C7 anion
- Formula: C7-
- Molecular weight: 84.0754
- CAS Registry Number: 64886-38-0
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 1015. ± 19. | kJ/mol | R-EA | Arnold, Bradforth, et al., 1991 | Linear structure for both neutral and anion |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (C7- • 4294967295C) + C = C7-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 478. ± 31. | kJ/mol | N/A | Arnold, Bradforth, et al., 1991 | gas phase; Linear structure for both neutral and anion |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 27090 ± 115 | gas | Yang, Taylor, et al., 1988 | |||||
Arnold, Bradforth, et al., 1991 | |||||||
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 35231 ± 25 | Ne | C-X | 278 | 284 | Forney, Grutter, et al., 1997 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 3 | 491 ± 25 | Ne | AB | Forney, Grutter, et al., 1997 | ||
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 20298 | gas | B-X | 447 | 493 | Ohara, Shiromaru, et al., 1997 | ||
Tulej, Kirkwood, et al., 1998 | |||||||
Tulej, Kirkwood, et al., 1998, 2 | |||||||
To = 20314 ± 8 | Ne | B-X | 380 | 493 | Forney, Grutter, et al., 1997 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 2038 | gas | MPD | Ohara, Shiromaru, et al., 1997 Tulej, Kirkwood, et al., 1998 Tulej, Kirkwood, et al., 1998, 2 | |
1 | Sym. stretch | 2058 ± 10 | Ne | AB | Forney, Grutter, et al., 1997 | ||
2 | 1569 ± 9 | Ne | AB | Forney, Grutter, et al., 1997 | |||
3 | 532 | gas | MPD | Tulej, Kirkwood, et al., 1998 Tulej, Kirkwood, et al., 1998, 2 | |||
3 | 575 ± 8 | Ne | AB | Forney, Grutter, et al., 1997 | |||
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 15930 | gas | A-X | 496 | 627 | Ohara, Shiromaru, et al., 1997 | ||
Tulej, Kirkwood, et al., 1998 | |||||||
Tulej, Kirkwood, et al., 1998, 2 | |||||||
Lakin, Pachkov, et al., 2000 | |||||||
To = 15954 ± 5 | Ne | A-X | 495 | 627 | Forney, Grutter, et al., 1997 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σg+ | 1 | Sym. stretch | 1870 | gas | MPD | Ohara, Shiromaru, et al., 1997 Tulej, Kirkwood, et al., 1998 Tulej, Kirkwood, et al., 1998, 2 Lakin, Pachkov, et al., 2000 | |
1 | Sym. stretch | 1877 ± 6 | Ne | AB | Forney, Grutter, et al., 1997 | ||
2 | 1452 | gas | MPD | Tulej, Kirkwood, et al., 1998 Tulej, Kirkwood, et al., 1998, 2 Lakin, Pachkov, et al., 2000 | |||
2 | 1457 ± 5 | Ne | AB | Forney, Grutter, et al., 1997 | |||
3 | 543 | gas | MPD | Ohara, Shiromaru, et al., 1997 Tulej, Kirkwood, et al., 1998 Tulej, Kirkwood, et al., 1998, 2 Lakin, Pachkov, et al., 2000 | |||
3 | 562 ± 5 | Ne | AB | Forney, Grutter, et al., 1997 | |||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σu+ | 5 | Asym. stretch | 1736.4 | Ne | IR | Freivogel, Grutter, et al., 1997 | |
5 | Asym. stretch | 1734.8 | Ar | IR | Szczepanski, Ekern, et al., 1997 Szczepanski, Hodyss, et al., 1998 | ||
Additional references: Jacox, 1994, page 370; Jacox, 1998, page 329; Jacox, 2003, page 344
Notes
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
d | Photodissociation threshold |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Arnold, Bradforth, et al., 1991
Arnold, D.W.; Bradforth, S.E.; Kitsopoulos, T.N.; Neumark, D.M.,
Vibrationally Resolved Spectra of C2-C11 by Anion Photoelectron Spectroscopy,
J. Chem. Phys., 1991, 95, 12, 8753, https://doi.org/10.1063/1.461211
. [all data]
Yang, Taylor, et al., 1988
Yang, S.; Taylor, K.J.; Craycraft, M.J.; Conceicao, J.; Pettiette, C.L.; Cheshnovsky, O.; Smalley, R.E.,
UPS of 2--30-atom carbon clusters: Chains and rings,
Chem. Phys. Lett., 1988, 144, 5-6, 431, https://doi.org/10.1016/0009-2614(88)87291-9
. [all data]
Forney, Grutter, et al., 1997
Forney, D.; Grutter, M.; Freivogel, P.; Maier, J.P.,
Electronic Absorption Spectra of Carbon Chain Anions (,
J. Phys. Chem. A, 1997, 101, 29, 5292, https://doi.org/10.1021/jp970954k
. [all data]
Ohara, Shiromaru, et al., 1997
Ohara, M.; Shiromaru, H.; Achiba, Y.,
Resonance-enhanced multiphoton electron detachment spectra of C[sub 7][sup -], C[sub 9][sup -], and C[sub 11][sup -],
J. Chem. Phys., 1997, 106, 24, 9992, https://doi.org/10.1063/1.474074
. [all data]
Tulej, Kirkwood, et al., 1998
Tulej, M.; Kirkwood, D.A.; Maccaferri, G.; Dopfer, O.; Maier, J.P.,
Electronic spectra of linear carbon anions,
Chem. Phys., 1998, 228, 1-3, 293, https://doi.org/10.1016/S0301-0104(97)00358-3
. [all data]
Tulej, Kirkwood, et al., 1998, 2
Tulej, M.; Kirkwood, D.A.; Pachkov, M.; Maier, J.P.,
Gas-Phase Electronic Transitions of Carbon Chain Anions Coinciding with Diffuse Interstellar Bands,
Astrophys. J., 1998, 506, 1, L69, https://doi.org/10.1086/311637
. [all data]
Lakin, Pachkov, et al., 2000
Lakin, N.M.; Pachkov, M.; Tulej, M.; Maier, J.P.; Chambaud, G.; Rosmus, P.,
Theoretical and experimental study of the A[sup 2]Π[sub u]--X[sup 2]Π[sub g] band system of C[sub 7][sup -],
J. Chem. Phys., 2000, 113, 21, 9586, https://doi.org/10.1063/1.1321768
. [all data]
Freivogel, Grutter, et al., 1997
Freivogel, P.; Grutter, M.; Forney, D.; Maier, J.P.,
Infrared bands of mass-selected carbon chains Cn (n = 8-12) and Cn- (n = 5-10, 12) in neon matrices,
Chem. Phys., 1997, 216, 3, 401, https://doi.org/10.1016/S0301-0104(97)00038-4
. [all data]
Szczepanski, Ekern, et al., 1997
Szczepanski, J.; Ekern, S.; Vala, M.,
Vibrational Spectroscopy of Small Matrix-Isolated Linear Carbon Cluster Anions,
J. Phys. Chem. A, 1997, 101, 10, 1841, https://doi.org/10.1021/jp963200z
. [all data]
Szczepanski, Hodyss, et al., 1998
Szczepanski, J.; Hodyss, R.; Vala, M.,
Isotopic Infrared Absorption Study of C,
J. Phys. Chem. A, 1998, 102, 43, 8300, https://doi.org/10.1021/jp982963e
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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