HSSH
- Formula: H2S2
- Molecular weight: 66.146
- CAS Registry Number: 63344-86-5
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a | 1 | SH s-stretch | 2555.78 | gas | IR | Winnewisser and Winnewisser, 1968 Winnewisser, 1970 | |
| 1 | SH s-stretch | 2553.8 | Ar | IR | Isoniemi, Khriachtchev, et al., 1999 | ||
| 2 | Deformation | 883 | gas | IR | Winnewisser and Winnewisser, 1968 | ||
| 2 | Deformation | 880.3 | Ar | IR | Isoniemi, Khriachtchev, et al., 1999 | ||
| 3 | SS stretch | 515.92 | gas | IR MW | Winnewisser and Winnewisser, 1968 Urban, Behrend, et al., 1993 | ||
| 4 | Torsion | 417.48 | gas | IR | Redington, 1962 Winnewisser and Winnewisser, 1968 Urban, Herbst, et al., 1989 Urban, Behrend, et al., 1993 | ||
| b | 5 | SH a-stretch | 2558.63 | gas | IR | Wilson and Badger, 1949 Winnewisser and Winnewisser, 1968 Winnewisser, 1970 Mittler, Yamada, et al., 1994 | |
| 5 | SH a-stretch | 2556.6 | Ar | IR | Isoniemi, Khriachtchev, et al., 1999 | ||
| 6 | Deformation | 882.0 | gas | IR | Wilson and Badger, 1949 Winnewisser and Winnewisser, 1968 | ||
Additional references: Jacox, 1994, page 155; Jacox, 1998, page 230; Jacox, 2003, page 178; Winnewisser, Winnewisser, et al., 1968; Winnewisser, 1972; Winnewisser and Helminger, 1972; Winnewisser and Helminger, 1972, 2; Winnewisser, 1972, 2; Plummer, Winnewisser, et al., 1987; Behrend, Mittler, et al., 1990; Behrend, Mittler, et al., 1991; Pelz, Yamada, et al., 1993; Yamada, Behrend, et al., 1996
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Winnewisser and Winnewisser, 1968
Winnewisser, B.P.; Winnewisser, M.,
Z. Naturforsch., 1968, 23a, 832. [all data]
Winnewisser, 1970
Winnewisser, B.P.,
High resolution infrared spectrum of ν1 and ν5 of disulfane,
J. Mol. Spectrosc., 1970, 36, 3, 414, https://doi.org/10.1016/0022-2852(70)90218-3
. [all data]
Isoniemi, Khriachtchev, et al., 1999
Isoniemi, E.; Khriachtchev, L.; Pettersson, M.; Rasanen, M.,
Infrared spectroscopy and 266 nm photolysis of H2S2 in solid Ar,
Chem. Phys. Lett., 1999, 311, 1-2, 47, https://doi.org/10.1016/S0009-2614(99)00756-3
. [all data]
Urban, Behrend, et al., 1993
Urban, S.; Behrend, J.; Yamada, K.M.T.; Winnewisser, G.,
Coriolis Interactions between the Fundamental Stretching and Torsional-Vibrational States of Disulfane (H2S2),
J. Mol. Spectrosc., 1993, 161, 2, 511, https://doi.org/10.1006/jmsp.1993.1255
. [all data]
Redington, 1962
Redington, R.L.,
The infrared spectrum and barriers hindering internal rotation in H2S2, CF3SH, and CF3SD,
J. Mol. Spectrosc., 1962, 9, 469, https://doi.org/10.1016/0022-2852(62)90252-7
. [all data]
Urban, Herbst, et al., 1989
Urban, S.; Herbst, E.; Mittler, P.; Winnewisser, G.; Yamada, K.M.T.; Winnewisser, M.,
The high-resolution rotational and torsional spectra of HSSH,
J. Mol. Spectrosc., 1989, 137, 2, 327, https://doi.org/10.1016/0022-2852(89)90177-X
. [all data]
Wilson and Badger, 1949
Wilson, M.K.; Badger, R.M.,
The Infra-Red Spectrum and Molecular Configuration of Hydrogen Persulfide,
J. Chem. Phys., 1949, 17, 12, 1232, https://doi.org/10.1063/1.1747148
. [all data]
Mittler, Yamada, et al., 1994
Mittler, P.; Yamada, K.M.T.; Winnewisser, G.; Birk, M.,
High-Resolution FTIR Spectrum of HSSH in the SH-Stretching Region: The ν5 Band,
J. Mol. Spectrosc., 1994, 164, 2, 390, https://doi.org/10.1006/jmsp.1994.1083
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Winnewisser, Winnewisser, et al., 1968
Winnewisser, G.; Winnewisser, M.; Gordy, W.,
Millimeter-Wave Rotational Spectrum of HSSH and DSSD. I. Q Branches,
J. Chem. Phys., 1968, 49, 8, 3465, https://doi.org/10.1063/1.1670621
. [all data]
Winnewisser, 1972
Winnewisser, G.,
Millimeter Wave Rotational Spectrum of HSSH and DSSD. II. Anomalous K Doubling Caused by Centrifugal Distortion in DSSD,
J. Chem. Phys., 1972, 56, 6, 2944, https://doi.org/10.1063/1.1677629
. [all data]
Winnewisser and Helminger, 1972
Winnewisser, G.; Helminger, P.,
Millimeter Wave Rotational Spectrum of HSSH and DSSD. III. Q Branches of DSSD,
J. Chem. Phys., 1972, 56, 6, 2954, https://doi.org/10.1063/1.1677630
. [all data]
Winnewisser and Helminger, 1972, 2
Winnewisser, G.; Helminger, P.,
Millimeter Wave Rotational Spectrum of HSSH and DSSD. IV. P, Q, and R Branches of HSSH,
J. Chem. Phys., 1972, 56, 6, 2967, https://doi.org/10.1063/1.1677631
. [all data]
Winnewisser, 1972, 2
Winnewisser, G.,
Direct Observation of the Anomalous K Doubling Caused by Centrifugal Distortion in HSSH,
J. Chem. Phys., 1972, 57, 4, 1803, https://doi.org/10.1063/1.1678483
. [all data]
Plummer, Winnewisser, et al., 1987
Plummer, G.M.; Winnewisser, G.; Winnewisser, M.; Hahn, J.; Reinartz, K.,
HSSH revisited: The high-resolution Fourier transform spectrum of the ground state between 30 and 90 cm-1,
J. Mol. Spectrosc., 1987, 126, 2, 255, https://doi.org/10.1016/0022-2852(87)90235-9
. [all data]
Behrend, Mittler, et al., 1990
Behrend, J.; Mittler, P.; Winnewisser, G.; Yamada, K.M.T.; Winnewisser, M.,
Complete rotational analysis of the ground state of HSSH,
J. Mol. Spectrosc., 1990, 141, 2, 265, https://doi.org/10.1016/0022-2852(90)90163-K
. [all data]
Behrend, Mittler, et al., 1991
Behrend, J.; Mittler, P.; Winnewisser, G.; Yamada, K.M.T.,
Spectra of deuterated disulfane and spectroscopic determination of its molecular structure,
J. Mol. Spectrosc., 1991, 150, 1, 99, https://doi.org/10.1016/0022-2852(91)90196-H
. [all data]
Pelz, Yamada, et al., 1993
Pelz, G.; Yamada, K.M.T.; Winnewisser, G.,
Torsional Dependence of the Effective Rotational Constants of H2O2 and H2S2,
J. Mol. Spectrosc., 1993, 159, 2, 507, https://doi.org/10.1006/jmsp.1993.1146
. [all data]
Yamada, Behrend, et al., 1996
Yamada, K.M.T.; Behrend, J.; Belov, S.P.; Winnewisser, G.,
AnomalousK-Type Doubling of HSSH,
J. Mol. Spectrosc., 1996, 176, 2, 397, https://doi.org/10.1006/jmsp.1996.0101
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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