Benzamide, N-methyl-
- Formula: C8H9NO
- Molecular weight: 135.1632
- IUPAC Standard InChIKey: NCCHARWOCKOHIH-UHFFFAOYSA-N
- CAS Registry Number: 613-93-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: N-Methylbenzamide; N-Methylbenzenamide
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 352. | K | N/A | Saavedra, 1979 | Uncertainty assigned by TRC = 3. K; TRC |
Reduced pressure boiling point
Tboil (K) | Pressure (atm) | Reference | Comment |
---|---|---|---|
440.2 | 0.014 | Aldrich Chemical Company Inc., 1990 | BS |
437. to 438. | 0.020 | Frinton Laboratories Inc., 1986 | BS |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
17.9 | 309. | A | Stephenson and Malanowski, 1987 | Based on data from 297. to 321. K. See also Aihara, 1955.; AC |
20.5 | 318. | A | Stephenson and Malanowski, 1987 | Based on data from 307. to 329. K. See also Aihara, 1960.; AC |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference |
---|---|---|
9.33 ± 0.05 | EI | Thorstad, Undheim, et al., 1975 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Saavedra, 1979
Saavedra, J.E.,
Reductdion of Nitrosoamides to Alcohols Using Sodium Borohydride,
J. Org. Chem., 1979, 44, 860-1. [all data]
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Frinton Laboratories Inc., 1986
Frinton Laboratories Inc.,
Catalog Number 11, Frinton Laboratories Inc., Vineland, NJ, 1986, 99. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Aihara, 1955
Aihara, A.,
J. Chem. Soc. Jpn. Pure Chem. Sect., 1955, 76, 495. [all data]
Aihara, 1960
Aihara, Ariyuki,
Estimation of the Energy of Hydrogen Bonds Formed in Crystals. III. Amides,
Bull. Chem. Soc. Jpn., 1960, 33, 9, 1188-1194, https://doi.org/10.1246/bcsj.33.1188
. [all data]
Thorstad, Undheim, et al., 1975
Thorstad, O.; Undheim, K.; El-Gendy, M.A.F.,
Ionisation potentials in structure analysis of isomeric nitrones, oxaziranes, O-ether oximes acid amides,
Org. Mass Spectrom., 1975, 10, 1155. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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