Stibine, triethyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid5. ± 11.kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Δcliquid-4864. ± 11.kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
242.25298.15Maslova, Novoselova, et al., 1973T = 60 to 300 K.; DH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
13.0 ± 0.3EIBogolyubov, Grishin, et al., 1969RDSH
9.2 ± 0.3EIBogolyubov, Grishin, et al., 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3Sb+16.5 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
CH4Sb+17.4 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H4Sb+14.8 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H5Sb+12.4 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H6Sb+12.6 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C2H7Sb+12.6 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C4H10Sb+10.7 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
C4H11Sb+10.0 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
SbH+18.3 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
SbH2+17.2 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH
Sb+19.2 ± 0.3?EIBogolyubov, Grishin, et al., 1969RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Maslova, Novoselova, et al., 1973
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B., Specific heat and phase changes of triethylindium, triethyl antimony, and trimethyl gallium, Trudy. Khim. Khim. Tekhnol., 1973, (2), 51-52. [all data]

Bogolyubov, Grishin, et al., 1969
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of group V and group VI elements. X. Mass spectra of tetraethyldistibine, diethyl diselenide, diethyl ditelluride, and the corresponding monoderivatives. Interpretation of mass-spectral intensities, Zh. Obshch. Khim., 1969, 39, 2244, In original 2190. [all data]


Notes

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