HSSH+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 46700 ± 1200 gas Solouki and Bock, 1977

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 37200 ± 400 gas Solouki and Bock, 1977

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 25900 ± 400 gas Solouki and Bock, 1977

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 7020 ± 400 gas Wagner and Bock, 1974
Frost, Lee, et al., 1977
Solouki and Bock, 1977
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a 3 S-S stretch 500 ± 30 gas PE Frost, Lee, et al., 1977

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a 3 S-S stretch 480 ± 30 gas PE Frost, Lee, et al., 1977

Additional references: Jacox, 1994, page 153

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Solouki and Bock, 1977
Solouki, B.; Bock, H., Photoelectron spectra and molecular properties. 59. Ionization energies of disulfur dihalides and isomerization surfaces XSSX .dblarw. SSX2, Inorg. Chem., 1977, 16, 3, 665, https://doi.org/10.1021/ic50169a035 . [all data]

Wagner and Bock, 1974
Wagner, G.; Bock, H., Photoelektronenspektren und molekuleigenschaften, XXVI. Die delokalisation von schwefel-elektronenpaaren in alkylsulfiden und -disulfiden, Chem. Ber., 1974, 107, 68. [all data]

Frost, Lee, et al., 1977
Frost, D.C.; Lee, S.T.; McDowell, C.A.; Westwood, N.P.C., A versatile, fast pumping ultraviolet photoelectron spectrometer for the study of transient and unstable species, J. Electron Spectrosc. Relat. Phenom., 1977, 12, 1, 95, https://doi.org/10.1016/0368-2048(77)85070-6 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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