α-Aminoisobutanoic acid
- Formula: C4H9NO2
- Molecular weight: 103.1198
- IUPAC Standard InChIKey: FUOOLUPWFVMBKG-UHFFFAOYSA-N
- CAS Registry Number: 62-57-7
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Alanine, 2-methyl-; α-Aminoisobutyric acid; α-Methylalanine; α,α-Dimethylglycine; AIB; Propionic acid, 2-amino-2-methyl-; 2-Amino-2-methylpropanoic acid; 2-Aminoisobutyric acid; 2-Methylalanine; Propanoic acid, 2-amino-2-methyl-; 2-Amino-2-methylpropionic acid; NSC 16590
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Condensed phase thermochemistry data
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -594.28 ± 0.48 | kJ/mol | Ccb | Steele, Chirico, et al., 1997 | |
ΔfH°solid | -527. ± 2.0 | kJ/mol | Ccb | Contineanu and Marchidan, 1994 | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -2265.99 ± 0.42 | kJ/mol | Ccb | Steele, Chirico, et al., 1997 | |
ΔcH°solid | -2330. ± 2.0 | kJ/mol | Ccb | Contineanu and Marchidan, 1994 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
125.8 | 450.5 | A | Stephenson and Malanowski, 1987 | Based on data from 439. to 462. K. |
134.2 | 413.5 | A | Stephenson and Malanowski, 1987 | Based on data from 403. to 424. K. |
129.5 ± 0.4 | 455. | ME | Svec and Clyde, 1965 | See also Clyde and Svec, 1964. |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compiled by: Coblentz Society, Inc.
- SOLID (NUJOL MULL); PERKIN-ELMER 21 (GRATING) $$SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1; 2 cm-1 resolution
- SOLID (OIL MULL) $$SPECTRAL CONTAMINATION DUE TO OIL AROUND 1450 CM-1; BAIRD (PRISM); DIGITIZED BY COBLENTZ SOCIETY (BATCH II) FROM HARD COPY; 2 cm-1 resolution
- SOLID (SPLIT MULL), FLUOROLUBE FOR 3800-1330 CM-1, NUJOL FOR 1330-460 CM-1; DOW KBr FOREPRISM-GRATING; DIGITIZED BY COBLENTZ SOCIETY (BATCH I) FROM HARD COPY; 2 cm-1 resolution
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-5033 |
NIST MS number | 228103 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Steele, Chirico, et al., 1997
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A.,
Thermodynamic properties and ideal-gas enthalpies of formation for 2-aminoisobutyric acid (2-methylalanine), acetic acid, (4-methyl-3-penten-2-one), 4-methylpent-1-ene, 2,2'-bis(phenylthio)propane, and glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane),
J. Chem. Eng. Data, 1997, 42, 1052-1066. [all data]
Contineanu and Marchidan, 1994
Contineanu, J.; Marchidan, D.I.,
The enthalpies of combustion and formation of some isomers of aminobutyric (aminobutanoic) acid,
Rev. Roum. Chim., 1994, 39, 1391-1395. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Svec and Clyde, 1965
Svec, H.J.; Clyde, D.D.,
Vapor Pressures of Some α-Amino Acids.,
J. Chem. Eng. Data, 1965, 10, 2, 151-152, https://doi.org/10.1021/je60025a024
. [all data]
Clyde and Svec, 1964
Clyde, D.D.; Svec, H.,
, U. S. Atomic Energy Comm. IS-790, 1964, 1. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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