Methanamine, N-ethylidene-, (Z)-
- Formula: C3H7N
- Molecular weight: 57.0944
- IUPAC Standard InChI: InChI=1S/C3H7N/c1-3-4-2/h3H,1-2H3
- IUPAC Standard InChIKey: OHACMJAMDKRMSW-UHFFFAOYSA-N
- CAS Registry Number: 64611-40-1
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C3H7N+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.0 | PE | Bock and Dammel, 1987 | LBLHLM |
| 9.1 ± 0.1 | PE | Haselbach and Heilbronner, 1970 | RDSH |
| 9.5 | PE | Bock and Dammel, 1987 | Vertical value; LBLHLM |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-101 | 477. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bock and Dammel, 1987
Bock, H.; Dammel, R.,
Methanimine RR"C=NR": Darstellung und photoelektronen-spektren,
J. Am. Chem. Soc., 1987, 120, 1961. [all data]
Haselbach and Heilbronner, 1970
Haselbach, E.; Heilbronner, E.,
Die PhotoelektronSpektren von CH3-CH≡CH-CH3, CH3-N≡CH-CH3, CH3-N≡N-CH3, ein Beitrag zur Frage nach der Wechselwirkung zwischen den einsamen Elektronenpaaren der trans-konfigurierten Azogruppe,
Helv. Chim. Acta, 1970, 53, 684. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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