Mercury, diethyl-
- Formula: C4H10Hg
- Molecular weight: 258.71
- IUPAC Standard InChIKey: SPIUPAOJDZNUJH-UHFFFAOYSA-N
- CAS Registry Number: 627-44-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Diethylmercury; (C2H5)2Hg
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.5 ± 0.1 | EI | Gowenlock, Haynes, et al., 1962 | RDSH |
8.9 | PE | Creber and Bancroft, 1980 | Vertical value; LLK |
8.45 | PE | Fehlner, Ulman, et al., 1976 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C2H5+ | 10.3 ± 0.1 | ? | EI | Gowenlock, Haynes, et al., 1962 | RDSH |
C2H5Hg+ | 9.7 ± 0.1 | C2H5 | EI | Gowenlock, Haynes, et al., 1962 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Gowenlock, Haynes, et al., 1962
Gowenlock, B.G.; Haynes, R.M.; Majer, J.R.,
Electron impact measurement on some organomercury compounds,
J. Chem. Soc. Faraday Trans., 1962, 58, 1905. [all data]
Creber and Bancroft, 1980
Creber, D.K.; Bancroft, G.M.,
Photoelectron studies of dialkyl group 2B compounds: Ligand field splittings intensity variations with photon energy,
Inorg. Chem., 1980, 19, 643. [all data]
Fehlner, Ulman, et al., 1976
Fehlner, T.P.; Ulman, J.; Nugent, W.A.; Kochi, J.K.,
Effect of alkyl substituents on the first ionization potential and on 5d10 ionization in dialkylmercury compounds,
Inorg. Chem., 1976, 15, 2544. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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