sym-C6F3Cl3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16948 gas B-X 540 710 Maier, Marthaler, et al., 1980
Sears, Miller, et al., 1980
To = 16785 Ne B-X 390 660 Bondybey, 1979
To = 16636 Ar Bondybey, 1979
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 1146 gas LF Sears, Miller, et al., 1980
2 1148 Ne LF Bondybey, 1979
3 576 gas LF Sears, Miller, et al., 1980
3 581 Ne LF Bondybey, 1979
e' 8 1529 gas LF Sears, Miller, et al., 1980
8 1538 Ne LF Bondybey, 1979
9 1475 gas LF Sears, Miller, et al., 1980
9 1483 Ne LF Bondybey, 1979
10 1109 gas LF Sears, Miller, et al., 1980
10 1111 Ne LF Bondybey, 1979
12 393 gas LF Sears, Miller, et al., 1980
12 398 Ne LF Bondybey, 1979
13 294 gas LF Sears, Miller, et al., 1980
13 298 Ne LF Bondybey, 1979
14 180 gas LF Sears, Miller, et al., 1980
14 186 Ne LF Bondybey, 1979

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1' 3 584 gas LF Sears, Miller, et al., 1980
3 585 Ne LF Bondybey, 1979
e' 8 1629 Ne LF Bondybey, 1979
9 1428 Ne LF Bondybey, 1979
10 1128 Ne LF Bondybey, 1979
12 409 gas LF Sears, Miller, et al., 1980
429 Ne LF Bondybey, 1979
13 318 gas LF Sears, Miller, et al., 1980
13 324 Ne LF Bondybey, 1979
14 192 Ne LF Bondybey, 1979

Additional references: Jacox, 1994, page 439

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maier, Marthaler, et al., 1980
Maier, J.P.; Marthaler, O.; Mohraz, M.; Shiley, R.H., (π-1) → (π-1), (π-1) emission spectra of chlorofluorobenzene cations in the gaseous phase and their lifetimes in the (0o) states, Chem. Phys., 1980, 47, 3, 295, https://doi.org/10.1016/0301-0104(80)85015-4 . [all data]

Sears, Miller, et al., 1980
Sears, T.J.; Miller, T.A.; Bondybey, V.E., The laser induced fluorescence spectrum of the sym-trichlorotrifluorobenzene radical cation in the gas phase, J. Am. Chem. Soc., 1980, 102, 15, 4864, https://doi.org/10.1021/ja00535a002 . [all data]

Bondybey, 1979
Bondybey, V.E., Matrix studies of the ? 2A'2→? 2E transition of the sym-C6Cl3F3+ radical cation, J. Chem. Phys., 1979, 71, 9, 3586, https://doi.org/10.1063/1.438815 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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