Nitric acid, ethyl ester
- Formula: C2H5NO3
- Molecular weight: 91.0660
- IUPAC Standard InChIKey: IDNUEBSJWINEMI-UHFFFAOYSA-N
- CAS Registry Number: 625-58-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethyl nitrate; C2H5ONO2; Nitric ether; Ethylester kyseliny dusicne; NA 1993
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -37.0 ± 0.8 | kcal/mol | Eqk | Gray, Pratt, et al., 1956 | See Gray and Smith, 1954 |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -45.51 ± 0.25 | kcal/mol | Ccb | Fairbrother, Skinner, et al., 1957 | ALS |
ΔfH°liquid | -45.7 ± 0.8 | kcal/mol | Eqk | Gray, Pratt, et al., 1956 | See Gray and Smith, 1954; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -313.39 ± 0.23 | kcal/mol | Ccb | Fairbrother, Skinner, et al., 1957 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 59.08 | cal/mol*K | N/A | Gray and Smith, 1954 | DH |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
40.70 | 298. | Gray and Smith, 1954 | T = 21 to 293 K.; DH |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: NO2- + C2H5NO3 = (NO2- • C2H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.9 | kcal/mol | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 35.3 | cal/mol*K | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M |
By formula: (NO2- • O2S) + C2H5NO3 = (NO2- • C2H5NO3 • O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.4 | kcal/mol | HPMS | Wlodek, Luczynski, et al., 1983, 2 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 10.4 | cal/mol*K | HPMS | Wlodek, Luczynski, et al., 1983, 2 | gas phase; Entropy change is questionable; M |
By formula: (NO2- • 2C2H5NO3) + C2H5NO3 = (NO2- • 3C2H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.3 | kcal/mol | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 14.1 | cal/mol*K | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; Entropy change is questionable; M |
By formula: (NO2- • C2H5NO3) + C2H5NO3 = (NO2- • 2C2H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.5 | kcal/mol | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 12.8 | cal/mol*K | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; Entropy change is questionable; M |
By formula: (NO3- • C2H5NO3) + C2H5NO3 = (NO3- • 2C2H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.2 | kcal/mol | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 8.7 | cal/mol*K | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; Entropy change is questionable; M |
By formula: NO3- + C2H5NO3 = (NO3- • C2H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.2 | kcal/mol | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 32.2 | cal/mol*K | HPMS | Wlodek, Luczynski, et al., 1983 | gas phase; M |
By formula: C2H6O + HNO3 = C2H5NO3 + H2O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -6.00 | kcal/mol | Eqk | Rubtsov, 1986 | liquid phase; ALS |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.22 | PI | Watanabe, Nakayama, et al., 1962 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CH2NO3+ | 11.4 | CH3 | EI | Fraser and Paul, 1968 | RDSH |
CH2NO3+ | 10.13 ± 0.11 | CH3 | EI | Collin, 1963 | RDSH |
CH2O+ | 11.76 ± 0.65 | ? | EI | Collin, 1963 | RDSH |
CH3+ | 13.75 ± 0.50 | ? | EI | Collin, 1963 | RDSH |
C2H5+ | 11.86 ± 0.25 | ? | EI | Collin, 1963 | RDSH |
NO2+ | 12.3 | C2H5O | EI | Fraser and Paul, 1968 | RDSH |
NO2+ | 11.40 ± 0.12 | C2H5O | EI | Collin, 1962 | RDSH |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Gray, Pratt, et al., 1956
Gray, P.; Pratt, M.W.T.; Larkin, M.J.,
39. The latent heat of vaporization and the thermochemistry of ethyl nitrate,
J. Chem. Soc., 1956, 210-212. [all data]
Gray and Smith, 1954
Gray, P.; Smith, P.L.,
Low-temperature calorimetry and the thermodynamic properties of ethyl nitrate,
J. Chem. Soc., 1954, 769-773. [all data]
Fairbrother, Skinner, et al., 1957
Fairbrother, D.M.; Skinner, H.A.; Evans, F.W.,
The heats of combustion of organic compounds of nitrogen,
Trans. Faraday Soc., 1957, 53, 779-783. [all data]
Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H.,
Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate,
Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0
. [all data]
Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr.,
Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions,
J. Chem. Phys., 1980, 73, 2195. [all data]
Wlodek, Luczynski, et al., 1983, 2
Wlodek, S.; Luczynski, Z.; Wincel, H.,
Gas phase complexes of NO2- and NO3- with SO2,
Int. J. Mass Spectrom. Ion Processes, 1983, 49, 301. [all data]
Rubtsov, 1986
Rubtsov, Yu.I.,
Thermodynamic calculation of equilibrium in nitration of alcohols,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 19-22. [all data]
Watanabe, Nakayama, et al., 1962
Watanabe, K.; Nakayama, T.; Mottl, J.,
Ionization potentials of some molecules,
J. Quant. Spectry. Radiative Transfer, 1962, 2, 369. [all data]
Fraser and Paul, 1968
Fraser, R.T.M.; Paul, N.C.,
The mass spectrometry of nitrate esters and related compounds. Part I,
J. Chem. Soc. B, 1968, 659. [all data]
Collin, 1963
Collin, J.E.,
L'ionisation et la dissociation du nitrate d'ethyle sous l'impact electronique, et le potential d'ionisation du dioxyde d'azote,
Bull. Soc. Roy. Sci. Liege, 1963, 32, 133. [all data]
Collin, 1962
Collin, J.E.,
Ionization potential of NO2,
Nature, 1962, 196, 373. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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