Stibine, triethyl-
- Formula: C6H15Sb
- Molecular weight: 208.943
- IUPAC Standard InChIKey: KKOFCVMVBJXDFP-UHFFFAOYSA-N
- CAS Registry Number: 617-85-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Triethylantimony; Triethylstibine; (C2H5)3Sb
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Condensed phase thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 5. ± 11. | kJ/mol | Review | Martinho Simões | MS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -4864. ± 11. | kJ/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
242.25 | 298.15 | Maslova, Novoselova, et al., 1973 | T = 60 to 300 K.; DH |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
13.0 ± 0.3 | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
9.2 ± 0.3 | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CH3Sb+ | 16.5 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
CH4Sb+ | 17.4 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
C2H4Sb+ | 14.8 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
C2H5Sb+ | 12.4 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
C2H6Sb+ | 12.6 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
C2H7Sb+ | 12.6 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
C4H10Sb+ | 10.7 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
C4H11Sb+ | 10.0 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
SbH+ | 18.3 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
SbH2+ | 17.2 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
Sb+ | 19.2 ± 0.3 | ? | EI | Bogolyubov, Grishin, et al., 1969 | RDSH |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Maslova, Novoselova, et al., 1973
Maslova, V.A.; Novoselova, N.V.; Moseeva, E.M.; Berezhnaya, N.D.; Rabinovich, I.B.,
Specific heat and phase changes of triethylindium, triethyl antimony, and trimethyl gallium,
Trudy. Khim. Khim. Tekhnol., 1973, (2), 51-52. [all data]
Bogolyubov, Grishin, et al., 1969
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A.,
Organic derivatives of group V and group VI elements. X. Mass spectra of tetraethyldistibine, diethyl diselenide, diethyl ditelluride, and the corresponding monoderivatives. Interpretation of mass-spectral intensities,
Zh. Obshch. Khim., 1969, 39, 2244, In original 2190. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy Cp,liquid Constant pressure heat capacity of liquid ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.