n-Pentadecanol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-658.3 ± 0.6kJ/molCcbMosselman and Dekker, 1975ALS
Quantity Value Units Method Reference Comment
Δcsolid-9817.7kJ/molCcbMosselman and Dekker, 1975Corresponding Δfsolid = -658.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
567.4323.15Khasanshin and Zykova, 1989T = 323 to 573 K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
537.3358.Vasil'ev, Petrov, et al., 1982T = 358 to 608 K.; DH
400.298.15Mosselman, Mourik, et al., 1974T = 295 to 308 K.; DH
535.318.Mosselman, Mourik, et al., 1974T = 318 to 346 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus317.65KN/AGaikwad and Subrahmanyam, 1985Uncertainty assigned by TRC = 0.4 K; TRC
Tfus311.7KN/ABelousov, Bubnov, et al., 1977Uncertainty assigned by TRC = 2. K; TRC
Tfus316.92KN/AMosselman, Mourik, et al., 1974, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.05 K; TRC
Tfus316.61KN/AMosselman, Mourik, et al., 1974, 2Crystal phase 2 phase; Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Δvap103.5 ± 3.3kJ/molCGCNichols, Kweskin, et al., 2006AC
Δvap102.5kJ/molGSKulikov, Verevkin, et al., 2001Based on data from 319. to 358. K.; AC
Δvap107.2kJ/molCGCKoutek, Hoskovec, et al., 1994Based on data from 353. to 393. K. See also Ova, Koultek, et al., 2000.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
95.5339.GSKulikov, Verevkin, et al., 2001Based on data from 319. to 358. K.; AC
92.4368.N/AN'Guimbi, Kasehgari, et al., 1992Based on data from 343. to 393. K.; AC
75.0453.AStephenson and Malanowski, 1987Based on data from 438. to 600. K.; AC
72.4468.AStephenson and Malanowski, 1987Based on data from 453. to 584. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
29.6316.4DSCVentol«65533», Calvet, et al., 2004AC
53.62316.9N/Avan Miltenburg, van den Berg, et al., 2003The value of 53.62 includes both the enthalpy of fusion as well as the enthalpy of solid-to-solid transition that occurs at 315.4 K; AC
54.73316.6N/AMosselman, Mourik, et al., 1974AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
74.81316.Mosselman and Mouric, 1974CAL
172.86316.6

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
23.650316.2crystaline, βcrystaline, αMosselman, Mourik, et al., 1974DH
54.720316.6crystaline, βliquidMosselman, Mourik, et al., 1974DH
30.350316.9crystaline, αliquidMosselman, Mourik, et al., 1974DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
74.8316.2crystaline, βcrystaline, αMosselman, Mourik, et al., 1974DH
172.8316.6crystaline, βliquidMosselman, Mourik, et al., 1974DH
95.8316.9crystaline, αliquidMosselman, Mourik, et al., 1974DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

n-Pentadecanol + Chloridosulfuric acid = Pentadecyl sulfuric acid + Hydrogen chloride

By formula: C15H32O + ClHO3S = C15H32O4S + HCl

Quantity Value Units Method Reference Comment
Δr56. ± 3.kJ/molCmMarkitanova, Barsukov, et al., 1981liquid phase; solvent: Dichloromethane; Sulfation

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Khasanshin and Zykova, 1989
Khasanshin, T.S.; Zykova, T.B., Specific heat of saturated monatomic alcohols, Inzh. -Fiz. Zhur., 1989, 56(6), 991-994. [all data]

Vasil'ev, Petrov, et al., 1982
Vasil'ev, I.A.; Petrov, V.M.; Treibsho, E.I., Study of the specific heat of some liquid higher alcohols, Zhur. Priklad. Khim., 1982, 55, 2116-2117. [all data]

Mosselman, Mourik, et al., 1974
Mosselman, C.; Mourik, J.; Dekker, H., Enthalpies of phase change and heat capacities of some long-chain alcohols. Adiabatic semi-microcalorimeter for studies of polymorphism, J. Chem. Thermodynam., 1974, 6, 477-487. [all data]

Gaikwad and Subrahmanyam, 1985
Gaikwad, B.R.; Subrahmanyam, V.V., Melting behavior of fatty alcohols and their binary blends., J. Indian Chem. Soc., 1985, 62, 513. [all data]

Belousov, Bubnov, et al., 1977
Belousov, V.P.; Bubnov, V.I.; Pfestorf, R.; Schumichen, A., Calorimetric characteristics of selected nonelectrotype systems. Additional experimental measurement of enthalpy of mixing in systems of n- alkylanine-aromatic & n-alchohol-aromatic, Z. Chem., 1977, 17, 382. [all data]

Mosselman, Mourik, et al., 1974, 2
Mosselman, C.; Mourik, J.; Dekker, H., Enthalpies of phase change and heat capacities of some long-chain alcohols. Adiabatic semi-microcalorimeter for studies of polymorphism, J. Chem. Thermodyn., 1974, 6, 477-87. [all data]

Nichols, Kweskin, et al., 2006
Nichols, Gary; Kweskin, Sasha; Frericks, Margaret; Reiter, Sarah; Wang, Gin; Orf, Jennifer; Carvallo, Brett; Hillesheim, Dorothea; Chickos, James, Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols: The Vaporization Enthalpy of 1-, 6-, 7-, and 9-Heptadecanol, 1-Octadecanol, 1-Eicosanol, 1-Docosanol, 1-Hexacosanol, and Cholesterol at T = 298.15 K by Correlation Gas Chromatography, J. Chem. Eng. Data, 2006, 51, 2, 475-482, https://doi.org/10.1021/je0503857 . [all data]

Kulikov, Verevkin, et al., 2001
Kulikov, Dmitry; Verevkin, Sergey P.; Heintz, Andreas, Enthalpies of vaporization of a series of aliphatic alcohols, Fluid Phase Equilibria, 2001, 192, 1-2, 187-207, https://doi.org/10.1016/S0378-3812(01)00633-1 . [all data]

Koutek, Hoskovec, et al., 1994
Koutek, Bohumír; Hoskovec, Michal; Vrkocová, Pavlína; Konecný, Karel; Feltl, Ladislav, Gas chromatographic determination of vapour pressures of pheromone-like compounds II. Alcohols, Journal of Chromatography A, 1994, 679, 2, 307-317, https://doi.org/10.1016/0021-9673(94)80573-3 . [all data]

Ova, Koultek, et al., 2000
Ova, P.V.; Koultek, B.; Hoskovec, M., Practice Oriented Results on Use and Production of Neem Ingredients and Pheromones VI, H. Kleeberg and C.P.W. Zebitz, ed(s)., Druck and Graphic, Giessen, 2000, 211-218. [all data]

N'Guimbi, Kasehgari, et al., 1992
N'Guimbi, J.; Kasehgari, H.; Mokbel, I.; Jose, J., Tensions de vapeur d'alcools primaires dans le domaine 0,3 Pa à 1,5 kPa, Thermochimica Acta, 1992, 196, 2, 367-377, https://doi.org/10.1016/0040-6031(92)80100-B . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Ventol«65533», Calvet, et al., 2004
Ventol«65533», L.; Calvet, T.; Cuevas-Diarte, M.A.; Ram«65533»rez, M.; Oonk, H.A.J.; Mondieig, D.; Negrier, Ph., Melting behaviour in the n-alkanol family. Enthalpy?entropy compensation, Phys. Chem. Chem. Phys., 2004, 6, 8, 1786, https://doi.org/10.1039/b313106h . [all data]

van Miltenburg, van den Berg, et al., 2003
van Miltenburg, J. Cees; van den Berg, Gerrit.J.K.; Ramirez, Marius, Heat Capacities and Derived Thermodynamic Functions of 1-Dodecanol and 1-Tridecanol between 10 K and 370 K and Heat Capacities of 1-Pentadecanol and 1-Heptadecanol between 300 K and 380 K and Correlations for the Heat Capacity and the Entropy of Liquid n -Alcohols, J. Chem. Eng. Data, 2003, 48, 1, 36-43, https://doi.org/10.1021/je025524o . [all data]

Mosselman and Mouric, 1974
Mosselman, C.; Mouric, J., Enthalpies of phase change and heat capacities of some long-chain alcohols. Adiabatic semi-microcalorimeter for studies of polymorphism, J. Chem. Thermodyn., 1974, 6, 5, 477, https://doi.org/10.1016/0021-9614(74)90009-3 . [all data]

Markitanova, Barsukov, et al., 1981
Markitanova, L.I.; Barsukov, I.I.; Passet, B.V., Determination of heat of sulfation by calorimetric titration, J. Gen. Chem. USSR, 1981, 51, 1286-1289. [all data]


Notes

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