2-Tetrazene, 1,1,4,4-tetramethyl-

• Formula: C₄H₁₂N₄
• Molecular weight: 116.1649
• IUPAC Standard InChI: InChI=1S/C4H12N4/c1-7(2)5-6-8(3)4/h1-4H3 Copy

  
• IUPAC Standard InChIKey: PRGCYUAJTPIADR-UHFFFAOYSA-N Copy
• CAS Registry Number: 6130-87-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Tetramethyl-2-tetrazene; Tetramethyltetrazene; Tetramethyltetrazone; 1,1,4,4-Tetramethyl-2-tetrazene; 1,1,4,4-Tetramethyltetrazene; (CH3)2NN=NN(CH3)2; NSC 38247; 2-Tetrazene, tetramethyl-
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• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Donovan, Shomate, et al., 1960
Donovan, T.M.; Shomate, C.H.; McBride, W.R., The heat of combustion of tetramethyltetrazene and 1,1-dimethylhydrazine, J. Phys. Chem., 1960, 64, 281-282. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Bischof, Gleiter, et al., 1975
Bischof, P.; Gleiter, R.; Dach, R.; Enders, D.; Seebach, D., Zur Wechselwirkung einsamer Elektronenpaare in Δ² Tetrazenen. Photoelektronenspektroskopische Untersuchungen, Tetrahedron, 1975, 31, 1415. [all data]

Gowenlock, Jones, et al., 1961
Gowenlock, B.G.; Jones, P.P.; Majer, J.R., Bond dissociation energies in some molecules containing alkyl substituted CH₃, NH₂, and OH, J. Chem. Soc. Faraday Trans., 1961, 57, 23. [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  ΔcH°liquid	Enthalpy of combustion of liquid at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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