]

Morse, Hopkins, et al., 1983
Morse, M.D.; Hopkins, J.B.; Langridge-Smith, P.R.R.; Smalley, R.E., Spectroscopic studies of the jet-cooled copper trimer, J. Chem. Phys., 1983, 79, 5316. [all data]


Notes

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