Phosphine, diethyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C4H11P+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.69PECullen, Frost, et al., 1972LLK
8.5EIBogolyubov, Grishin, et al., 1969RDSH
8.5 ± 0.3EIBogolyubov, Grishin, et al., 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH2P+18.1 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
CH3P+16.8 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
CH4P+14.4 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H3+20.4 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H4P+15.6 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H5+14.5 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H5P+12.0 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H6P+13.7 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H7P+10.9 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C3H6P+13.2 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C3H8P+12.1 ± 0.3CH3EIBogolyubov, Grishin, et al., 1969RDSH
C4H10P+13.2 ± 0.3HEIBogolyubov, Grishin, et al., 1969RDSH
PH3+12.8 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 711

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References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cullen, Frost, et al., 1972
Cullen, W.R.; Frost, D.C.; Leeder, W.R., The ultraviolet and photoelectron spectra of some unsaturated fluorocarbon derivatives, J. Fluorine Chem., 1972, 1, 227. [all data]

Bogolyubov, Grishin, et al., 1969
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of group V and group VI elements. VIII.Mass spectra of phosphines and diphosphines, Zh. Obshch. Khim., 1969, 39, 1808, In original 1772. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References