Silane, tetraethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.9PEPotzinger, Ritter, et al., 1975LLK
10.5EIdeRidder and Dijkstra, 1967RDSH
9.8PEBeltram, Fehlner, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H5Si+19.4?EIdeRidder and Dijkstra, 1967RDSH
C2H7Si+11.8?EIdeRidder and Dijkstra, 1967RDSH
C4H11Si+12.5?EIdeRidder and Dijkstra, 1967RDSH
C6H15Si+10.0 ± 0.1C2H5EIPotzinger, Ritter, et al., 1975LLK
C6H15Si+11.0?EIdeRidder and Dijkstra, 1967RDSH
SiH+26.8?EIdeRidder and Dijkstra, 1967RDSH
SiH2+25.7?EIdeRidder and Dijkstra, 1967RDSH
SiH3+20.6?EIdeRidder and Dijkstra, 1967RDSH
Si+28.0?EIdeRidder and Dijkstra, 1967RDSH

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryApiezon L160.922.Peetre and Smith, 1974 
PackedPolymethylsiloxane, (PMS-20000)50.923.5Ainshtein and Shulyatieva, 1972He, Chromosorb W; Column length: 2. m

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApieson M160.922.Ellren, Peetre, et al., 1974Chromosorb G AW DMCS (80-100 mesh)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J., Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen, Z. Naturforsch. A:, 1975, 30, 347. [all data]

deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G., Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead, Rec. Trav. Chim., 1967, 86, 737. [all data]

Beltram, Fehlner, et al., 1980
Beltram, G.; Fehlner, T.P.; Mochida, K.; Kochi, J.K., UV photoelectron spectra of group IV alkyl hydrides, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 153. [all data]

Peetre and Smith, 1974
Peetre, I.-B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. IV. determination, calculation and correlation of Kováts retention indices for tetraalkylsilanes, J. Chromatogr., 1974, 90, 1, 41-55, https://doi.org/10.1016/S0021-9673(01)94772-7 . [all data]

Ainshtein and Shulyatieva, 1972
Ainshtein, A.A.; Shulyatieva, T.I., Retention indices of alkyl- and arylchlorosilanes, Zh. Anal. Khim., 1972, 27, 816-821. [all data]

Ellren, Peetre, et al., 1974
Ellren, O.; Peetre, I.B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. V. Use of refractive index in conjunction with Kovats retention index for the identification of organosilicon compounds, J. Chromatogr., 1974, 93, 2, 383-392, https://doi.org/10.1016/S0021-9673(01)85402-9 . [all data]


Notes

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