Silane, triethyl-
- Formula: C6H16Si
- Molecular weight: 116.2767
- IUPAC Standard InChIKey: AQRLNPVMDITEJU-UHFFFAOYSA-N
- CAS Registry Number: 617-86-7
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Triethylsilane; (C2H5)3SiH; Triethylsilicon hydride; CT2523
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.5 | PE | Potzinger, Ritter, et al., 1975 | LLK |
9.9 | PE | Beltram, Fehlner, et al., 1980 | Vertical value; LLK |
10.0 | PE | Roberge, Sandorfy, et al., 1978 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C4H10Si+ | 9.8 ± 0.1 | C2H6 | EI | Potzinger, Ritter, et al., 1975 | LLK |
C6H15Si+ | 10.4 ± 0.1 | H | EI | Potzinger, Ritter, et al., 1975 | LLK |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Polymethylsiloxane, (PMS-20000) | 50. | 743.7 | Ainshtein and Shulyatieva, 1972 | He, Chromosorb W; Column length: 2. m |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-101 | 737. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Methyl Silicone | 744. | Zenkevich and Kuznetsova, 1990 | Program: not specified |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J.,
Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen,
Z. Naturforsch. A:, 1975, 30, 347. [all data]
Beltram, Fehlner, et al., 1980
Beltram, G.; Fehlner, T.P.; Mochida, K.; Kochi, J.K.,
UV photoelectron spectra of group IV alkyl hydrides,
J. Electron Spectrosc. Relat. Phenom., 1980, 18, 153. [all data]
Roberge, Sandorfy, et al., 1978
Roberge, R.; Sandorfy, C.; Matthews, J.I.; Strausz, O.P.,
The far ultraviolet HeI photoelectron spectra of alkyl and fluorine substituted silane derivatives,
J. Chem. Phys., 1978, 69, 5105. [all data]
Ainshtein and Shulyatieva, 1972
Ainshtein, A.A.; Shulyatieva, T.I.,
Retention indices of alkyl- and arylchlorosilanes,
Zh. Anal. Khim., 1972, 27, 816-821. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Zenkevich and Kuznetsova, 1990
Zenkevich, I.G.; Kuznetsova, L.M.,
Logic Criteria on Prediction of Gas Chromatographic Retention Indices from Physico-Chemical Properties of Organic Compounds,
Dokl. Akad. Nauk SSSR, 1990, 315, 4, 881-885. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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